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Technical Paper

24SIAT-0900: Heavy Duty Vehicle Aftertreatment Technologies for the Future: What May Be Required at BSVII?

2024-01-16
2024-26-0149
This paper describes the after-treatment technology that could be used to meet a future BS-VII standard, considering close-coupled SCR (cc-SCR) to help start NOx conversion earlier. Both active (Cu/Fe-SCR based) and passive (V-SCR based) systems have the potential to meet emission limits. V-SCR may be considered in the rear position because V-SCR shows a fast response with very low N2O formation. Next-gen V-SCR technology shows significantly improved performance and durability closer to Cu-SCR. The steady-state NOx conversions over Next-Gen V-SCR were better than BS-VI V-SCR in both fresh and aged-580°C/100h conditions. High durability was also observed after engine aging of 1000h (WHTC + high load). Another big challenge in BS VII could be the PN10 requirement. With enhanced filtration coating (EFC) technology, PN emissions drop drastically in comparison to Euro VI reference without EFC to meet a future BS VII.
Technical Paper

Continuously Varying Exhaust Outlet Diameter to Improve Efficiency and Emissions of a Small SI Natural Gas Two-Stroke Engine by Internal EGR

2018-04-03
2018-01-0985
With continuously increasing concern for the emissions from two-stroke engines including regulated hydrocarbon (HC) and oxides of nitrogen (NOx) emissions, non-road engines are implementing proven technologies from the on-road market. For example, four stroke diesel generators now include additional internal exhaust gas recirculation (EGR) via an intake/exhaust valve passage. EGR can offer benefits of reduced HC, NOx, and may even improve combustion stability and fuel efficiency. In addition, there is particular interest in use of natural gas as fuel for home power generation. This paper examines exhaust throttling applied to the Helmholtz resonator of a two-stroke, port injected, natural gas engine. The 34 cc engine was air cooled and operated at wide-open throttle (WOT) conditions at an engine speed of 5400 RPM with fueling adjusted to achieve maximum brake torque. Exhaust throttling served as a method to decrease the effective diameter of the outlet of the convergent cone.
Technical Paper

After-Treatment Systems to Meet China NS VI, India BS VI Regulation Limits

2017-03-28
2017-01-0941
Future emissions regulations proposed for the Asian automotive industry (BS VI regulations for India and NS VI regulations for China) are strict and similar to EU VI regulations. As a result, they will require both advanced NOx control as well as advanced Particulate Matter (PM) control. This will drive implementation of full Catalyzed Diesel Particulate Filter (cDPF) and simultaneous NOx control using Selective Catalytic Reduction (SCR) technologies. In this work, we present the performance of various Diesel Oxidation Catalyst (DOC), cDPF, SCR and Ammonia slip catalyst (ASC) systems utilizing the World Harmonized Transient Cycle (WHTC). Aftertreatment Systems (ATS) required for both active and passive filter regeneration applications will be discussed. The sensitivity of key design parameters like catalyst technology, PGM loading, catalyst sizing to meet the regulation limits has been investigated.
Technical Paper

Heavy Duty Diesel Engine Emission Control to Meet BS VI Regulations

2017-01-10
2017-26-0125
The next generation advanced emission regulations have been proposed for the Indian heavy duty automotive industry for implementation from 2020. These BS VI emission regulations will require both advanced NOx control as well as advanced PM (Particulate Matter) control along with Particle Number limitations. This will require implementation of full DPF (Diesel Particulate Filter) and simultaneous NOx control using SCR technologies. DPF technologies have already been successfully implemented in Euro VI and US 10 HDD systems. These systems use low temperature NO2 based passive DPF regeneration as well as high temperature oxygen based active DPF regeneration. Effective DPF and DOC designs are essential to enable successful DPF regeneration (minimize soot loading in the DPF) while operating HDD vehicles under transient conditions. DOC designs are optimized to oxidize engine out NO into NO2, which helps with passive DPF regeneration.
Journal Article

Development of Emission Control Systems to Enable High NOx Conversion on Heavy Duty Diesel Engines

2015-04-14
2015-01-0992
Selective Catalytic Reduction (SCR) systems have been demonstrated as effective solutions for controlling NOx emissions from Heavy Duty diesel engines. Future HD diesel engines are being designed for higher engine out NOx to improve fuel economy, while discussions are in progress for tightening NOx emissions from HD engines post 2020. This will require increasingly higher NOx conversions across the emission control system and will challenge the current aftertreatment designs. Typical 2010/2013 Heavy Duty systems include a diesel oxidation catalyst (DOC) along with a catalyzed diesel particulate filter (CDPF) in addition to the SCR sub-assembly. For future aftertreatment designs, advanced technologies such as cold start concept (dCSC™) catalyst, SCR coated on filter (SCRF® hereafter referred to as SCR-DPF) and SCR coated on high porous flow through substrates can be utilized to achieve high NOx conversions, in combination with improved control strategies.
Technical Paper

Demonstration of SCR on a Diesel Particulate Filter System on a Heavy Duty Application

2015-04-14
2015-01-1033
Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. Typical 2013 Heavy Duty Diesel emission control systems include a DOC upstream of a catalyzed soot filter (CSF) which is followed by urea injection and the SCR sub-assembly. There is a strong desire to further increase the NOx conversion capability of such systems, which would enable additional fuel economy savings by allowing engines to be calibrated to higher engine-out NOx levels. One potential approach is to replace the CSF with a diesel particulate filter coated with SCR catalysts (SCRF® technology, hereafter referred to as SCR-DPF) while keeping the flow-through SCR elements downstream, which essentially increases the SCR volume in the after-treatment assembly without affecting the overall packaging.
Journal Article

Development of SCR on High Porosity Substrates for Heavy Duty and Off-Road Applications

2014-04-01
2014-01-1521
Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. There is a drive to reduce the overall packaging volume of the aftertreatment system for these applications. In addition, more active SCR catalysts will be needed as the applications become more challenging: e.g. lower temperatures and higher engine out NOx, for fuel consumption improvements. One approach to meet the challenges of reduced volume and/or higher NOx reduction is to increase the active site density of the SCR catalyst by coating higher amount of SCR catalyst on high porosity substrates (HPS). This approach could enable the reduction of the overall packaging volume while maintaining similar NOx conversion as compared to 2010/2013 systems, or improve the NOx reduction performance for equivalent volume and NH3 slip.
Technical Paper

Development of Emission Control Systems to Enable High NOx Conversion on Heavy Duty Diesel Engines

2014-04-01
2014-01-1525
Selective Catalytic Reduction (SCR) systems have been demonstrated as effective solutions for controlling NOx emissions from Heavy Duty diesel engines. Future HD diesel engines are being designed for higher engine out NOx to improve fuel economy, which will require increasingly higher NOx conversion to meet emission regulations. For future aftertreatment designs, advanced technologies such as SCR coated on filter (SCRF®) and SCR coated on high porous flow through substrates can be utilized to achieve high NOx conversion. In this work, different options were evaluated for achieving high NOx conversion. First, high performance NOx control catalysts were designed by using SCRF unit followed by additional SCR on high porosity substrates. Second, different control strategies were evaluated to understand the effect of reductant dosing strategy and thermal management on NOx conversion. Tests were carried out on a HD engine under transient test cycles.
Technical Paper

Chassis Dynamometer Emissions Characterization of a Urea-SCR Transit Bus

2012-06-01
2011-01-2469
West Virginia University characterized the emissions and fuel economy performance of a 30-foot 2010 transit bus equipped with urea selective catalytic reduction (u-SCR) exhaust aftertreatment. The bus was exercised over speed-time driving schedules representative of both urban and on-highway activity using a chassis dynamometer while the exhaust was routed to a full-scale dilution tunnel with research grade emissions analyzers. The Paris speed-time driving schedule was used to represent slow urban transit bus activity while the Cruise driving schedule was used to represent on-highway activity. Vehicle weights representative of both one-half and empty passenger loading were evaluated. Fuel economy observed during testing with the urban driving schedule was significantly lower (55%) than testing performed with the on-highway driving schedule.
Journal Article

Diesel Exhaust Aftertreatment with Scrubber Process: NOx Destruction

2012-05-15
2011-01-2440
Oxides of nitrogen (NOx) emissions, produced by engines that burn fuels with atmospheric air, are known to cause negative health and environmental effects. Increasingly stringent emissions regulations for marine engines have caused newer engines to be developed with inherent NOx reduction technologies. Older marine engines typically have a useful life of over 20 years and produce a disproportionate amount of NOx emissions when compared with their newer counterparts. Wet scrubbing as an aftertreatment method for emissions reduction was applied to ocean-going marine vessels for the reduction of sulfur oxides (SOx) and particulate matter (PM) emissions. The gaseous absorption process was explored in the laboratory as an option for reducing NOx emissions from older diesel engines of harbor craft operating in ports of Houston and Galveston. A scrubber system was designed, constructed, and evaluated to provide the basis for a real-world design.
Technical Paper

Relationship between Carbon Monoxide and Particulate Matter Levels across a Range of Engine Technologies

2012-04-16
2012-01-1346
Relationships between diesel particulate matter (PM) mass and gaseous emissions mass produced by engines have been explored to determine whether any gaseous species may be used as surrogates to infer PM quantitatively. It was recognized that sulfur content of fuel might independently influence PM mass, since PM historically is composed of elemental carbon, organic carbon, sulfuric acid, ash and wear particles. Previous research has suggested that PM may be correlated with carbon monoxide (CO) for an engine that is exercised through a variety of speed and load cycles, but that the correlation does not extend to a group of engines. Large databases from the E-55/59 and Gasoline/Diesel PM Split programs were employed, along with the IBIS bus emissions database and several additional data sets for on- and off-road engines to examine possible relationships.
Journal Article

Development of SCR on Diesel Particulate Filter System for Heavy Duty Applications

2011-04-12
2011-01-1312
Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. Typical 2010 Heavy-Duty systems include a DOC along with a catalyzed soot filter (CSF) in addition to the SCR sub-assembly. There is a strong desire to further increase the NOx conversion capability of such systems, to enable additional fuel economy savings by allowing engines to be calibrated to higher engine-out NOx levels. One potential approach is to replace the CSF with a diesel particulate filter coated with SCR catalysts (SCR-DPF) while keeping the flow-through SCR elements downstream, which essentially increases the SCR volume in the after-treatment assembly without affecting the overall packaging. In this work, a system consisting of SCR-DPF was evaluated in comparison to the DOC + CSF components from a commercial 2010 DOC + CSF + SCR system on an engine with the engine EGR on (standard engine-out NOx) and off (high engine-out NOx).
Journal Article

An Evaluation of Particle Size Distributions and Particle Number-Based Reductions from Various PM Emission Control Technologies

2011-04-12
2011-01-0600
For diesel emission control technologies, reduction efficiencies of Particulate Matter (PM) control systems have been traditionally reported based on mass-based criteria. However, particle number-based criteria are now receiving increased attention. In this paper, results of real-time particle size distribution and number based evaluation of the effectiveness of multiple PM control technologies are reported on an HDD engine. An Engine Exhaust Particle Sizer (EEPS) was used for comparative analysis. The technologies that were evaluated included diesel oxidation catalysts (DOC), a DOC with an uncatalyzed wall-flow filter as a continuously regenerating diesel particulate filter (CR-DPF) system, a DOC with a catalytically coated wall-flow filter as a catalyzed CR-DPF (CCR-DPF), and a DOC with a partial filter as a continuously regenerating partial filter (CR-PF).
Technical Paper

Engine Performance of Cu- and Fe-Based SCR Emission Control Systems for Heavy Duty Diesel Applications

2011-04-12
2011-01-1329
Since early 2010, most new medium- and heavy-duty diesel vehicles in the US rely on urea-based Selective Catalytic Reduction (SCR) technology for meeting the most stringent regulations on nitrogen oxides (NOx) emissions in the world today. Catalyst technologies of choice include Copper (Cu)- and Iron (Fe)-based SCR. In this work, the performances of Fe-SCR and Cu-SCR were investigated in the most commonly used DOC + CSF + SCR system configuration. Cu-SCR offered advantages over Fe-SCR in terms of low temperature conversion, NO₂:NOx ratio tolerance and NH₃ slip, while Fe-SCR demonstrated superior performance under optimized NO₂:NOx ratio and at higher temperatures. The Cu-SCR catalyst displayed less tolerance to sulfur (S) exposure. Reactor testing has shown that Cu-SCR catalysts deactivate at low temperature when poisoned by sulfur.
Technical Paper

Modeling and Validation of an Over-the-Road Truck

2010-10-05
2010-01-2001
Heavy-duty trucks are an important sector to evaluate when seeking fuel consumption savings and emissions reductions. With fuel costs on the rise and emissions regulations becoming stringent, vehicle manufacturers find themselves spending large amounts of capital improving their products in order to be compliant with regulations. The Powertrain System Analysis Toolkits (PSAT), developed by the Argonne National Laboratory (ANL), is a simulation tool that helps mitigate costs associated with research and automotive system design. While PSAT has been widely used to predict the fuel consumption and exhaust emissions of conventional and hybrid light-duty vehicles, it also may be employed to test heavy-duty vehicles. The intent of this study was to develop an accurate model that predicts emissions and fuel economy for heavy-duty vehicles for use within PSAT.
Technical Paper

Comparative Emissions from Diesel and Biodiesel Fueled Buses from 2002 to 2008 Model Years

2010-10-05
2010-01-1967
Fuel economy and regulated emissions were measured from eight forty-foot transit buses operated on petroleum diesel and a “B20” blend of 80% diesel fuel and 20% biodiesel by volume. Use of biodiesel is attractive to displace petroleum fuel and reduce an operation's carbon footprint. Usually it is assumed that biodiesel will also reduce particulate matter (PM) emissions relative to those of petroleum diesel. Model years of the vehicles evaluated were newer 2007-08 Gillig low-floor buses, 2005 Gillig Phantom buses, and a 2002 Gillig Phantom bus. Engine technology represented three different emissions standards, and included buses with OEM diesel particulate filters. Each bus was evaluated using two transient speed-time schedules, the Orange County Transit Authority (OCTA) driving schedule which represents moderate speed urban/suburban operation and the Urban Dynamometer Driving Schedule (UDDS) which represents a mix of suburban and higher speed on-highway operation.
Technical Paper

Biodiesel Blend Emissions of a 2007 Medium Heavy Duty Diesel Truck

2010-10-05
2010-01-1968
Biodiesel may be derived from either plant or animal sources, and is usually employed as a compression ignition fuel in a blend with petroleum diesel (PD). Emissions differences between vehicles operated on biodiesel blends and on diesel have been published previously, but data do not cover the latest engine technologies. Prior studies have shown that biodiesel offers advantages in reducing particulate matter, with either no advantage or a slight disadvantage for oxides of nitrogen emissions. This paper describes a recent study on the emissions impact of two biodiesel blends B20A, made from 20% animal fat (tallow) biodiesel and 80% PD, and B20B, obtained from 20% soybean biodiesel and 80% PD. These blends used the same PD fuel for blending and were contrasted with the same PD fuel as a reference. The research was conducted on a 2007 medium heavy-duty diesel truck (MHDDT), with an engine equipped with Exhaust Gas Recirculation (EGR) and a Diesel Particulate Filter (DPF).
Technical Paper

Nano Particulate Matter Evolution in a CFR1065 Dilution Tunnel

2009-11-02
2009-01-2672
Dual primary full-flow dilution tunnels represent an integral part of a heavy-duty transportable emissions measurement laboratory designed and constructed to comply with US Code of Federal Regulations (CFR) 40 Part 1065 requirements. Few data exist to characterize the evolution of particulate matter (PM) in full scale dilution tunnels, particularly at very low PM mass levels. Size distributions of ultra-fine particles in diesel exhaust from a naturally aspirated, 2.4 liter, 40 kW ISUZU C240 diesel engine equipped with a diesel particulate filter (DPF) were studied in one set of standard primary and secondary dilution tunnels with varied dilution ratios. Particle size distribution data, during steady-state engine operation, were collected using a Cambustion DMS500 Fast Particulate Spectrometer. Measurements were made at four positions that spanned the tunnel cross section after the mixing orifice plate for the primary dilution tunnel and at the outlet of the secondary dilution tunnel.
Technical Paper

Emissions from a Legacy Diesel Engine Exercised through the ACES Engine Test Schedule

2008-06-23
2008-01-1679
Most transient heavy duty diesel emissions data in the USA have been acquired using the Federal Test Procedure (FTP), a heavy-duty diesel engine transient test schedule described in the US Code of Federal Regulations. The FTP includes both urban and freeway operation and does not provide data separated by driving mode (such as rural, urban, freeway). Recently, a four-mode engine test schedule was created for use in the Advanced Collaborative Emission Study (ACES), and was demonstrated on a 2004 engine equipped with cooled Exhaust Gas Recirculation (EGR). In the present work, the authors examined emissions using these ACES modes (Creep, Cruise, Transient and High-speed Cruise) and the FTP from a Detroit Diesel Corporation (DDC) Series 60 1992 12.7 liter pre-EGR engine. The engine emissions were measured using full exhaust dilution, continuous measurement of gaseous species, and filter-based Particulate Matter (PM) measurement.
Journal Article

Summary of In-use NOx Emissions from Heavy-Duty Diesel Engines

2008-04-14
2008-01-1298
As part of the 1998 Consent Decrees concerning alternative ignition strategies between the six settling heavy-duty diesel engine manufacturers and the United States government, the engine manufacturers agreed to perform in-use emissions measurements of their engines. As part of the Consent Decrees, pre- (Phase III, pre-2000 engines) and post- (Phase IV, 2001 to 2003 engines) Consent Decree engines used in over-the-road vehicles were tested to examine the emissions of oxides of nitrogen (NOx) and carbon dioxide (CO2). A summary of the emissions of NOx and CO2 and fuel consumption from the Phase III and Phase IV engines are presented for 30 second “Not-to-Exceed” (NTE) window brake-specific values. There were approximately 700 Phase III tests and 850 Phase IV tests evaluated in this study, incorporating over 170 different heavy duty diesel engines spanning 1994 to 2003 model years. Test vehicles were operated over city, suburban, and highway routes.
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