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In the upcoming decade sustainable powertrain technologies will seek for market entrance in the transport sector. One promising solution is the utilization of dual-fuel engines using renewable methanol ignited by a pilot diesel fuel. This approach allows the displacement of a significant portion of fossil diesel, thereby reducing greenhouse gas emissions. Additionally, this technology is, next to newbuilds, suited for retrofitting existing engines, while maintaining high efficiencies and lowering engine-out emissions. Various researchers have experimentally tested the effects of replacing diesel by methanol and have reported different boundaries for substituting diesel by methanol, including misfire, partial burn, knock and pre-ignition. However, little research has been conducted to explore ways to extend these substitution limits.

To mitigate climate change, it is essential that sustainable technologies emerge in the transport industry. One viable solution is the use of methanol or hydrogen combined with internal combustion engines (ICEs). The dual-fuel technology in particular, in which a diesel pilot ignites port fuel injected methanol or hydrogen, is of great interest to transition from diesel engines to ICEs using purely these fuels. This approach allows for a significant portion of fossil diesel to be replaced with sustainable methanol or hydrogen, while maintaining high efficiencies and the possibility to run solely on diesel if required. Additionally, lower engine-out pollutant emissions (NOx, soot) are produced. Although multiple experimental research results are available, numerical literature on both fuels in dual-fuel mode is scarce. Therefore, this study aims to develop a multi-zone dual-fuel combustion model for engine simulations.

In the search for sustainable transportation fuels that are not in competition with food production, considerable efforts are made in the development of so-called second-generation (2G) biofuels. This paper looks into the results of a novel 2G biofuel production technique that is based on a catalytic process that operates at low temperature and that converts woody biomass feedstock into a stable light naphtha. The process development is integrated in the Belgian federal government funded Ad-Libio project and the process outcome is mainly consisting of hydrocarbons containing five to six carbon atoms. Their composition can be altered, resulting in a large amount of different possible fuel blends. The ultimate goal is to produce a drop-in fuel that can be fully interchanged with the gasoline fuels in use today. This is a challenge, since the Ad-Libio fuel components differ significantly from gasoline fuel components.

A commercially available fuel, E85, a blend of ~85% ethanol and ~15% gasoline, can be a viable substitute for fossil fuels in internal combustion engines in order to achieve a reduction of the greenhouse gas (GHG) emissions. Ethanol is traditionally made of biomass, which makes it a part of the food-feed-fuel competition. New processes that reuse waste products from other industries have recently been developed, making ethanol a renewable and sustainable second-generation fuel. So far, work on E85 has focused on spark ignition (SI) concepts due to high octane rating of this fuel. There is very little research on its application in CI engines. Alcohols are known for low soot particle emissions, which gives them an advantage in the NOx-soot trade-off of the compression ignition (CI) concept.

To speed up the development of the next-generation combustion engines with renewable fuels, the importance of reliable and robust simulations cannot be overemphasized. Compared to gasoline, methanol is a promising fuel for spark-ignited engines due to its higher research octane number to resist auto-ignition, higher flame speed for faster combustion and higher heat of vaporization for intake charge cooling. These advantageous properties all contribute to higher thermal efficiency and lower knock tendency, and they need to be well-captured in the simulation environment in order to generate accurate predictions. In this paper, the sub-models which estimate the burning velocities and ignition delay of methanol are revisited. These building blocks are implemented and integrated in a quasi-dimensional simulation environment to predict the combustion behavior, which are subsequently validated against test data measured on both light-duty and heavy-duty engines.

The large difference in fuel properties between methanol and gasoline demand the development of a dedicated spark ignition (SI) engine in order to exploit methanol’s properties for maximum thermal efficiency, rather than using the flex-fuel engines of today. In order to develop such an engine, proven technologies on a high efficiency gasoline engine are a good reference point to start with. The engine setup used in this work was a 1.6l turbocharged direct injection engine equipped with variable valve timing (VVT) and a low pressure EGR loop. A central composite design (CCD) was used to quantify the influence of five control parameters on the brake thermal efficiency (BTE) and main energy losses when running the engine on methanol at full load and a fixed engine speed of 1700 rpm. The set of control parameters consisted of the intake valve opening timing, exhaust valve opening timing, opening of the waste gate, opening of the EGR valve and opening of the backpressure valve.

Methanol is a promising fuel for future spark-ignition engines. Its properties enable increased engine efficiency. Moreover, the ease with which methanol can be reformed, using waste exhaust heat, potentially offers a pathway to even higher efficiencies. The primary objective of this study was to build and validate a model for a methanol fueled direct-injection spark-ignition engine with on-board fuel reforming for future investigation and optimization. The second objective was to understand the combustion characteristics, energy losses and engine efficiency. The base engine model was developed and calibrated before adding a reformed-exhaust gas recirculation system (R-EGR). A newly developed laminar burning velocity correlation with universal dilution term was implemented into the model to predict the laminar burning velocity with the presence of hydrogen in the reforming products.

In this work, the possibility to perform a cold-flow simulation as a way to improve the accuracy of the starting conditions for a combustion simulation is examined. Specifically, a dual-fuel marine engine running on methanol/diesel and natural gas/diesel fueling conditions is investigated. Dual-fuel engines can provide a short-term solution to cope with the more stringent emission legislations in the maritime sector. Both natural gas and methanol appear to be interesting alternative fuels that can be used as main fuel in these dual-fuel engines. Nevertheless, it is observed that combustion problems occur at part load using these alternative fuels. Therefore, different methods to increase the combustion efficiency at part load are investigated. Numerical simulations prove to be very suitable hereto, as they are an efficient way to study the effect of different parameters on the combustion characteristics.

Partially premixed combustion (PPC) is one of several advanced combustion concepts for the conventional diesel engine. PPC uses a separation between end of fuel injection and start of combustion, also called ignition dwell, to increase the mixing of fuel and oxidizer. This has been shown to be beneficial for simultaneously reducing harmful emissions and fuel consumption. The ignition dwell can be increased by means of exhaust gas recirculation or lower intake temperature. However, the most effective means is to use a fuel with high research octane number (RON). Methanol has a RON of 109 and a recent study found that methanol can be used effectively in PPC mode, with multiple injections, to yield high brake efficiency. However, the early start of injection (SOI) timings in this study were noted as a potential issue due to increased combustion sensitivity. Therefore, the present study attempts to quantify the changes in engine performance for different injection strategies.

Partially premixed combustion (PPC) with gasoline fuels is a new promising combustion concept for future internal combustion engines. However, many researchers have argued the capabilities of research octane number (RON) and Motor Octane Number (MON) to describe the autoignition behaviour of gasoline fuels in advanced combustion concepts like PPC. The objective of this study is to propose a new method, called PPC number, to characterize the auto ignition quality of gasoline fuels in a light-duty direct injected compression ignition engine under PPC conditions. The experimental investigations were performed on a 4-cylinder Volvo D4 2 litre engine. The ignition delay which was defined as the crank angle degrees between the start of injection (SOI) and start of combustion (SOC) was used to represent the auto ignition quality of a fuel.

Lean operation is a promising approach to increase the engine efficiency. One of the main challenges for lean-burn technology is the combustion instability. Using a high laminar burning velocity fuel such as methanol might solve that problem. The potential of lean-burn limit extension with methanol was investigated through a comparison with conventional gasoline. In this work, a direct injection turbocharged SI engine was operated at wide open throttle (WOT), with the load controlled by a lean-burn strategy. The amount of fuel was decreased (or lambda increased) until the combustion became unstable. For methanol, the lambda limit was about 1.5, higher than the lambda limit for gasoline which was only about 1.2. The brake thermal efficiency for methanol increased as lambda increased and reached its peak at ~41% in a lambda range of 1.2-1.4. Then, the efficiency decreased as lambda increased.

Low Temperature Combustion is a technology that enables achieving both a higher efficiency and simultaneously lower emissions of NOx and particulate matter. It is a noun for combustion regimes that operate with a lean air-fuel mixture and where the combustion occurs at a low temperature, such as Homogeneous Charge Compression Ignition and Partially Premixed Combustion. In this work a new model is proposed to predict the instantaneous heat flux in engines with Low Temperature Combustion. In-cylinder heat flux measurements were used to construct this model. The new model addresses two shortcomings of the existing heat transfer models already present during motored operation: the phasing of the instantaneous heat flux and the overprediction of the heat flux during the expansion phase. This was achieved by implementing the in-cylinder turbulence in the heat transfer model. The heat transfer during the combustion was taken into account by using the turbulence generated in the burned zone.

Engine optimization requires a good understanding of the in-cylinder heat transfer since it affects the power output, engine efficiency and emissions of the engine. However little is known about the convective heat transfer inside the combustion chamber due to its complexity. To aid the understanding of the heat transfer phenomena in a Spark Ignition (SI) engine, accurate measurements of the local instantaneous heat flux are wanted. An improved understanding will lead to better heat transfer modelling, which will improve the accuracy of current simulation software. In this research, prototype thin film gauge (TFG) heat flux sensors are used to capture the transient in-cylinder heat flux within a Cooperative Fuel Research (CFR) engine. A two-zone temperature model is linked with the heat flux data. This allows the distinction between the convection coefficient in the unburned and burned zone.

Methanol fueled spark ignition (SI) engines have the potential for very high efficiency using an advanced heat recovery system for fuel reforming. In order to allow simulation of such an engine system, several sub-models are needed. This paper reports the development of two laminar burning velocity correlations, corresponding to two reforming concepts, one in which the reformer uses water from an extra tank to produce hydrogen rich gas (syngas) and another that employs the water vapor in the exhaust gas recirculation (EGR) stream to produce reformed-EGR (R-EGR). This work uses a one-dimensional (1D) flame simulation tool with a comprehensive chemical kinetic mechanism to predict the laminar burning velocities of methanol/syngas blends and correlate it. The syngas is a mixture of H2/CO/CO2 with a CO selectivity of 6.5% to simulate the methanol steam reforming products over a Cu-Mn/Al catalyst.

Homogeneous Charge Compression Ignition (HCCI) engines can achieve both a high thermal efficiency and near-zero emissions of NOx and soot. However, their maximum attainable load is limited by the occurrence of a ringing combustion. At high loads, the fast combustion rate gives rise to pressure oscillations in the combustion chamber accompanied by a ringing or knocking sound. In this work, it is investigated how these pressure oscillations affect the in-cylinder heat transfer and what the best approach is to model the heat transfer during ringing combustion. The heat transfer is measured with a thermopile heat flux sensor inside a CFR engine converted to HCCI operation. A variation of the mass fuel rate at different compression ratios is performed to measure the heat transfer during three different operating conditions: no, light and severe ringing. The occurrence of ringing increases both the peak heat flux and the total heat loss.

To optimize internal combustion engines (ICEs), a good understanding of engine operation is essential. The heat transfer from the working gases to the combustion chamber walls plays an important role, not only for the performance, but also for the emissions of the engine. Besides, thermal management of ICEs is becoming more and more important as an additional tool for optimizing efficiency and emission aftertreatment. In contrast little is known about the convective heat transfer inside the combustion chamber due to the complexity of the working processes. Heat transfer measurements inside the combustion chamber pose a challenge in instrumentation due to the harsh environment. Additionally, the heat loss in a spark ignition (SI) engine shows a high temporal and spatial variation. This poses certain requirements on the heat flux sensor. In this paper we examine the heat transfer in a production SI ICE through the use of Thin Film Gauge (TFG) heat flux sensors.

In the development of internal combustion engines, measurements of the heat transfer to the cylinder walls play an important role. These measurements are necessary to provide data for building a model of the heat transfer, which can be used to further develop simulation tools for engine optimization. This research will focus on the Thin Film Gauge (TFG) heat flux sensor. This sensor consists of a platinum RTD (Resistance Temperature Detector) on an insulating Macor® (ceramic) substrate. The sensor has a high frequency response (up to 100 kHz) and is small and robust. These properties make the TFG sensor adequate for measurements in the combustion chamber of an internal combustion engine. To use this sensor, its thermal properties - namely the temperature sensitivity coefficient and the thermal product - must be correctly calibrated. First, different calibration setups with a different temperature range are used to calibrate the temperature sensitivity coefficient of the TFG sensor.

Stricter CO2 and emissions regulations are pushing spark ignition engines more and more towards downsizing, enabled through direct injection and turbocharging. The advantages which come with direct injection, such as increased charge density and an elevated knock resistance, are even more pronounced when using low carbon number alcohols instead of gasoline. This is mainly due to the higher heat of vaporization and the lower air-to-fuel ratio of light alcohols such as methanol, ethanol and butanol. These alcohols are also attractive alternatives to gasoline because they can be produced from renewable resources. Because they are liquid, they can be easily stored in a vehicle. In this respect, the performance and engine-out emissions (NOx, CO, HC and PM) of methanol, ethanol and butanol were examined on a 4 cylinder 2.4 DI production engine and are compared with those on neat gasoline.

Fuel atomization and combustion at engine-like conditions are complicated and sensitive processes which make it hard to perform quantitative experiments with high precision and reproducibility. A better understanding of the processes can be obtained by controlling the boundary conditions. Variable parameters with an important influence on the sprays include fuel temperature, chamber temperature, injection pressure, gas velocity. Controlling all these parameters in an experimental setup is not evident since a lot of them fluctuate with time or interact with each other. Constant volume combustion chambers, using the pre-combustion method, have already shown to be a useful experimental tool for this kind of research purposes. The obtained quantitative results can in a next step be used to evaluate either multi-dimensional or simplified lower dimensional models.

Using liquid alcohols, such as methanol and ethanol, in spark-ignition engines is a promising approach to decarbonize transport and secure domestic energy supply. Methanol and ethanol are compatible with the existing fuelling and distribution infrastructure and are easily stored in a vehicle. They can be used in internal combustion engines with only minor adjustments and have the potential to increase the efficiency and decrease noxious emissions compared to gasoline engines. In addition, methanol can be synthesized from a wide variety of sources, including renewably produced hydrogen in combination with atmospheric CO₂. Presently, during the production of ethanol or methanol a dehydration step is always applied. This step accounts for a significant part of the entire production process' energy consumption and thus, from an economical point of view, methanol and ethanol could become more interesting alternative fuels if the costs related with dehydration could be reduced.