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In a DI diesel engine, THC emissions increase significantly with lower compression ratios, a low coolant temperature, or during the transient state. During the transient after a load increase, THC emissions are increased significantly to very high concentrations from just after the start of the load increase until around the 10th cycle, then rapidly decreased until the 20th cycle, before gradually decreasing to a steady state value after 1000 cycles. In the fully-warmed steady state operation with a compression ratio of 16 and diesel fuel, THC is reasonably low, but THC increases with lower coolant temperatures or during the transient period just after increasing the load. This THC increase is due to the formation of over-lean mixture with the longer ignition delay and also due to the fuel adhering to the combustion chamber walls. A low distillation temperature fuel such as normal heptane can eliminate the THC increase.

This research investigates the influences of the injection timing, injection pressure, and compression ratio on the combustion and exhaust emissions in a single cylinder 1.0 L DI diesel engine operating with ultra-high EGR. Longer ignition delays due to either advancing or retarding the injection timing reduced the smoke emissions, but advancing the injection timing has the advantages of maintaining the thermal efficiency and preventing misfiring. Smokeless combustion is realized with an intake oxygen content of only 9-10% regardless of the injection pressure. Reduction in the compression ratio is effective to reduce the in-cylinder temperature and increase the ignition delay as well as to expand the smokeless combustion range in terms of EGR and IMEP. However, the thermal efficiency deteriorates with excessively low compression ratios.

Ultra-low NOx and smokeless operation at higher loads up to half of the rated torque is attempted with large ratios of cold EGR. NOx decreases below 6 ppm (0.05 g/(kW·h)) and soot significantly increases when first decreasing the oxygen concentration to 16% with cold EGR, but after peaking at 12-14% oxygen, soot then deceases sharply to essentially zero at 9-10% oxygen while maintaining ultra low NOx and regardless of fuel injection quantity. However, at higher loads, with the oxygen concentration below 9-10%, the air/fuel ratio has to be over-rich to exceed half of rated torque, and thermal efficiency, CO, and THC deteriorate significantly. As EGR rate increases, exhaust gas emissions and thermal efficiency vary with the intake oxygen content rather than with the excess air ratio.

The thermal cracking and polyaromatic hydrocarbon (PAH) formation processes of dimethyl ether (DME), ethanol, and ethane were investigated with chemical kinetics to determine the soot formation mechanism of oxygenated fuels. The modeling analyzed three processes, an isothermal constant pressure condition, a temperature rising condition under a constant pressure, and an unsteady condition approximating diesel combustion. With the same mole number of oxygen atoms, the DME rich mixtures form much carbon monoxide and methane and very little non-methane HC and PAH, in comparison with ethanol or ethane mixtures. This suggests that the existence of the C-C bond promotes the formation of PAH and soot.

Direct injection of various ignition suppressors, including water, methanol, ethanol, 1-propanol, hydrogen, and methane, was implemented to control ignition timing and expand the operating range in an HCCI engine with induced DME as the main fuel. Ultra-low NOx and smoke-less combustion was realized over a wide operating range. The reaction suppressors reduced the rate of low-temperature oxidation and consequently delayed the onset of high-temperature oxidation. Analysis of the chemical kinetics showed a reduction of OH radical in the premixed charge with the suppressors. Among the ignition suppressors, alcohols had a greater impact on OH radical reduction resulting in stronger ignition suppression. Although water injection caused a greater lowering of the temperature, which also suppressed ignition, the strong chemical effect of radical reduction with methanol injection resulted in the larger impact on suppression of oxidation reaction rates.

The fundamental parameters related to engine combustion and performances, such as, heating value, theoretical air-fuel ratio, adiabatic flame temperature, carbon dioxide (CO2), and nitric oxide (NO) emissions, specific heat and engine thermal efficiency were investigated with computations for a wide range of oxygenated fuels. The computed results showed that almost all of the above combustion-related parameters are closely related to oxygen content in the fuels regardless of the kinds or chemical structures of oxygenated fuels. An interesting finding was that with the increase in oxygen content in the fuels NO emission decreased linearly, and the engine thermal efficiency was almost unchanged below oxygen content of 30 wt-% but gradually decreased above 30 wt-%.

Smokeless and ultra low NOx combustion without knocking in a dual-fuel diesel engine with induced LPG as the main fuel was established with a uniquely developed piston cavity divided by a lip in the sidewall. A small quantity of diesel fuel was directly injected at early compression stroke into the lower part of the cavity as an ignition source for this confined area, and this suppressed explosively rapid combustion just after ignition and spark-knock like combustion at later stage. A combination of the divided cavity, EGR, and intake air throttling was effective to simultaneously eliminate knocking, and reduce THC and NOx significantly.

Ultra low emissions and high performance combustion was achieved with a combination of high EGR, a three-way catalyst, and a highly oxygenated liquid fuel, neat dimethoxy methane (DMM), in an ordinary DI diesel engine. The smokeless nature of neat DMM effectively allowed stoichiometric diesel combustion by controlling BMEP with EGR. NOx, THC, and CO emissions were reduced with a three-way catalyst. At lower BMEP with excess air, the EGR effectively reduced NOx. High-speed video in a bottom view type engine revealed that luminous flame decreased with increased fuel oxygen content and almost disappeared with DMM.

Significant improvements in exhaust emissions and engine performance in an ordinary DI diesel engine were realized with highly oxygenated fuels. The smoke emissions decreased sharply and linearly with increases in oxygen content and entirely disappeared at an oxygen content of 38 wt-% even at stoichiometric conditions. The NOx, THC, and CO were almost all removed with a three-way catalyst under stoichiometric diesel combustion at both the higher and lower BMEP with the combination of EGR and a three-way catalyst. The engine output for the highly oxygenated fuels was significantly higher than that with the conventional diesel fuel due to the higher air utilization.

Changes in exhaust gas emissions during starting in a DI diesel engine were investigated. The THC after starting increased until around the 50th cycle when the fuel deposited on the combustion chamber showed the maximum, and THC then decreased to reach a steady value after about 1000 cycles when the piston wall temperature became constant. The NOx showed an initial higher peak just after starting, and increased to a steady value after about 1000 cycles. Exhaust odor had a strong correlation with THC, and at the early stage odor was stronger than would be expected from the THC concentration. The THC increased with increased fuel injection amounts, decreased cranking speeds, and fuels with higher viscosity, higher 90% distillation temperature, and lower ignitability.

The effect of direct water injection into the combustion chamber on NOx reduction in an IDI diesel engine was investigated. The temperature distribution in the swirl chamber was analyzed quantitatively with high speed photography and the two color method. Direct water injection into a swirl chamber prior to fuel injection reduced NOx emission significantly over a wide output range without sacrifice of BSFC. Other emissions were almost unchanged or slightly decreased with water injection. Water injection reduced the flame temperature at the center of the swirl chamber, while the mean gas temperature in the cylinder and the rate of heat release changed little.

A new concept DISC engine equipped with a two-stage injection system was developed. The engine was modified from a single cylinder DI diesel engine with large cylinder diameter (135mm). Combustion characteristics and exhaust emissions with regular gasoline were examined, and the experiments were also made with gasoline-diesel fuel blends with higher boiling temperatures and lower octane numbers. To realize stratified mixture distribution in combustion chamber flexibly, the fuel was injected in two-stages: the first stage was before the compression stroke to create a uniform premixed lean mixture and the second stage was at the end of the compression stroke to maintain stable ignition and faster combustion. In this paper, the effect of the two-stage injection on combustion and exhaust emissions were analyzed under several operating conditions.

Time series analysis of diesel exhaust gas emissions under transient operation was carried out using a uniquely developed gas sampling system to efficiently collect all exhaust gas throughout transient cycles. The effects of fuel properties and other engine operation parameters on the exhaust emissions under transient runs when fuel amounts abruptly increase were analyzed. The results showed that THC increased abruptly to 2 or 6 times the final steady-state concentration immediately after the start of acceleration and then decreased to the steady-state values after 70∼200 cycles. At acceleration, NOx increased abruptly to about 80 % of the final NOx concentration, and then increased gradually to reach the final values after 60∼500 cycles. The behaviors of THC and NOx during transient operation can be described by exponential functions of the elapsed cycle numbers and the final emission concentrations.

Experiments on a large number of soluble fuel additives were systematically conducted for diesel soot reduction. It was found that Ca and Ba were the most effective soot suppressors. The main determinants of soot reduction were: the metal mol-content of the fuel, the excess air factor, and the gas turbulence in the combustion chamber. The soot reduction ratio was expressed by an exponential function of the metal mol-content in the fuel, depending on the metal but independent of the metal compound. A rise in excess air factor or gas turbulence increased the value of a coefficient in the function, resulting in larger reductions in soot with the fuel additives. High-speed soot sampling from the cylinder showed that with the metal additive, the soot concentration in the combustion chamber was substantially reduced during the whole period of combustion. It is thought that the additive acts as a catalyst not only to improve soot oxidation but also to suppress soot formation.

This paper is concerned with the effects of temperature of heavy fuels on combustion and engine performance in a naturally aspirated DI diesel engine. Engine performance and exhaust gas emissions were measured for rapeseed oil, B-heavy oil, and diesel fuel at fuel temperatures from 40°C to 400°C. With increased fuel temperature, mainly from improved efficiency of combustion there were significant reductions in the specific energy consumption and smoke emissions. It was found that the improvements were mainly a function of the fuel viscosity, and it was independent of the kind of fuel. The optimum temperature of the fuels with regard to specific energy consumption and smoke emission is about 90°C for diesel fuel, 240°C for B-heavy oil, and 300°C for rapeseed oil. At these temperatures, the viscosities of the fuels show nearly identical value, 0.9 - 3 cst. The optimum viscosity tends to increase slightly with increases in the swirl ratio in the combustion chamber.

Spark-assisted diesel engines operated with alcohol fuels usually display misfiring or knocking problems. This paper presents an analysis of the factors influencing the ignition characteristics of ethanol in a swirl chamber diesel engine with a multi-spark ignitor. In the experiments, cycle-to-cycle combustion variations and the degree of knocking were investigated by changing engine parameters over a wide operating range. The results of the investigations showed that stable ignition and smooth combustion is achieved when a flammable mixture is formed in the vicinity of the spark plug when only a small amount of the injected fuel has evaporated. By optimizing the design factors, operation with high efficiency and low exhaust emissions was achieved.

Many of the promissing alternative fuels have relatively low cetane numbers, and may-result in combustion variation problems. This paper presents the chracteristics of the cycle-to-cycle combustion variations in diesel engines, and analyzes and evaluates the mechanism. Combustion variations appear in various forms, such as variations in ignition lag, indicated mean effective pressure, maximum combustion pressure, or rate of heat release. These variations are clearly correlated, and it is possible to represent the combustion variations by the standard deviation in the combustion peak pressure. The combustion variations are random (non-periodic), and are affected by ethanol amount, intake air temperature, engine speed and other various operating conditions.

Forced ignition with glow plugs has great potential for the utilization of alcohol fuels in diesel engines. However, the installation of glow plugs may cause misfiring or knocking in parts of the operating range. This paper presents an analysis of the factors influencing the ignition characteristics of ethanol in a glow plug-assisted diesel engine; these factors may be classified into two categories: the factors related to the temperature history of the drop lets before contact with the glow plug, and those related to the probability of contact. By optimizing these factors, the combustion difficulties were successfully eliminated over the whole operating range, and engine performance comparable with conventional diesel operation was achieved.

In a four-cycle, naturally aspirated, pre-chamber diesel engine, the combustion characteristics such as the rates of fuel injection, the ignition lag, the rates of heat release, the combustion peak pressure, the maximum rates of pressure rise, and the smoke density, were investigated for over 70 consecutive cycles under acceleration, with the aid of an on-line data handling system developed for this experiment. The effects of operating conditions such as the fuel injection timing, the fuel spray angle, the wall temperature of the combustion chamber, and the coolant temperature, on the combustion characteristics were also investigated.

To get accurate indicator diagrams without the use of pressure transducers, the strain and the displacement of the various parts of engine structures that would have some relationship with the pressure variation in the cylinder were measured and analyzed mathematically. By measuring the strain of the cylinder head bolts, the horizontal displacement of the crank shaft end, and the vertical displacement of the intake valve stem, we realized that the indicator diagrams could be obtained easily without a passage from the interior to the outside of the combustion chamber. Accurate indicator diagrams were estimated by applying the pressure-strain diagram obtained from the static pressure test in the cylinder to the strain variation in the cylinder head bolts. On this occasion, the accuracy of the estimated indicator diagrams could be improved by providing the cylinder head system with a one degree freedom vibration system.