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Technical Paper

A Three-Way Catalyst Model for a Bio-Methane Heavy-Duty Engine: Characterization at Different Lambda

2024-04-09
2024-01-2084
Given the spread of natural gas engines in low-term toward decarbonization and the growing interest in gaseous mixtures as well as the use of hydrogen in Heavy-Duty (HD) engines, appropriate strategies are needed to maximize thermal efficiency and achieve near-zero emissions from these propulsor systems. In this context, some phenomena related to real-world driving operations, such as engine cut-off or misfire, can lead to inadequate control of the Air-to-Fuel ratio, key factor for Three-Way Catalyst (TWC) efficiency. Goal of the present research activity is to investigate the performance of a bio-methane-fueled HD engine and its Aftertreatment System (ATS), consisting of a Three-Way Catalyst, at different Air-to-Fuel ratio. An experimental test bench characterization, in different operating conditions of the engine workplan, was carried out to evaluate the catalyst reactivity to a defined pattern of the Air-to-Fuel ratio.
Technical Paper

Experimental and Numerical Investigation of a Particle Filter Technology for NG Heavy-Duty Engines

2023-04-11
2023-01-0368
The forthcoming introduction of the EURO VII regulation requires urgent strategies and solutions for the reduction of sub-23 nm particle emissions. Although they have been historically considered as particulate matter-free, the high interest for Natural Gas (NG) Heavy-Duty engines in the transport sector, demands their compliance with the new proposed regulations. In order to obtain high conversion of gas pollutants and a strong abatement of the emitted particles, the use of Particle Filters in NG aftertreatment (CPF) in conjunction with the Three-Way Catalyst (TWC) may represent an attractive and feasible solution. Performances of a cordierite filter were explored through an extensive experimental campaign both in Steady-State conditions and during transient engine maneuvers that involved a whole analysis of the emitted particles in terms of number and mass.
Technical Paper

Methane Conversion and Ammonia Formation Model over a Pd-Rh Three-Way Catalyst for CNG Heavy-Duty Engines

2021-09-05
2021-24-0002
Research activities in the development of reliable computational models for aftertreatment systems are constantly increasing in the automotive field. These investigations are essential in order to get a complete understanding of the main catalytic processes which clearly have a great impact on tailpipe emissions. In this work, a 1D chemical reaction model to simulate the catalytic activity of a Pd/Rh Three-Way Catalyst (TWC) for a Natural Gas heavy-duty engine is presented. An extensive database of tests carried out with the use of a Synthetic Gas Bench (SGB) has been collected to investigate the methane abatement pathways, linked to the lambda variation and oxide formation on palladium surface. Specific steady-state tests have shown a dynamics of the methane conversion even at fixed λ and temperature conditions, essentially due to the Pd/PdO ratio.
Technical Paper

Experimental and Numerical Assessment of Active Pre-chamber Ignition in Heavy Duty Natural Gas Stationary Engine

2020-04-14
2020-01-0819
Gas engines (fuelled with CNG, LNG or Biogas) for generation of power and heat are, to this date, taking up larger shares of the market with respect to diesel engines. In order to meet the limit imposed by the TA-Luft regulations on stationary engines, lean combustion represents a viable solution for achieving lower emissions as well as efficiency levels comparable with diesel engines. Leaner mixtures however affect the combustion stability as the flame propagation velocity and consequently heat release rate are slowed down. As a strategy to deliver higher ignition energy, an active pre-chamber may be used. This work focuses on assessing the performance of a pre-chamber combustion configuration in a stationary heavy-duty engine for power generation, operating at different loads, air-to-fuel ratios and spark timings.
Technical Paper

Combustion and Emission Characteristics of a Diesel Engine Fuelled with Diesel-LPG Blends

2019-09-09
2019-24-0038
Recently, it has been worth pointing out the relevance of alternative fuels in the improvement of air quality conditions and in the mitigation of global warming. In order to deal with these demands, in recent studies, it has been considered a great variety of alternative fuels. It goes without saying that the alternative fuels industry needs the best of the efficiency with a moderate layout. From this perspective, Liquefied Petroleum Gas (LPG) could represent a valid option, although it is not a renewable fuel. In terms of polluting emissions, the LPG can reduce nitrous oxides and smoke concentrations in the air, a capability that has a relevant importance for the modern pollution legislation. LPG is well known as an alternative fuel for Spark Ignition (SI) engines and, more recently, LPG systems have also been introduced in the Compression Ignition (CI) engines in dual-fuel configuration.
Technical Paper

Development of a Dedicated CNG Three-Way Catalyst Model in 1-D Simulation Platforms

2019-09-09
2019-24-0074
A growing interest towards heavy-duty engines powered with NG, dictated by stringent regulations in terms of emissions, has made it essential to study a specific Three-Way Catalyst (TWC). Oxygen storage phenomena characterize the catalytic converter efficiency under real world driving operating conditions and, consequently, during strong dynamics in Air-to-Fuel ratio (AFR). A numerical “quasi-steady” model has been set-up to simulate the chemical process inside the reactor. A dedicated experimental campaign has been performed in order to evaluate the catalyst response to a defined λ variation, thus providing the data necessary for the numerical model validation. In fact, goal of the present research activity was to investigate the effect of very fast composition transitions of the engine exhaust typical of the mentioned driving conditions (including fuel cutoffs etc.) on the catalyst performance and on related emissions.
Journal Article

Key Fuel Injection System Features for Efficiency Improvement in Future Diesel Passenger Cars

2019-04-02
2019-01-0547
Diesel will continue to be an indispensable energy carrier for the car fleet CO2 emission targets in the short-term. This is particularly relevant for heavy-duty vehicles as for mid-size cars and SUVs. Looking at the latest technology achievements on the after-treatment systems, it can be stated that the concerning about the NOx emission gap between homologation test and real road use is basically solved, while the future challenge for diesel survival is to keep its competitiveness in the CO2 vs cost equation in comparison to other propulsion systems. The development of the combustion system design still represents an important leverage for further efficiency and emissions improvements while keeping the current excellent performance in terms of power density and low-end torque.
Technical Paper

Assessment of Engine Control Parameters Effect to Minimize GHG Emissions in a Dual Fuel NG/Diesel Light Duty Engine

2018-04-03
2018-01-0266
The interest in Natural Gas (NG) as alternative fuel for transportation is constantly growing, mostly due to its large availability and lower environmental impact with respect to gasoline or diesel fuel. In this scenario, the application of the Dual Fuel (DF) Diesel- Natural Gas (NG) combustion concept to light duty engines can represent an important route to increment the diffusion of natural gas use. Many studies have proven the benefits of DF with respect to conventional diesel combustion in terms of CO2, NOx, PM and PN emissions, with the main drawback of high unburned hydrocarbon, mainly at low/partial engine loads. This last aspect still prevents the application of DF mode to small displacement engines. In the present work, a 2.0 L Euro 5 compliant diesel engine, equipped with an advanced electronic closed-loop combustion control (CLCC) system, has been set up to operate in DF mode and tested on a dyno test bench.
Technical Paper

How Much Regeneration Events Influence Particle Emissions of DPF-Equipped Vehicles?

2017-09-04
2017-24-0144
Diesel particulate filter (DPF) is the most effective emission control device for reducing particle emissions (both mass, PM, and number, PN) from diesel engines, however many studies reported elevated emissions of nanoparticles (<50 nm) during its regeneration. In this paper the results of an extensive literature survey is presented. During DPF active regeneration, most of the literature studies showed an increase in the number of the emitted nanoparticles of about 2-3 orders of magnitude compared to the normal operating conditions. Many factors could influence their amount, size distribution, chemical-physical nature (volatiles, semi-volatiles, solid) and the duration of the regenerative event: i.e. DPF load and thermodynamic conditions, lube and fuel sulfur content, engine operative conditions, PN sampling and measurement methodologies.
Technical Paper

Parametric Analysis of the Effect of Pilot Quantity, Combustion Phasing and EGR on Efficiencies of a Gasoline PPC Light-Duty Engine

2017-09-04
2017-24-0084
In this paper, a parametric analysis on the main engine calibration parameters applied on gasoline Partially Premixed Combustion (PPC) is performed. Theoretically, the PPC concept permits to improve both the engine efficiencies and the NOx-soot trade-off simultaneously compared to the conventional diesel combustion. This work is based on the design of experiments (DoE), statistical approach, and investigates on the engine calibration parameters that might affect the efficiencies and the emissions of a gasoline PPC. The full factorial DoE analysis based on three levels and three factors (33 factorial design) is performed at three engine operating conditions of the Worldwide harmonized Light vehicles Test Cycles (WLTC). The pilot quantity (Qpil), the crank angle position when 50% of the total heat is released (CA50), and the exhaust gas recirculation (EGR) factors are considered. The goal is to identify an engine calibration with high efficiency and low emissions.
Technical Paper

Hydrocracked Fossil Oil and Hydrotreated Vegetable Oil (HVO) Effects on Combustion and Emissions Performance of “Torque-Controlled” Diesel Engines

2015-09-06
2015-24-2497
The present paper describes the results of a research activity aimed at studying the potential offered by the use of Hydrocracked fossil oil (HCK) and Hydrotreated Vegetable Oil (HVO) blends as premium fuels for next generation diesel engines. Five fuels have been tested in a light duty four cylinder diesel engine, Euro 5 version, equipped with closed loop control of the combustion. The set of fuels comprises four experimental fuels specifically formulated by blending high cetane HVO and HCK streams and oneEN590-compliant commercial diesel fuel representative of the current market fuel quality. A well consolidated procedure has been carried out to estimate, for the tested fuels, the New European Driving Cycle (NEDC) vehicle performance by means of the specific emissions at steady-state engine operating points.
Technical Paper

On Cooler and Mixing Condensation Phenomena in the Long-Route Exhaust Gas Recirculation Line

2015-09-06
2015-24-2521
The abatement of nitrogen oxides emissions is a topic of major concern for automotive manufacturers. In addition to aftertreatment solutions such as LNT or SCR devices, the use of exhaust gas recirculation (EGR) is necessary in most of the applications to meet emissions regulations. Due to the high specific humidity of the exhaust gases, a high condensate flow may be generated if EGR gases are significantly cooled down. In the case of long-route EGR (LR-EGR) usage, this condensate flow would reach the compressor wheel. This paper explores the variables governing the condensation process and the potential effects of the liquid droplets and streams on the compressor wheel durability combining experimental and theoretical approach. For this purpose, visualization of both the condensate flow and the compressor wheel are performed. Tests are conducted in a flow test rig in which LR-EGR water content is reproduced by water injection on the hot air mass flow.
Technical Paper

Investigation of the Effect of Compression Ratio on the Combustion Behavior and Emission Performance of HVO Blended Diesel Fuels in a Single-Cylinder Light-Duty Diesel Engine

2015-04-14
2015-01-0898
Hydrotreated vegetable oil (HVO) is a renewable high quality paraffinic diesel that can be obtained by the hydrotreating of a wide range of biomass feedstocks, including vegetable oils, animal fats, waste oils, greases and algal oils. HVO can be used as a drop-in fuel with beneficial effects for the engine and the environment. The main objective of this study was to explore the potential of HVO as a candidate bio blendstock for new experimental formulations of diesel fuel to be used in advanced combustion systems at different compression ratios and at high EGR rates in order to conform to the Euro 6 NOx emission standard. The experiments were carried out in a single-cylinder research engine at three steady-state operating conditions and at three compression ratios (CR) by changing the piston.
Technical Paper

Analysis of the Impact of the Dual-Fuel Ethanol-Diesel System on the Size, Morphology, and Chemical Characteristics of the Soot Particles Emitted from a LD Diesel Engine

2014-04-01
2014-01-1613
Nowadays, alcohol fuels are of increasing interest as alternative transportation biofuels even in compression ignition engines because they are oxygenated and producible in a sustainable way. In this paper, the experimental research activity was conducted on a single cylinder research engine provided with a modern architecture and properly modified in a dual-fuel (DF) configuration. Looking at ethanol the as one of the future environmental friendly biofuels experimental campaign was aimed to evaluate in detail the effect of the use of the ethanol as port injected fuel in diesel engine on the size, morphology, reactivity and chemical features of the exhaust emitted soot particles. The engine tests were chosen properly in order to represent actual working conditions of an automotive light-duty diesel engine. A proper engine Dual-Fuel calibration was set-up respecting prefixed limits on in-cylinder peak firing pressure, cylinder pressure rise, fuel efficiency and gaseous emissions.
Technical Paper

Effect of High Levels of Boost and Recirculated Exhaust Gas on Diesel Combustion Characteristics at Part Load

2014-04-01
2014-01-1245
Future diesel combustion systems may operate with significantly higher levels of boost and EGR than used with present systems. The potential benefits of higher boost and EGR were studied experimentally in a single-cylinder diesel engine with capability to adjust these parameters independently. The objective was to study the intake and exhaust conditions with a more optimum combustion phasing to minimize fuel consumption while maintaining proper constraints on emissions and combustion noise. The engine was tested at four part-load operating points using a Design of Experiments (DOE) approach. Two of the operating points correspond to low-speed and low-load conditions relevant for the New European Driving Cycle (NEDC). The other two points focus on medium load conditions representative of the World-wide harmonized Light-duty Test Procedures (WLTP).
Journal Article

Analysis of Nozzle Coking Impact on Emissions and Performance of a Euro5 Automotive Diesel Engine

2013-09-08
2013-24-0127
The present paper reassumes the results of an experimental study focused on the effects of the nozzle injector's coking varying the flow number (FN); the performance and emissions of an automotive Euro5 diesel engine have been analyzed using diesel fuel. As the improvement of the diesel engine performance requires a continuous development of the injection system and in particular of the nozzle design, in the last years the general trend among OEMs is lowering nozzle flow number and, as a consequence, nozzle holes size. The study carried out moves from the consideration that a reduction of the nozzle holes diameter could increase the impact of their coking process. For this purpose, an experimental campaign has been realized, testing the engine in steady state in three partial load operating points, representative of the European homologation driving cycle, and in full load conditions.
Technical Paper

Emission Reduction Technologies for the Future Low Emission Rail Diesel Engines: EGR vs SCR

2013-09-08
2013-24-0087
The EU emission standards for new rail Diesel engines are becoming even more stringent. EGR and SCR technologies can both be used to reduce NOx emissions; however, the use of EGR is usually accompanied by an increase in PM emissions and may require a DPF. On the other hand, the use of SCR requires on-board storage of urea. Thus, it is necessary to study these trade-offs in order to understand how these technologies can best be used in rail applications to meet new emission standards. The present study assesses the application of these technologies in Diesel railcars on a quantitative basis using one and three dimensional numerical simulation tools. In particular, the study considers a 560 kW railcar engine with the use of either EGR or SCR based solutions for NOx reduction. The NOx and PM emissions performances are evaluated over the C1 homologation cycle.
Technical Paper

Analysis of Diesel Injector Nozzle Flow Number Impact on Emissions and Performance of a Euro5 Automotive Diesel Engine

2012-04-16
2012-01-0891
The present paper describes the results of a research project aimed at studying the impact of nozzle flow number on a Euro5 automotive diesel engine, featuring Closed-Loop Combustion Control. In order to optimize the trade-offs between fuel economy, combustion noise, emissions and power density for the next generation diesel engines, general trend among OEMs is lowering nozzle flow number and, as a consequence, nozzle hole size. In this context, three nozzle configurations have been characterized on a 2.0L Euro5 Common Rail Diesel engine, coupling experimental activities performed on multi-cylinder and optical single cylinder engines to analysis on spray bomb and injector test rigs. More in detail, this paper deeply describes the investigation carried out on the multi-cylinder engine, specifically devoted to the combustion evolution and engine performance analysis, varying the injector flow number.
Technical Paper

Impact of Biodiesel on Particle Emissions and DPF Regeneration Management in a Euro5 Automotive Diesel Engine

2012-04-16
2012-01-0839
Biofuel usage is increasingly expanding thanks to its significant contribution to a well-to-wheel (WTW) reduction of greenhouse gas (GHG) emissions. In addition, stringent emission standards make mandatory the use of Diesel Particulate Filter (DPF) for the particulate emissions control. The different physical properties and chemical composition of biofuels impact the overall engine behaviour. In particular, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value (LHV). More specifically, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value, respectively. The particle emissions, in fact, are lower mainly because of the higher oxygen content. Subsequently less frequent regenerations are required.
Technical Paper

Combustion Behaviour and Emission Performance of Neat and Blended Polyoxymethylene Dimethyl Ethers in a Light-Duty Diesel Engine

2012-04-16
2012-01-1053
The combustion behaviour, the mechanisms of soot formation, and the emission performance of a mixture of polyoxymethylene dimethyl ethers (POMDME) oligomers with a number of oxymethylene units ranging from 3 to 5, both neat and blended at 12.5% and 50% levels with commercial diesel fuel have been investigated. The goals were a first evaluation of the POMDME impact on the diesel injector behaviour, on the combustion process as well as on the emission performance of a light duty engine. Then a brief screening on the capability to improve the NOx-PM trade-off using POMDME by means of the exhaust gas recirculation (EGR) rate increment was also assessed.
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