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High cycle-to-cycle variations (CTCV) in a Hydrogen-Fueled Internal Combustion Engine (H2-ICE), especially in the lean-burn condition, not only lower the engine’s efficiency but also increase emissions and torque variations. High CTCV are mainly due to the variations in: mixture motion within the cylinder at the time of spark, amount of air and fuel fed to the cylinder, and mixing of the fresh mixture and residual gases within the cylinder during each cycle. In this article, multiple cycle-based methodologies were compared and analyzed specifically for H2-ICEs based on systematic experimentation. The experimental test campaign was performed on a Port Fuel Injection (PFI) H2-ICE designed by PUNCH Torino and data is processed with MATLAB. A MATLAB code is also proposed as a tool for comparing multiple methodologies for the analysis of CTCV specifically for H2-ICE.

Given the spread of natural gas engines in low-term toward decarbonization and the growing interest in gaseous mixtures as well as the use of hydrogen in Heavy-Duty (HD) engines, appropriate strategies are needed to maximize thermal efficiency and achieve near-zero emissions from these propulsor systems. In this context, some phenomena related to real-world driving operations, such as engine cut-off or misfire, can lead to inadequate control of the Air-to-Fuel ratio, key factor for Three-Way Catalyst (TWC) efficiency. Goal of the present research activity is to investigate the performance of a bio-methane-fueled HD engine and its Aftertreatment System (ATS), consisting of a Three-Way Catalyst, at different Air-to-Fuel ratio. An experimental test bench characterization, in different operating conditions of the engine workplan, was carried out to evaluate the catalyst reactivity to a defined pattern of the Air-to-Fuel ratio.

The forthcoming introduction of the EURO VII regulation requires urgent strategies and solutions for the reduction of sub-23 nm particle emissions. Although they have been historically considered as particulate matter-free, the high interest for Natural Gas (NG) Heavy-Duty engines in the transport sector, demands their compliance with the new proposed regulations. In order to obtain high conversion of gas pollutants and a strong abatement of the emitted particles, the use of Particle Filters in NG aftertreatment (CPF) in conjunction with the Three-Way Catalyst (TWC) may represent an attractive and feasible solution. Performances of a cordierite filter were explored through an extensive experimental campaign both in Steady-State conditions and during transient engine maneuvers that involved a whole analysis of the emitted particles in terms of number and mass.

Increasingly stringent pollutant and CO2 emission standards require the car manufacturers to investigate innovative solutions to further improve the fuel economy and environmental impact of their fleets. Nowadays, NOx emissions standards are stringent for spark-ignition (SI) internal combustion engines (ICEs) and many techniques are investigated to limit these emissions. Among these, an extremely lean combustion has a large potential to simultaneously reduce the NOx raw emissions and the fuel consumption of SI ICEs. Engines with pre-chamber ignition system are promising solutions for realizing a high air-fuel ratio which is both ignitable and with an adequate combustion speed. In this work, the combustion characteristics of an active pre-chamber system are experimentally investigated using a single-cylinder research engine. The engine under exam is a large bore heavy-duty unit with an active pre-chamber fuelled with compressed natural gas.

Active prechamber combustion systems for SI engines represent a feasible and effective solution in reducing fuel consumption and pollutant emissions for both marine and ground heavy-duty engines. However, reliable and low-cost numerical approaches need to be developed to support and speed-up their industrial design considering their geometry complexity and the involved multiple flow length scales. This work presents a CFD methodology based on the RANS approach for the simulation of active prechamber spark-ignition engines. To reduce the computational time, the gas exchange process is computed only in the prechamber region to correctly describe the flow and mixture distributions, while the whole cylinder geometry is considered only for the power-cycle (compression, combustion and expansion). Outside the prechamber the in-cylinder flow field at IVC is estimated from the measured swirl ratio.

Hydrogen Internal Combustion Engines (H2-ICEs) are being investigated due to their minimal criteria pollutant and zero CO2 tailpipe emissions. However, oil filters and non-hot joint gaskets have rubber material that can be damaged and deteriorate due to direct or indirect exposure to the high temperature and high-pressure hydrogen in a H2-ICE. Thus, the effects on the properties of a rubber exposed to a hydrogen environment need to be reviewed. In this review paper, the transportation, chemical and mechanical properties of a rubber exposed directly or indirectly to high temperature and high-pressure hydrogen in a H2-ICE have been reviewed. The compatibility of rubber materials used in H2-ICE has been explored. The effects of high-pressure hydrogen on the transportation, chemical and mechanical properties of NBR and HNBR have been reviewed.

Natural gas as an internal combustion engine fuel is taking a predominant role as a mid-term solution to pollution due to combustion driven human activities both in the energy and transport sectors. Engine researchers and manufacturers are in the process of investigating and improving strategies that decrease emissions and fuel consumption, without compromising engine performance and efficiency; active pre-chamber configurations are to be accounted for as one of these. A relatively small amount of fuel (up to 10 % of the total fuel-energy requirement) is introduced in the confined volume of the pre-chamber and forms a close-to-stoichiometric mixture with fresh charge that is introduced from the main combustion chamber during the compression stroke. After spark-ignition the products of this early stage of combustion can ignite ultra-lean mixtures (with λ up to 2) through the Turbulent Jet Ignition mechanism, hence reducing fuel consumption as well as noxious emissions such as NOx.

Research activities in the development of reliable computational models for aftertreatment systems are constantly increasing in the automotive field. These investigations are essential in order to get a complete understanding of the main catalytic processes which clearly have a great impact on tailpipe emissions. In this work, a 1D chemical reaction model to simulate the catalytic activity of a Pd/Rh Three-Way Catalyst (TWC) for a Natural Gas heavy-duty engine is presented. An extensive database of tests carried out with the use of a Synthetic Gas Bench (SGB) has been collected to investigate the methane abatement pathways, linked to the lambda variation and oxide formation on palladium surface. Specific steady-state tests have shown a dynamics of the methane conversion even at fixed λ and temperature conditions, essentially due to the Pd/PdO ratio.

A wider use of biofuels in internal combustion engines could reduce the emissions of pollutants and greenhouse gases from the transport sector. In particular, due to stringent emission regulatory programs, compression ignition engine requires interventions aimed at reducing their polluting emissions. Ethanol, a low carbon fuel generally produced from biomass, is a promising alternative fuel applicable in compression ignition engines to reduce CO2 and soot emissions. In this paper, the application of a dual fuel diesel-ethanol configuration in a light-duty compression ignition engine has been numerically investigated. Ethanol is injected into the intake port, while diesel fuel is directly injected into the combustion chamber of the analyzed engine. CFD simulations have been carried out by means of the AVL Fire 3-D code. The operation at given engine load and speed has been simulated considering different diesel injection timings.

Gas engines (fuelled with CNG, LNG or Biogas) for generation of power and heat are, to this date, taking up larger shares of the market with respect to diesel engines. In order to meet the limit imposed by the TA-Luft regulations on stationary engines, lean combustion represents a viable solution for achieving lower emissions as well as efficiency levels comparable with diesel engines. Leaner mixtures however affect the combustion stability as the flame propagation velocity and consequently heat release rate are slowed down. As a strategy to deliver higher ignition energy, an active pre-chamber may be used. This work focuses on assessing the performance of a pre-chamber combustion configuration in a stationary heavy-duty engine for power generation, operating at different loads, air-to-fuel ratios and spark timings.

A growing interest towards heavy-duty engines powered with NG, dictated by stringent regulations in terms of emissions, has made it essential to study a specific Three-Way Catalyst (TWC). Oxygen storage phenomena characterize the catalytic converter efficiency under real world driving operating conditions and, consequently, during strong dynamics in Air-to-Fuel ratio (AFR). A numerical “quasi-steady” model has been set-up to simulate the chemical process inside the reactor. A dedicated experimental campaign has been performed in order to evaluate the catalyst response to a defined λ variation, thus providing the data necessary for the numerical model validation. In fact, goal of the present research activity was to investigate the effect of very fast composition transitions of the engine exhaust typical of the mentioned driving conditions (including fuel cutoffs etc.) on the catalyst performance and on related emissions.

The combustion quality in modern diesel engines depends strictly on the quality of the air-fuel mixing and, in turn, from the quality of spray atomization process. So air-fuel mixing is strongly influenced by the injection pressure, geometry of the nozzle duct and the hydraulic characteristics of the injector. In this context, spray concepts alternative to the conventional multi-hole nozzles could be considered as solutions to the extremely high injection pressure increase to assure a higher and faster fuel-air mixing in the piston bowl, with the final target of increasing the fuel efficiency and reducing the engine emissions. The study concerns an experimental depiction of a spray generated through a prototype high-pressure hollow-cone nozzle, under evaporative and non-evaporative conditions, injecting the fuel in a constant-volume combustion vessel controlled in pressure and temperature up to engine-like gas densities in order to measure the spatial and temporal fuel patterns.

The interest in Natural Gas (NG) as alternative fuel for transportation is constantly growing, mostly due to its large availability and lower environmental impact with respect to gasoline or diesel fuel. In this scenario, the application of the Dual Fuel (DF) Diesel- Natural Gas (NG) combustion concept to light duty engines can represent an important route to increment the diffusion of natural gas use. Many studies have proven the benefits of DF with respect to conventional diesel combustion in terms of CO2, NOx, PM and PN emissions, with the main drawback of high unburned hydrocarbon, mainly at low/partial engine loads. This last aspect still prevents the application of DF mode to small displacement engines. In the present work, a 2.0 L Euro 5 compliant diesel engine, equipped with an advanced electronic closed-loop combustion control (CLCC) system, has been set up to operate in DF mode and tested on a dyno test bench.

Diesel particulate filter (DPF) is the most effective emission control device for reducing particle emissions (both mass, PM, and number, PN) from diesel engines, however many studies reported elevated emissions of nanoparticles (<50 nm) during its regeneration. In this paper the results of an extensive literature survey is presented. During DPF active regeneration, most of the literature studies showed an increase in the number of the emitted nanoparticles of about 2-3 orders of magnitude compared to the normal operating conditions. Many factors could influence their amount, size distribution, chemical-physical nature (volatiles, semi-volatiles, solid) and the duration of the regenerative event: i.e. DPF load and thermodynamic conditions, lube and fuel sulfur content, engine operative conditions, PN sampling and measurement methodologies.

In this paper, a parametric analysis on the main engine calibration parameters applied on gasoline Partially Premixed Combustion (PPC) is performed. Theoretically, the PPC concept permits to improve both the engine efficiencies and the NOx-soot trade-off simultaneously compared to the conventional diesel combustion. This work is based on the design of experiments (DoE), statistical approach, and investigates on the engine calibration parameters that might affect the efficiencies and the emissions of a gasoline PPC. The full factorial DoE analysis based on three levels and three factors (33 factorial design) is performed at three engine operating conditions of the Worldwide harmonized Light vehicles Test Cycles (WLTC). The pilot quantity (Qpil), the crank angle position when 50% of the total heat is released (CA50), and the exhaust gas recirculation (EGR) factors are considered. The goal is to identify an engine calibration with high efficiency and low emissions.

In the aim of reducing CO2 emissions and fuel consumption, the improvement of the diesel engine performance is based on the optimization of the whole combustion system efficiency. The focus of new technological solutions is devoted to the optimization of thermodynamic efficiency especially in terms of reduction of losses of heat exchange. In this context, it is required a continuous development of the engine combustion system, first of all the injection system and in particular the nozzle design. To this reason in the present paper a new concept of an open nozzle spray was investigated as a possible solution for application on diesel engines. The study concerns some experimental and numerical activities on a prototype of an open nozzle. An external supplier provided the prototypal version of the injector, with a dedicated piezoelectric actuation system, and with an appropriate choice of geometrical design parameters.

The paper reports an experimental study on the effect of compression ratio variation on the performance and pollutant emissions of a single-cylinder light-duty research diesel engine operating in DF mode. The architecture of the combustion system as well as the injection system represents the state-of-the-art of the automotive diesel technology. Two pistons with different bowl volume were selected for the experimental campaign, corresponding to two CR values: 16.5 and 14.5. The designs of the piston bowls were carefully performed with the 3D simulation in order to maintain the same air flow structure at the piston top dead center, thus keeping the same in-cylinder flow characteristics versus CR. The engine tests choice was performed to be representative of actual working conditions of an automotive light-duty diesel engine.

The present paper describes the results of a research activity aimed at studying the potential offered by the use of Hydrocracked fossil oil (HCK) and Hydrotreated Vegetable Oil (HVO) blends as premium fuels for next generation diesel engines. Five fuels have been tested in a light duty four cylinder diesel engine, Euro 5 version, equipped with closed loop control of the combustion. The set of fuels comprises four experimental fuels specifically formulated by blending high cetane HVO and HCK streams and oneEN590-compliant commercial diesel fuel representative of the current market fuel quality. A well consolidated procedure has been carried out to estimate, for the tested fuels, the New European Driving Cycle (NEDC) vehicle performance by means of the specific emissions at steady-state engine operating points.

The present paper reassumes the results of an experimental study focused on the effects of the nozzle injector's coking varying the flow number (FN); the performance and emissions of an automotive Euro5 diesel engine have been analyzed using diesel fuel. As the improvement of the diesel engine performance requires a continuous development of the injection system and in particular of the nozzle design, in the last years the general trend among OEMs is lowering nozzle flow number and, as a consequence, nozzle holes size. The study carried out moves from the consideration that a reduction of the nozzle holes diameter could increase the impact of their coking process. For this purpose, an experimental campaign has been realized, testing the engine in steady state in three partial load operating points, representative of the European homologation driving cycle, and in full load conditions.

In this paper the characteristics of a mixture of glycerol-based ethers usable in a compression ignition engine are investigated, in terms of efficiency and emissions. Alternative pathways for the energetic exploitation of biodiesel derived glycerol became of increasing interest as the biodiesel production was increased worldwide. Because of its detrimental physical and chemical properties, raw glycerol is hardly usable in conventional internal combustion engines (ICE). However, etherification of glycerol with tert-butyl alcohol and isobutylene allows obtaining a mixture mainly composed of higher glycerol ethers (GEM) suitable for compression ignition engines. Thus, the aim of this research study was to test a mixture of mono-, di- and tri-tert-butyl ethers of glycerol in blend with a commercial diesel fuel in a compression ignition engine, evaluating the fuel efficiency and the impact on the pollutant emissions.