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The effect of biodiesel on the Particulate emissions is gaining significant attention particularly with the drive for the use of alternative fuels. The particulate matter (PM), especially having a diameter less than 50 nm called the Nanoparticles or Nucleation mode particles (NMPs), has been raising concerns about its effect on human health. To better understand the effect of biodiesel and its blends on particulate emissions, steady state tests were conducted on a small-bore single-cylinder high-speed direct-injection research diesel engine. The engine was fueled with Ultra-Low Sulfur Diesel (ULSD or B-00), a blend of 20% soy-derived biodiesel and 80% ULSD on volumetric basis (B-20), B-40, B-60, B-80 and 100% soy-derived biodiesel (B-100), equipped with a common rail injection system, EGR and swirl control systems at a load of 5 bar IMEP and constant engine speed of 1500 rpm.

Fuel wall impingement commonly occurs in small-bore diesel engines. Particularly during engine starting, when wall temperatures are low, the evaporation rate of fuel film remaining from previous cycles plays a significant role in the autoignition process that is not fully understood. Pre-injection chemiluminescence (PIC), resulting from low-temperature oxidation of evaporating fuel film and residual gases, was measured over 3200 μsec intervals at the end of the compression strokes, but prior to fuel injection during a series of starting sequences in an optical diesel engine. These experiments were conducted to determine the effect of this parameter on combustion phasing and were conducted at initial engine temperatures of 30, 40, 50 and 60°C, at swirl ratios of 2.0 and 4.5 at 1000 RPM. PIC was determined to increase and be highly correlated with combustion phasing during initial cycles of the starting sequence.

Ultraviolet chemiluminescence has been observed in a diesel engine cyclinder during compression, but prior to fuel injection under engine starting conditions. During a portion of the warm-up sequence, the intensity of this emission exhibits a strong correlation to the phasing of the subsequent combustion. Engine exhaust measurements taken from a continuously misfiring, motored engine confirm the generation of formaldehyde (HCHO) in such processes. Fractions of this compound are expected to be recycled as residual to participate in the following combustion cycle. Spectral measurements taken during the compression period prior to fuel injection match the features of Emeleus' cool flame HCHO bands that have been observed during low temperature heat release reactions occurring in lean HCCI combustion. That the signal from the OH* bands is weak implies a buildup of HCHO during compression.

One of the most challenging problems in diesel engines is to reduce unburned HC emissions that appear as (white smoke) during cold starting. In this paper the research is carried out on a 4-cylinder diesel engine with a common rail fuel injection system, which is able to deliver multiple injections during cold start. The causes of combustion failure at lower temperature limits are investigated theoretically by considering the rate of heat release. The results of this clearly indicate that in addition to low cranking engine speed, heat transfer and blow-by losses at lower ambient temperatures, fuel injection events would contribute to the failure of combustion. Also, combustion failure takes place when the compression temperature is lower than some critical value. Based on these results, split-main injection strategy was applied during engine cold starting and validated by experiments in a cold room at lower ambient temperatures.

Combustion instability and white smoke emissions are serious problems during cold starting of diesel engines. In this investigation, a model has been applied to predict misfiring based on an analysis of the autoignition process. The effect of injection timing on combustion instability during the cold start transient, at different ambient temperatures is investigated, both theoretically and experimentally. Maps have been developed to show the zones where misfiring would occur. The experimental work was conducted on a direct injection heavy-duty diesel engine in a cold room. The room temperature covered a range from 21 ° C to -10 ° C. The cycle-by-cycle data analysis was made and results plotted on the developed maps. The experimental results correlated fairly well with the model prediction. Based on the analysis, a new strategy for cold starting can be developed to reduce combustion instability and white smoke emissions.

A new formulation is developed for the ignition delay (ID) in diesel engines to account for the effect of piston motion on the global autoignition reaction rates. A differentiation is made between the IDe measured in engines and IDv, measured in constant volume vessels. In addition, a method is presented to determine the coefficients of the IDe correlation from actual engine experimental data. The new formulation for IDe is applied to predict the misfiring cycles during the cold starting of diesel engines at different low ambient temperatures. The predictions are compared with experimental results obtained on a multi-cylinder heavy-duty diesel engine.

Engine-out HC emissions were investigated during cold and hot starts. The tests were conducted at room temperature, on a new Chrysler 2.4-L, 4-cylinder, 16-valve, DOHC, multipoint-port-fuel-injection gasoline engine. Real time engine-out HC emissions were measured using Cambustion Fast Response Flame Ionization Detector (FRFID). Sources of unburned hydrocarbon emissions were discussed in details. Unburned hydrocarbons emitted during the cold-start were much higher than the hot-start. Cylinder-to-cylinder variation was investigated. A fuel inventory program was used to characterize total injected fuel, burned fuel, unburned HC, and fuel unaccounted for (mainly accumulated fuel in the engine system and CO). A fuel interrupt test was run to examine the possibility of burning the leftover fuel after the fuel shut-off. The contribution of the cold and hot start modes in engine-out HC emissions was determined.

A long-distance microscope with pulse-laser as optical shutter up to 25kHz was used to magnify the diesel spray at the nozzle hole vicinity onto 35-mm photographic film through a still or a high-speed drum camera. The injectors examined are high-pressure valve-covered-orifice (VCO) nozzles, from unit injector and common rail injection systems. For comparison, a mini-sac injector from a hydraulic unit injector is also investigated. A phase-Doppler particle analyzer (PDPA) system with an external digital clock was also used to measure the droplet size, velocity and time of arrival relative to the start of the injection event. The visualization results provide very interesting and dynamic information on spray structure, showing spray angle variations, primary breakup processes, and spray asymmetry not observed using conventional macroscopic visualization techniques.

An experimental and numerical study was carried out to simulate the diesel spray behavior during cold starting conditions inside two single-cylinder optically accessible engines. One is an AVL single-cylinder research diesel engine converted for optical access; the other is a TACOM/LABECO engine retrofitted with mirror-coupled endoscope access. The first engine is suitable for sophisticated optical diagnostics but is constrained to limited consecutive fuel injections or firings. The second one is located inside a micro-processor controlled cold room; therefore it can be operated under a wide range of practical engine conditions and is ideal for cycle-to-cycle variation study. The intake and blow-by flow rates are carefully measured in order to clearly define the operation condition. In addition to cylinder pressure measurement, the experiment used 16-mm high-speed movie photography to directly visualize the global structures of the sprays and ignition process.

The UBHC emissions during cold starting need to be controlled in order to meet the future stringent standards. This requires a better understanding of the characteristics of the time resolved UBHC signal measured by a high frequency FID and its phasing with respect to the valve events. The computer program supplied with the instrument and currently used to compute the phase shift has many uncertainties due to the unsteady nature of engine operation during starting. A new technique is developed to measure the in-situ phase shift of the UBHC signal under the transient thermodynamic and dynamic conditions of the engine. The UBHC concentration is measured at two locations in the exhaust manifold of one cylinder in a multicylinder port injected gasoline engine. The two locations are 77 mm apart. The downstream probe is positioned opposite to a solenoid-operated injector which delivers a gaseous jet of hydrocarbon-free nitrogen upon command.

The instantaneous frictional torque (IFT) of the engine and the piston-ring assembly frictional force (PRAFF) were determined during cranking and starting of a direct injection single cylinder diesel engine. The measurements included the cylinder gas pressure, the instantaneous torque of the electric starter, the angular velocity of the crankshaft and the axial force on the connecting rod. The engine and piston friction were determined every crank angle degree for all the cycles from the time the starter was engaged to the time the engine reached the idling speed. The data was analyzed and a comparison was made between the friction in successive cycles.

Combustion instability is investigated during the cold starting of a single cylinder, direct injection, 4-stroke-cycle, air-cooled diesel engine. The experiments covered fuels of different properties at different ambient air temperatures and injection timings. The analysis showed that the pattern of misfiring (skipping) is not random but repeatable. The engine may skip once (8-stroke-cycle operation) or twice (12-stroke-cycle operation) or more times. The engine may shift from one mode of operation to another and finally run steadily on the 4-stroke cycle. All the fuels tested produced this type of operation at different degrees. The reasons for the combustion instability were analyzed and found to be related to speed, residual gas temperature and composition, accumulated fuel and ambient air temperature.

A method to calculate white smoke during starting was developed using a total balance of fuel injected and fuel burned. An accurate needle lift sensor with an in situ calibration was designed and used to measure cyclic fuel injection. The effects of ambient temperature, fuel type, injection timing and the number of repeated starting attempts were studied with regard to white smoke formation, cyclic fuel injection and fuel burned. It was found that the colder the ambient temperature, the less unburned fuel was emitted to the atmosphere due to the decrease in cyclic fuel injection. The more volatile the fuel, the easier it was to start the engine at low temperatures, and the less white smoke was produced. Earlier timing of fuel injection during starting resulted in an increased likelihood of engine starting and less white smoke formation.

Combustion in a diesel engine during cold starting under normal and border-line conditions was investigated. Experiments were conducted on a single cylinder, air-cooled, 4-stroke-cycle engine in a cold room. Tests covered different fuels, injection timings and ambient temperatures. Motoring tests, without fuel injection indicated that the compression pressure and temperature are dependent on the ambient temperature and cranking speeds. The tests with JP-5, with a static injection timing of 23° BTDC indicated that the engine may operate on the regular 4-stroke-cycle at normal operating ambient temperatures or may skip one cycle before each firing at moderately low temperatures, i.e. operate on an 8-stroke-cycle mode. At lower temperatures the engine may skip two cycles before each firing cycle, i.e. operate on a 12-stroke-cycle mode. These modes were reproducible and were found to depend mainly on the ambient temperature.

A mathematical model Is developed to study the transient behavior of a four-stroke, single cylinder naturally-aspirated, DI diesel engine during cranking and starting. The model simulates the full thermodynamic cycle of the engine and includes detailed sub-models for the intake and exhaust gas flow processes, autoignition combustion, heat transfer, mechanical friction, blowby, and engine dynamics. The model considers the period of time from starter on until the engine reaches the idle speed. Experimental data and results obtained from the engine are used to calibrate and validate the model. A comparison of results from the model and the experiments generally show good agreement for the starting conditions investigated.

Many problems can develop from the uncontrolled fuel injection during cranking and starting of diesel engines. Some of the problems are related to excessive wear as a result of the high peak pressures reached upon combustion after misfiring, the relatively low rotating speeds and the lack of formation of a lubricating oil film between the interacting surfaces. Another problem is the emission of high amounts of unburned hydrocarbons and white smoke. Experimental results are given for a single cylinder and a multicylinder diesel engine, for the instantaneous angular velocity and cylinder pressures from the starter-on point until the engine fires. The causes of misfiring during cranking are investigated. The role of the increased blow-by gases on the autoignition process at the low cranking speeds is analyzed both analytically and experimentally. The contribution of the instantaneous angular velocity at the time of injection, on the autoignition process is investigated.