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Technical Paper

Low NOx Emissions Performance after 800,000 Miles Aging Using CDA and an Electric Heater

2024-07-02
2024-01-3011
Engine and aftertreatment solutions have been identified to meet the upcoming ultra-low NOX regulations on heavy duty vehicles in the United States and Europe. These standards will require changes to current conventional aftertreatment systems for dealing with low exhaust temperature scenarios while increasing the useful life of the engine and aftertreatment system. Previous studies have shown feasibility of meeting the US EPA and California Air Resource Board (CARB) requirements. This work includes a 15L diesel engine equipped with cylinder deactivation (CDA) and an aftertreatment system that was fully DAAAC aged to 800,000 miles. The aftertreatment system includes an e-heater (electric heater), light-off Selective Catalytic Reduction (LO-SCR) followed by a primary aftertreatment system containing a DPF and SCR.
Technical Paper

Effect of Dithering on post-catalyst exhaust gas composition and on short time regeneration of deactivated PdO/Al2O3 catalysts under real engine conditions

2024-06-12
2024-37-0002
Fossil fuels such as natural gas used in engines still play the most important role worldwide despite such measures as the German energy transition which however is also exacerbating climate change as a result of carbon dioxide emissions. One way of reducing carbon dioxide emissions is the choice of energy sources and with it a more favourable chemical composition. Natural gas, for instance, which consist mainly of methane, has the highest hydrogen to carbon ratio of all hydrocarbons, which means that carbon dioxide emissions can be reduced by up to 35% when replacing diesel with natural gas. Although natural gas engines show an overall low CO2 and pollutant emissions level, methane slip due to incomplete combustion occurs, causing methane emissions with a more than 20 higher global warming potential than CO2.
Technical Paper

1D Modeling of a High-Performance Engine Fueled with H2 And Equipped with A Low NOx Aftertreatment Device

2024-06-12
2024-37-0009
Hydrogen engines are currently considered as a viable solution to preserve the internal combustion engine as a power unit for vehicle propulsion. In particular, lean-burn gasoline Spark-Ignition (SI) engines have been a major subject of investigations due to the reduced emission levels and high thermodynamic efficiency. This strategy is suitable for the purpose of passenger car applications and cannot be tailored in the field of high performance engine, where the air mass delivered would require oversized turbocharging systems or more complex charging solutions. For this reason, the range of stoichiometric feeding condition is explored in the high performance engine, leading to the consequent issue of abatement of pollutant emissions. In this work a 1D model will be applied to the modeling of a V8 engine fueled with DI of hydrogen. The engine has been derived by a gasoline configuration and adapted to hydrogen in such a way to keep the same performance.
Technical Paper

Acceleration of Fast-SCR Reactions by Eliminating “The Ammonia Blocking Effect”

2024-06-12
2024-37-0001
The recent and future trends of energy for heavy-duty vehicles are considered e-fuel, H2, and electricity, and the Selective Catalytic Reduction (SCR) system is necessary for achieving the goals of zero-emission internal combustion engines that use e-fuel and H2 as a fuel. The Japanese automotive industry uses a Cu-zeolite based SCR catalyst since Vanadium is designated as a specific chemical substance, which the Ministry of Environment prohibits its release into the atmosphere. This study attempted purification rate improvement by controlling the NH3 supply with a mini-reactor and by simulated exhaust gas. Specifically, the experiment was done by examining the effect of the pulse amplitude, frequency, and duty ratio on the purification rate by supplying the NH3 pulse injection to the test piece Cu-chabazite catalyst. Additionally, the results of the reactor experiment were validated by numerical simulation considering the detailed surface reaction processes on the catalyst.
Technical Paper

Catalytic Converter—An Integrated Approach to Reduce Carbon Dioxide Emission

2024-04-22
2024-01-5047
Vehicle emissions, which are rising alarmingly quickly, are a significant contributor to the air pollution that results. Incomplete combustion, which results in the release of chemicals including carbon monoxide, hydrocarbons, and particulate matter, is the main cause of pollutants from vehicle emissions. However, CO2 contributes more than the aforementioned pollutants combined. Carbon dioxide is the main greenhouse gas that vehicles emit. For every liter of gasoline burned by vehicles, around 2,347 grams of carbon dioxide are released. Therefore, it’s important to reduce vehicle emissions of carbon dioxide. The ability of materials like zeolite and silicon dioxide to absorb CO2 is outstanding. These substances transform CO2 into their own non-polluting carbonate molecules. Zeolite, silicon dioxide, and calcium oxide are combined to form the scrubbing material in a ratio based on their increasing adsorption propensities, along with enough bentonite sand to bind the mixture.
Technical Paper

Experimental Comparison of Different Cycle-Based Methodologies for the INDICATING in Hydrogen-Fueled Internal Combustion Engines

2024-04-09
2024-01-2834
High cycle-to-cycle variations (CTCV) in a Hydrogen-Fueled Internal Combustion Engine (H2-ICE), especially in the lean-burn condition, not only lower the engine’s efficiency but also increase emissions and torque variations. High CTCV are mainly due to the variations in: mixture motion within the cylinder at the time of spark, amount of air and fuel fed to the cylinder, and mixing of the fresh mixture and residual gases within the cylinder during each cycle. In this article, multiple cycle-based methodologies were compared and analyzed specifically for H2-ICEs based on systematic experimentation. The experimental test campaign was performed on a Port Fuel Injection (PFI) H2-ICE designed by PUNCH Torino and data is processed with MATLAB. A MATLAB code is also proposed as a tool for comparing multiple methodologies for the analysis of CTCV specifically for H2-ICE.
Technical Paper

Analysis of Dual Fuel Hydrogen/Diesel Combustion Varying Diesel and Hydrogen Injection Parameters in a Single Cylinder Research Engine

2024-04-09
2024-01-2363
In the perspective of a reduction of emissions and a rapid decarbonisation, especially for compression ignition engines, hydrogen plays a decisive role. The dual fuel technology is perfectly suited to the use of hydrogen, a fuel characterized by great energy potential. In fact, replacing, at the same energy content, the fossil fuel with a totally carbon free one, a significant reduction of the greenhouse gases, like carbon dioxide and total hydrocarbon, as well as of the particulate matter can be obtained. The dual fuel with indirect injection of gaseous fuel in the intake manifold, involves the problem of hydrogen autoignition. In order to avoid this difficulty, the optimal conditions for the injection of the incoming mixture into the cylinder were experimentally investigated. All combustion processes are carried out on a research engine with optical access. The engine speed has is set at 1500 rpm, while the EGR valve is deactivated.
Technical Paper

Simulation Methodology for Failure Analysis of Catalytic Converter Mounting on Commercial Vehicles

2024-04-09
2024-01-2247
Catalytic converters have been considered as an integral part of the vehicle powertrain for over a decade now, their application along with the engines increased significantly with the constant evolution of emission standards. Recent regulations keep a strict control on the major four pollutants of engine exhaust gas, i.e., Carbon Monoxide (CO), Nitrogen Oxides (NOx), Hydrocarbons (HC) & Particulate Matter (PM), which demands a highly efficient aftertreatment system. Efforts are continuously being made to downsize the engine for better fuel economy and low emissions, this puts additional requirement of designing a compact aftertreatment system equipped with Diesel Oxidation Catalyst (DOC), Diesel Particulate Filter (DPF) and Selective Catalytic Reduction (SCR). Compact catalytic converters experience larger vibration force transferred from the vehicle and hence the durability of the product is significantly impacted.
Technical Paper

Optical Investigation of Lean Combustion Characteristics of Non-Uniform Distributed Orifice Passive Pre-Chamber on a High Compression Ratio GDI Engine

2024-04-09
2024-01-2101
The passive pre-chamber (PC) is valued for its jet ignition (JI) and is suitable for wide use in the field of gasoline direct injection (GDI) for small passenger cars, which can improve the performance of lean combustion. However, the intake, exhaust, and ignition combustion stability of the engine at low speed is a shortcoming that has not been overcome. Changing the structural design to increase the fluidity of the main chamber (MC) and pre-chamber (PC) may reduce jet ignition performance, affecting engine dynamics. This investigation is based on non-uniformly nozzles distributed passive pre-chamber, which is adjusted according to the working medium exchange between PC and MC. The advantages and disadvantages of the ignition mode of PC and SI in the target engine speed range are compared through optical experiments on a small single-cylinder GDI engine.
Technical Paper

Numerical Study of an EGR Dilution in a Pre-Chamber Spark Ignited Engine Fuelled by Natural Gas

2024-04-09
2024-01-2081
Exhaust gas recirculation (EGR) is a proven strategy for the reduction of NOX emissions in spark ignited (SI) engines and compression ignition engines, especially in lean burn conditions where the increase of thermal efficiency is obtained. The dilution level of the mixture with EGR is in a conventional SI engine limited by the increase of combustion instability (CoV IMEP). A possible method to extend the EGR dilution level and ensure stable combustion is the implementation of an active pre-chamber combustion system. The pre-chamber spark ignited (PCSI) engine enables fast and stable combustion of lean mixtures in the main chamber by utilizing high ignition energy of multiple flame jets penetrating from the pre-chamber to the main chamber. In this paper, as an initial research step, a numerical analysis is performed by employing the 0D/1D simulation model, validated with the initial experimental and 3D-CFD results.
Technical Paper

Oxygenated Fuels as Reductants for Lean NOx Trap Regeneration

2024-04-09
2024-01-2132
The push for environmental protection and sustainability has led to strict emission regulations for automotive manufacturers as evident in EURO VII and 2026 EPA requirements. The challenge lies in maintaining fuel efficiency and simultaneously reducing the carbon footprint while meeting future emission regulations. Alcohol (primarily methanol, ethanol, and butanol) and ether (dimethyl ether) fuels, owing to their comparable energy density to existing fuels, the comparative ease of handling, renewable production, and suitable emission characteristics may present an attractive drop-in replacement, fully or in part as an additive, to the gasoline/diesel fuels, without extensive modifications to the engine geometry. Additionally, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines.
Technical Paper

Pre-Chamber Combustion System Development for an Ultra-Lean Gasoline Engine

2024-04-09
2024-01-2110
Amid rising demands for fuel efficiency and emissions reduction, enhancing the thermal efficiency of gasoline engines has become imperative, which requires higher efficiency combustion strategies and integrated optimized design to maximize the work output from fuel. In gasoline engine, both increasing the compression ratio and using lean burn mode improve the ratio of useful work output to the energy input effectively, which resulting in higher thermal efficiency. Although there is limited scope for increasing the compression ratio due to the higher sensitivity to knocking, especially under stoichiometric conditions, reduced sensitivity could be got with leaner mixture fill into cylinder, which can further increase the specific heat ratio and thermal efficiency.
Technical Paper

Simulation Study of Sparked-Spray Induced Combustion at Ultra-Lean Conditions in a GDI Engine

2024-04-09
2024-01-2107
Ultra-lean combustion of GDI engine could achieve higher thermal efficiency and lower NOx emissions, but it also faces challenges such as ignition difficulties and low-speed flame propagation. In this paper, the sparked-spray is proposed as a novel ignition method, which employs the spark to ignite the fuel spray by the cooperative timing control of in-cylinder fuel injection and spark ignition and form a jet flame. Then the jet flame fronts propagate in the ultra-lean premixed mixture in the cylinder. This combustion mode is named Sparked-Spray Induced Combustion (SSIC) in this paper. Based on a 3-cylinder 1.0L GDI engine, a 3D simulation model is established in the CONVERGE to study the effects of ignition strategy, compression ratio, and injection timing on SSIC with a global equivalence ratio of 0.50. The results show it is easier to form the jet flame when sparking at the spray front because the fuel has better atomization and lower turbulent kinetic energy at the spray front.
Technical Paper

Combustion and HC&PN Emission Characteristics at First Cycle Starting of Gasoline Engine under Lean Burn Based on Active Pre-Chamber

2024-04-09
2024-01-2108
As a novel ignition technology, pre-chamber ignition can enhance ignition energy, promote flame propagation, and augment turbulence. However, this technology undoubtedly faces challenges, particularly in the context of emission regulations. Of this study, the transient characteristics of combustion and emissions in a hybrid electric vehicle (HEV) gasoline engine with active pre-chamber ignition (PCI) under the first combustion cycle of quick start are focused. The results demonstrate that the PCI engine is available on the first cycle for lean combustion, such as lambda 1.6 to 2.0, and exhibit particle number (PN) below 7×107 N/mL at the first cycle. These particles are predominantly composed of nucleation mode (NM, <50 nm) particles, with minimal accumulation mode (AM, >50 nm) particles.
Technical Paper

Numerical Modeling of Liquid Film Boiling, Urea Deposition and Solidification in SCR Applications

2024-04-09
2024-01-2626
The proposed Euro 7 regulation aims to substantially reduce the NOx emissions to 0.03 g/km, a trend also seen in upcoming China 6b and US EPA regulations. Meeting these stringent requirements necessitates advancements in Urea/Selective Catalytic Reduction (SCR) aftertreatment systems, with the urea deposit formation being a key challenge to its design. It’s proven that Computational Fluid Dynamics (CFD) can be an effective tool to predict Urea deposits. Transient wall temperature prediction is crucial in Urea deposit modeling. Additionally, fully understanding the kinetics of urea decomposition and by-products solidification are also critical in predicting the deposit amount and its location. In this study, we introduce (i) a novel film boiling model (IFPEN-BRT model) and (ii) a new urea by-product solidification model in the CONVERGE CFD commercial solver, and validate the results against the recent experiments.
Technical Paper

Algorithm to Calibrate Catalytic Converter Simulation Light-Off Curve

2024-04-09
2024-01-2630
Spark ignition engines utilize catalytic converters to reform harmful exhaust gas emissions such as carbon monoxide, unburned hydrocarbons, and oxides of nitrogen into less harmful products. Aftertreatment devices require the use of expensive catalytic metals such as platinum, palladium, and rhodium. Meanwhile, tightening automotive emissions regulations globally necessitate the development of high-performance exhaust gas catalysts. So, automotive manufactures must balance maximizing catalyst performance while minimizing production costs. There are thousands of different recipes for catalytic converters, with each having a different effect on the various catalytic chemical reactions which impact the resultant tailpipe gas composition. In the development of catalytic converters, simulation models are often used to reduce the need for physical parts and testing, thus saving significant time and money.
Technical Paper

Kinetic Model Development for Selective Catalytic Converter Integrated Particulate Filters

2024-04-09
2024-01-2631
To meet the stringent NOx and particulate emissions requirements of Euro 6 and China 6 standard, Selective Catalyst Reduction (SCR) catalyst integrated with wall flow particulate filter (SCR-DPF) has been found to be an effective solution for the exhaust aftertreatment systems of diesel engines. NOx is reduced by ammonia generated from urea injection while the filter effectively traps and burns the particulate matter periodically in a process called regeneration. The engine control unit (ECU) effectively manages urea injection quantity, timing and soot burning frequency for the stable functioning of the SCR-DPF without impacting drivability. To control the NOx reduction and particulate regeneration process, the control unit uses lookup tables generated from extensive hardware testing to get the current soot load and NOx slip information of SCR-DPF as a function of main exhaust state variables.
Technical Paper

Reducing Emissions from Lean-Burn Hydrogen Combustion Engines Using a State-of-the-Art Oxidation Catalyst and a VWTi-Based SCR Catalyst: Potentials and Challenges

2024-04-09
2024-01-2634
Hydrogen (H2) is commonly considered as one of the most promising carbon-free energy carriers allowing for a decarbonization of combustion applications, for instance by retrofitting of conventional diesel internal combustion engines (ICEs). Although modern H2-ICEs emit only comparably low levels of nitrogen oxides (NOx), efficient catalytic converters are mandatory for exhaust gas after-treatment in order to establish near-zero emission applications. In this context, the present study evaluates the performance of a commercial state-of-the-art oxidation catalyst (OC) and of a catalyst for selective catalytic reduction (SCR) that are typically used for emission reduction from diesel exhausts under conditions representative for H2-fueled ICEs, namely oxygen-rich exhausts with high water vapor levels, comparably low temperatures, and potentially considerable levels of unburnt H2.
Technical Paper

Development of Optimal Specification of Exhaust Purification System for Euro7 Commercial Diesel Legislation

2024-04-09
2024-01-2627
In this study, an integrated emission prediction model was used to predict whether EURO7-compliant commercial internal combustion engine vehicles would be able to meet upcoming regulations. In particular, the optimal value of Adblue injection and EHC (Electrically Heated Catalyst) control strategy for each combination of the specifications of the close-coupled SCR system (volume, substrate spec., EHC, etc.) was derived. Through this, it was intended to derive the best specification combination in terms of control and emission performance, and to use the results as a basis for decision-making in the early stages of product concept selection.
Technical Paper

Numerical Study on the Design of a Passive Pre-Chamber for a Heavy-Duty Hydrogen Combustion Engine

2024-04-09
2024-01-2112
Lean-burn hydrogen internal combustion engines are a good option for future transportation solutions since they do not emit carbon-dioxide and unburned hydro-carbons, and the emissions of nitric-oxides (NOx) can be kept low. However, under lean-burn conditions the combustion duration increases, and the combustion stability decreases, leading to a reduced thermal efficiency. Turbulent jet ignition (TJI) can be used to extend the lean-burn limit, while decreasing the combustion duration and improving combustion stability. The objective of this paper is to investigate the feasibility of a passive pre-chamber TJI system on a heavy-duty hydrogen engine under lean-burn conditions using CFD modelling. The studied concept is mono-fuel, port-fuel injected, and spark ignited in the pre-chamber. The overall design of the pre-chamber is discussed and the effect of design parameters on the engine performance are studied.
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