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Nowadays, the push for more ecological low-carbon propulsion systems is high in all mobility sectors, including the recreational or light-commercial boating, where propulsion is usually provided by internal combustion engines derived from road applications. In this work, the effects of replacing conventional fossil-derived B7 diesel with Hydrotreated Vegetable Oil (HVO) were experimentally investigated in a modern Medium-Duty Engine, using the advanced biofuel as drop-in and testing according to the ISO 8178 marine standard. The compounded results showed significant benefits in terms of NOx, Soot, mass fuel consumption and WTW CO2 thanks to the inner properties of the aromatic-free, hydrogen-rich renewable fuel, with no impact on the engine power and minimal deterioration of the volumetric fuel economy.

High cycle-to-cycle variations (CTCV) in a Hydrogen-Fueled Internal Combustion Engine (H2-ICE), especially in the lean-burn condition, not only lower the engine’s efficiency but also increase emissions and torque variations. High CTCV are mainly due to the variations in: mixture motion within the cylinder at the time of spark, amount of air and fuel fed to the cylinder, and mixing of the fresh mixture and residual gases within the cylinder during each cycle. In this article, multiple cycle-based methodologies were compared and analyzed specifically for H2-ICEs based on systematic experimentation. The experimental test campaign was performed on a Port Fuel Injection (PFI) H2-ICE designed by PUNCH Torino and data is processed with MATLAB. A MATLAB code is also proposed as a tool for comparing multiple methodologies for the analysis of CTCV specifically for H2-ICE.

Given the spread of natural gas engines in low-term toward decarbonization and the growing interest in gaseous mixtures as well as the use of hydrogen in Heavy-Duty (HD) engines, appropriate strategies are needed to maximize thermal efficiency and achieve near-zero emissions from these propulsor systems. In this context, some phenomena related to real-world driving operations, such as engine cut-off or misfire, can lead to inadequate control of the Air-to-Fuel ratio, key factor for Three-Way Catalyst (TWC) efficiency. Goal of the present research activity is to investigate the performance of a bio-methane-fueled HD engine and its Aftertreatment System (ATS), consisting of a Three-Way Catalyst, at different Air-to-Fuel ratio. An experimental test bench characterization, in different operating conditions of the engine workplan, was carried out to evaluate the catalyst reactivity to a defined pattern of the Air-to-Fuel ratio.

Predicting and preventing combustion anomalies leads to safe and efficient operation of the hydrogen internal combustion engine. This research presents the application of three machine learning (ML) models – K-Nearest Neighbors (KNN), Random Forest (RF) and Logistic Regression (LR) – for the prediction of combustion anomalies in a hydrogen internal combustion engine. A small experimental dataset was used to train the models and posterior experiments were used to evaluate their performance and predicting capabilities (both in operating points -speed and load- within the training dataset and operating points in other areas of the engine map). KNN and RF exhibit superior accuracy in classifying combustion anomalies in the training and testing data, particularly in minimizing false negatives, which could have detrimental effects on the engine.

The present paper reports experimental and numerical research activities devoted to deeply characterize the behavior and performance of a Heavy Duty (HD) internal combustion engine fed by compressed natural gas (CNG). Current research interest in HD engines fed by gaseous fuels with low C/H ratios is related to the well-known potential of such fuels in reducing carbon dioxide emissions, combined to extremely low particulate matter emissions too. Moreover, methane, the main CNG component, can be produced through alternative processes relying on renewable sources, or in the next future replaced by methane/H2 blends. The final goal of the presented investigations is the development of a predictive 0D combustion submodel within the framework of a 1D numerical simulation platform.

Methanol is currently being evaluated as a promising alternative fuel for internal combustion engines, due to being attainable by carbon neutral or negative pathways (renewable energy and carbon capture technology). The low ignitability of methanol has made it attractive mostly as a fuel for spark ignition engines, however the low sooting properties of the fuel could potentially reduce the NOx-soot tradeoff present in compression ignition engines. In this work, using a 4-cylinder engine with compression ratio modified from 16:1 to 19:1, methanol combustion is evaluated under five operating conditions in terms of fuel consumption, criteria pollutants, CO2 emissions and engine efficiency in addition to the qualitative assessment of the combustion stability. It was found that combustion is stable at medium to high loads, with medium load NOx emissions levels at least 30% lower than the original diesel engine and comparable emissions at maximum load conditions.

The urban mobility electrification has been proposed as the main solution to the vehicle emission issues in the next years. However, internal combustion engines have still great potential to decarbonize the transport sector through the use of low/zero-carbon fuels. Alcohols such us methanol, have long been considered attractive alternative fuels for spark ignition engines. They have properties similar to those of gasoline, are easy to transport and store. Recently, great attention has been devoted to gaseous fuels that can be used in existing engine after minor modification allowing to drastically reduce the pollutant emissions. In this regard, this study tries to provide an overview on the use of alternative fuels, both liquid and gaseous in spark ignition engines, highlighting the benefits as well as the criticalities. The investigation was carried out on a small displacement spark ignition engine capable to operate both in port fuel and direct injection mode.

The forthcoming introduction of the EURO VII regulation requires urgent strategies and solutions for the reduction of sub-23 nm particle emissions. Although they have been historically considered as particulate matter-free, the high interest for Natural Gas (NG) Heavy-Duty engines in the transport sector, demands their compliance with the new proposed regulations. In order to obtain high conversion of gas pollutants and a strong abatement of the emitted particles, the use of Particle Filters in NG aftertreatment (CPF) in conjunction with the Three-Way Catalyst (TWC) may represent an attractive and feasible solution. Performances of a cordierite filter were explored through an extensive experimental campaign both in Steady-State conditions and during transient engine maneuvers that involved a whole analysis of the emitted particles in terms of number and mass.

Hydrogen Internal Combustion Engines (H2-ICEs) are subject to increased attention thanks to their extremely low criteria pollutant emission and near-zero CO2 tailpipe emissions. However, to further minimize exhaust emissions and increase the efficiency of a H2-ICE, it is important to carefully control the relative air-fuel ratio of operation, i.e. Lambda (λ), which will lead in turn to an optimal combustion process. The precise λ control mainly relies upon the methodology to calculate λ on board of the engine, where the availability of reliable sensors specifically-developed for hydrogen combustion is currently limited. In this article, a comparative analysis of different methodologies for the calculation of λ is performed, comparing four methodologies: exhaust gas analysis through a Spindt-Brettschneider approach (λEMI), raw Universal Exhaust Gas Oxygen (λR-UEGO), processed Universal Exhaust Gas Oxygen (λP-UEGO) and speed-density (λSD) outputs.

Increasingly stringent pollutant and CO2 emission standards require the car manufacturers to investigate innovative solutions to further improve the fuel economy and environmental impact of their fleets. Nowadays, NOx emissions standards are stringent for spark-ignition (SI) internal combustion engines (ICEs) and many techniques are investigated to limit these emissions. Among these, an extremely lean combustion has a large potential to simultaneously reduce the NOx raw emissions and the fuel consumption of SI ICEs. Engines with pre-chamber ignition system are promising solutions for realizing a high air-fuel ratio which is both ignitable and with an adequate combustion speed. In this work, the combustion characteristics of an active pre-chamber system are experimentally investigated using a single-cylinder research engine. The engine under exam is a large bore heavy-duty unit with an active pre-chamber fuelled with compressed natural gas.

Direct injection spark ignition engines represent an effective technology to achieve the goal of carbon dioxide emission reduction. Further reduction of the carbon footprint can be achieved by using carbon-neutral fuels. Oxygenated alcohols are well consolidated fuels for spark ignition engines providing also the advantages of knock resistance and low soot tendency production. Methanol and ethanol are possible candidates as alternative fuels to gasoline due to their similar properties. In this study a blend at 25 % v/v of ethanol in gasoline (E25) and a blend with 80% gasoline, 5 % v/v ethanol and 15% v/v of methanol (GEM) were tested. These blends were considered since E25 is already available at fuel pump in some countries. The GEM blend, instead, could represent a valid alternative in the next future. Experiments were carried out on a high performance, turbocharged 1.8 L direct injection spark ignition engine over the Worldwide Harmonized Light Vehicles Test Cycle.

De-fossilization is an increasingly important trend in the energy sector. In the transport sector the de-fossilization efforts have been centered in promoting the electrification of vehicles, nonetheless other pathways, like the use of carbon neutral or carbon-offsetting fuels under current vehicle fleets, are also worth considering. Low-carbon fuels (LCF) can be synthetized from sources that can take advantage of the carbon already present in the atmosphere (either by technologies like direct carbon capture or biological processes like photosynthesis in biofuels) and use energy from renewable sources for the necessary industrial processes. Although, LCFs can be compared to fossil fuels as energy sources for internal combustion engines, their composition is not the same and their properties can modify the engine combustion and emissions.

In the recent years, the interest in heavy-duty engines fueled with Compressed Natural Gas (CNG) is increasing due to the necessity to comply with the stringent CO2 limitation imposed by national and international regulations. Indeed, the reduced number of carbon atoms of the NG molecule allows to reduce the CO2 emissions compared to a conventional fuel. The possibility to produce synthetic methane from renewable energy sources, or bio-methane from agricultural biomass and/or animal waste, contributes to support the switch from conventional liquid fuels to CNG. To drive the engine development and reduce the time-to-market, the employment of numerical analysis is mandatory. This requires a continuous improvement of the simulation models toward real predictive analyses able to reduce the experimental R&D efforts. In this framework, 1D numerical codes are fundamental tools for system design, energy management optimization, and so on.

Aiming at meeting the stringent regulations imposed by the EU and other legislators in the transport sector, various advanced combustion modes for Internal Combustion Engines (ICEs) are currently under investigation. Among those, Homogeneous Charge Compression Ignition (HCCI) appears a promising solution, simultaneously reducing pollutant emission and enhancing thermal efficiency. Hence, to simulate HCCI combustion mode, a general multi-zone model has been developed and implemented through user coding into a commercial software (GT-Power™). This model is based on a control mass Lagrangian multi-zone approach, and it incorporates a procedure based on an off-line tabulation of chemical kinetics (Tabulated Kinetic of Ignition - TKI). It performs an accurate and fast prediction of the air/fuel mixture auto-ignition, combining the accuracy of detailed chemistry with a lighter computational effort.

Natural gas as an internal combustion engine fuel is taking a predominant role as a mid-term solution to pollution due to combustion driven human activities both in the energy and transport sectors. Engine researchers and manufacturers are in the process of investigating and improving strategies that decrease emissions and fuel consumption, without compromising engine performance and efficiency; active pre-chamber configurations are to be accounted for as one of these. A relatively small amount of fuel (up to 10 % of the total fuel-energy requirement) is introduced in the confined volume of the pre-chamber and forms a close-to-stoichiometric mixture with fresh charge that is introduced from the main combustion chamber during the compression stroke. After spark-ignition the products of this early stage of combustion can ignite ultra-lean mixtures (with λ up to 2) through the Turbulent Jet Ignition mechanism, hence reducing fuel consumption as well as noxious emissions such as NOx.

In view of the new emission regulations seeking to lower the particle cut-off size down to the current 23 nm, an extensive comprehension on the nature of sub-23 nm particles is crucial. In this regard, a new challenge lies ahead considering an even more massive use of biofuels. The objective of this research study was to characterize the sub-23 nm particles and to evaluate their volatile organic fraction (VOF) from a high performance, 1.8 L gasoline direct injection (GDI) engine under the Worldwide harmonized Light vehicles Test Cycle (WLTC). Particle emissions were measured through an Engine Exhaust Particle Sizer (EEPS) capable of particle sizing and counting in the range 5.6 - 560 nm. The sampling and conditioning were performed by both a single diluter and the Dekati Engine Exhaust Diluter (DEED) a Particle Measurement Programme (PMP) compliant sample conditioning system.

In recent years, internal combustion engine (ICE) downsizing coupled with turbocharging was considered the most effective path to improve engine efficiency at low load, without penalizing rated power/torque performance at full load. On the other side, issues related to knocking combustion and excessive exhaust gas temperatures obliged adopting countermeasures that highly affect the efficiency, such as fuel enrichment and delayed combustion. Powertrain electrification allows operating the ICE mostly at medium/high loads, shifting design needs and constraints towards targeting high efficiency under those operating conditions. Conversely, engine efficiency at low loads becomes a less important issue. In this track, the aim of this work is the investigation of the potential of the oversizing of a small Variable Valve ActuationSpark Ignition gasoline engine towards efficiency increase and tailpipe emission reduction.

Research activities in the development of reliable computational models for aftertreatment systems are constantly increasing in the automotive field. These investigations are essential in order to get a complete understanding of the main catalytic processes which clearly have a great impact on tailpipe emissions. In this work, a 1D chemical reaction model to simulate the catalytic activity of a Pd/Rh Three-Way Catalyst (TWC) for a Natural Gas heavy-duty engine is presented. An extensive database of tests carried out with the use of a Synthetic Gas Bench (SGB) has been collected to investigate the methane abatement pathways, linked to the lambda variation and oxide formation on palladium surface. Specific steady-state tests have shown a dynamics of the methane conversion even at fixed λ and temperature conditions, essentially due to the Pd/PdO ratio.

Within the context of environmental impact reduction for small size spark ignition (SI) engines, especially green-house gas emissions, this study looked at laminar flame speed as an optimization parameter for hydrogen-methane fueled micro-generators. To this aim, SI engine operation was modeled in a 0D/1D simulation framework, so as to identify the best choice of methane-hydrogen ratios in different conditions. Starting from experimental data recorded on a small size engine, an optimization method was implemented for achieving the proposed goal. One of the main conclusions is that high concentrations of hydrogen and resulting fast burn rates are beneficial at high engine speed settings, while the opposite is true at low engine speed. Hydrogen addition was also considered as an additional control margin during lean operation, given that stable combustion can be achieved even with very low equivalence ratios.

In the framework of an increasing demand for a more sustainable mobility, where the fuel consumption reduction is a key driver for the development of innovative internal combustion engines, Turbulent Jet Ignition (TJI) represents one of the most promising solutions to improve the thermal efficiency. However, details concerning turbulent jet assisted combustion are still to be fully captured, and therefore the design and the calibration of efficient TJI systems require the support of reliable simulation tools that can provide additional information not accessible through experiments. To this aim, an experimental investigation combined with a 3D-CFD study was performed to analyze the TJI combustion characteristics in a single-cylinder spark-ignition (SI) engine. Firstly, the model was validated against experiments considering stoichiometric mixture at 3000 rpm, wide open throttle operating conditions.