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Technical Paper

Mechanism of NOx Reduction by Ethanol on a Silver-Base Catalyst

2001-05-07
2001-01-1935
Since there is a trade-off relationship between NOx and particulates in exhaust gas emitted from a diesel engine, simultaneous reduction of the amounts of NOx and particulates in a combustion chamber is difficult. However, the amount of particulates produced in the combustion process could be reduced in a state of almost complete combustion, and the amount of NOx produced during the combustion process could be reduced by the use of a catalyst and reducing agent in the exhaust process. It has been demonstrated that the use of ethanol as a reducing agent on a silver-base catalyst in the presence of oxygen is an effective means for reducing NOx, although the mechanism of the reduction has not been elucidated. Therefore, in the present study, an NOx-reduction apparatus was conducted, and model experiments on NOx reduction were carried out in an atmosphere simulating exhaust gas emitted from a diesel engine and at the same catalyst temperature as that in a combustion chamber.
Technical Paper

A Study on In-Cylinder Injection of Low Pressure Natural Gas for Performance Improvement of Small Sized Two-Stroke SI Engines

2001-05-07
2001-01-1959
Small two stroke SI engines supplied with natural gas in the intake port are advantageous for low maintenance and low cost when used in co-generation systems for residential use. However in the engines with port injection systems, the unburned HC emissions are higher and thermal efficiency is lower than with 4 stroke engines. To overcome these disadvantages, an in-cylinder injection with a special low pressure injection nozzle system was attempted. The results showed that improvements in unburned HC emissions and thermal efficiency are possible due to the remarkable reduction in scavenging loss and the lean combustion.
Technical Paper

Thermodynamic Characteristics of Premixed Compression Ignition Combustions

2001-05-07
2001-01-1891
Thermodynamic characteristics of premixed compression ignition combustions were clarified quantitatively by heat balance estimation. Heat balance was calculated from temperature, mole fractions of intake and exhaust gases, mass and properties of fuels. Heat balance estimation was conducted for three types of combustion; a conventional diesel combustion, a homogeneous charge compression ignition (HCCI) combustion; fuel is provided and mixed with air in an intake pipe in this case, and an extremely early injection type PREmixed lean DIesel Combustion (PREDIC). The results show that EGR should be applied for premixed compression ignition combustion to complete combustion at lower load conditions and to control ignition timing at higher load conditions. With an application of EGR, both HCCI and PREDIC showed low heat loss characteristics at lower load conditions up to 1/2 load.
Technical Paper

A Study of Lean Burn of a 4 Stroke Gasoline Engine by the Aid of Low Pressure Air Assisted In-Cylinder Injection - Part II

1999-10-25
1999-01-3689
Lean-burn engines now being developed employ in-cylinder injection which requires high pressures and so necessitates expensive injection equipment. The injection system proposed here is an air assisted in-cylinder injection system which is injecting a mixture of air and fuel in the cylinder during the intake stroke and allowing atomization at lower injection pressures than those necessary in compressing fuel with a usual solid injection. This time, the experiments used a testing engine of a 4 stroke gasoline OHV type replacing the Side Valve type. Performance with a small depression in the main combustion chamber was investigated with a spark plug and reed valve installed in the depression. The engine was operated then following the same method as last year (SAE 982698). As a result, the lean burn method employed here was possible over a wide range of engine speeds and loads. Moreover, it was also shown that this operation was possible with a fully opened throttle valve.
Technical Paper

A Computational Investigation of Premixed Lean Diesel Combustion - Characteristics of Fuel-Air Mixture Formation, Combustion and Emissions

1999-03-01
1999-01-0229
The effects of fuel injection timing on fuel-air mixture formation, combustion and emissions for a PREmixed lean DIesel Combustion (PREDIC) engine has been studied numerically by the KIVA II modeling package. The software was modified with an improved autoignition and combustion submodel, which describes the formation of combustible or ignitable fuel-air mixtures by turbulent mixing, and describes four chemical reactions, including low-temperature oxidation. The results indicate that the present computational model reproduces major features of two-stage autoignition and experimentally observed trends in NO and unburned fuel emissions. The relationships among in-cylinder distributions of fuel sprays, fuel-air equivalence ratio, temperature and mass fractions of NO and unburned fuel were demonstrated by graphically imaged results. A method of fuel-air mixture characterization has been introduced and used to analyze the numerical results.
Technical Paper

Approaches to Solve Problems of the Premixed Lean Diesel Combustion

1999-03-01
1999-01-0183
Previous research in our laboratory has shown that NOx emissions can be sharply reduced by PREDIC (PRE-mixed lean DIesel Combustion), in which fuel is injected very early in the compression process. However some points of concern remained unsolved, such as a large increase in THC and CO, higher fuel consumption, and an operating region narrowly limited to partial loads, compared to conventional diesel operation. In this paper, the causes of PREDIC's problem areas were analyzed through engine performance tests and combustion observation with a single cylinder engine, through fuel spray observation with a high-pressure vessel, and through numerical modeling. Subsequently, measurable improvements were achieved on the basis of these analyses. As a result, the ignition and combustion processes were clarified in terms of PREDIC fuel-air mixture formation. Thus, THC and CO emissions could be decreased by adopting a pintle type injection nozzle, or a reduced top-land-crevice piston.
Technical Paper

An attempt at Lean Burn of a4 Stroke Gasoline Engine by the Aid of Low Pressure Air Assisted In-Cylinder Injection

1998-10-19
982698
Lean burn engines now being developed employ in-cylinder injection which requires high pressures and so necessitates expensive injection equipment. The experiments reported here used air assisted in-cylinder injection, and injected a mixture of air and fuel during the intake stroke, so allowing atomization at lower injection pressures than those necessary in compressing fuel with solid injection. The experiments confirmed that operation in this manner resulted in similar output and fuel consumption as with a carburetor. Next, a divided combustion chamber was installed and connected to the main combustion chamber and air assisted in-cylinder injection from a reed type injection nozzle was attempted. With this arrangement, stable idling operation was possible to air-fuel ratios (A/F) of 70. Lean burn at A/F = 22 to 35 was also achieved at maximum rated outputs (3.7 kW at 4200 min-l) of 6 - 18 %.
Technical Paper

The Effects of Mixture Formation on Premixed Lean Diesel Combustion Engine

1998-02-23
980533
Previous research in our laboratory has shown that NOx emissions can be sharply reduced by PREDIC (PRE-mixed lean DIesel Combustion), in which fuel is injected very early in the compression process. However some problems still remain, such as higher fuel consumption, a lack of ignition timing control, and a large increase in THC and CO, compared to conventional diesel combustion. Appropriate mixture formation is necessary to solve these problems. In this paper, the influence of mixture formation on PREDIC was investigated. It was found that the pintle type injection nozzle was shown to be suitable for PREDIC, because it produced a comparatively uniform mixture in the combustion chamber and avoided collision of the fuel spray with the cylinder liner. Modeling by the KIVA-II software package was carried out to improve our understanding of the mixture formation process.
Technical Paper

Study on Exhaust Control Valves and Direct Air-Fuel Injection for Improving Scavenging Process in Two-Stroke Gasoline Engines

1996-02-01
960367
A critical factor in improving performance of crankcase-scavenged two-stroke gasoline engines is to reduce the short-circuiting of the fresh charge to the exhaust in the scavenging process. To achieve this, the authors developed a reciprocating exhaust control valve mechanism and direct air-fuel injection system. This paper investigates the effects of exhaust control valve and direct air-fuel injection in the all aspect of engine performance and exhaust emissions over a wide range of loads and engine speeds. The experimental results indicate that the exhaust control valve and direct air-fuel injection system can improve specific fuel consumption, and that HC emissions can be significantly reduced by the reduction in fresh charge losses. The pressure variation also decreased by the improved combustion process. CRANKCASE SCAVENGED two-stroke gasoline engines suffer from fresh charge losses leading to poor fuel economy and it is a reason for large increases of HC in the exhaust.
Technical Paper

Simultaneous Reductions of Smoke and NOx from a DI Diesel Engine with EGR and Dimethyl Carbonate

1995-10-01
952518
Extensive experiments were conducted on a low emission DI diesel engine by using Dimethyl Carbonate (DMC) as an oxygenate fuel additive. The results indicated that smoke reduced almost linearly with fuel oxygen content. Accompanying noticeable reductions of HC and CO were attained, while a small increase in NOx was encountered. The effective reduction in smoke with DMC was maintained with intake charge CO2, which led to low NOx and smoke emissions by the combined use of oxygenated fuel and exhaust gas recirculation (EGR). Further experiments were conducted on an optically accessible combustion bomb and a thermal cracking set-up to study the mechanisms of DMC addition on smoke reduction.
Technical Paper

Analysis of NO Formation Characteristics and Control Concepts in Diesel Engines from NO Reaction-Kinetic Considerations

1995-02-01
950215
This paper uses NO Reaction Kinetic to determine NO formation characteristics in diesel engines. The NO formation was calculated by Extended Zel'dovich Reaction Kinetics in a diffusion process. The results show that the NO formation rate is independent of the mixing of the combustion gas, and that internal EGR (combustion gas mixing in a cylinder) has no effect on NO reduction. The paper also shows the potential of two stage combustion, and its effect strongly depends on the time-scale of mixing. Additionally the paper investigates the mechanism of increased NOx emissions in high pressure fuel injection.
Technical Paper

Theory and Experiments on Air-Entrainment in Fuel Sprays and Their Application to Interpret Diesel Combustion Processes

1995-02-01
950447
This paper presents a theory and its experimental validation for air entrainment changes into fuel sprays in DI diesel engines. The theory predicts air entrainment changes for a variety of swirl speeds, number of nozzle holes, nozzle diameters, engine speeds, injection speeds and fuel densities. The formulae of the theory are simple non-dimensional equations, which apply for different sized engines. Experiments were performed to compare theoretical predictions and experimental results in six different engines varying from 85 to 800mm bore. All results showed good agreement with the theoretical predictions for shallow-dish piston engines. However the agreement became poor in the case of deep cavity piston engines. With the theory, it is possible to interpret a variety of combustion phenomena in diesel engines, providing additional understanding of diesel combustion processes.
Technical Paper

Improvement of Performance and Emissions of a Compression Ignition Methanol Engine with Dimethyl Ether

1994-10-01
941908
Dimethyl ether (DME) has very good compression ignition characteristics, and can be converted from methanol using a γ - alumina catalyst. A previous report investigated a compression ignition methanol engine with DME as an ignition improver. The results showed that the engine operation was sufficiently smooth without either spark or glow plugs. Two methods were studied, one was an aspiration method, and the other was a torch ignition chamber method (TIC method). The aspiration method allows a simple engine structure, but suffers from poor engine emissions and requires large amounts of DME. With the TIC method where the DME was introduced into a torch ignition chamber (TIC) during the intake stroke, the diffusion of the DME into the main combustion chamber was limited, and significant reductions in both the necessary quantity of DME and emissions were obtained [1][2].
Technical Paper

Formation Process of SOF in the Combustion Chamber of IDI Diesel Engines

1993-10-01
932799
Exhaust Particulate emitted from diesel engines is a serious problem form the point of view of the environment and energy saving. Exhaust particulate is consist of dry soot and SOF (soluble organic fraction). To clarify the formation process of SOF in the combustion chamber of diesel engines, first lower temperature column condensed method was investigated. The gas from combustion chamber was collected to the sampling column using this method, and the cracked as well as the condensation polymerized components were analyzed with gas chromatography. The sampling condition of the low temperature column condensation method are length of condensation column 600mm, cooling temperature 198K, and dilution ratio 5. The diesel fuel injected into the combustion chamber, first cracks into lower boiling point hydrocarbons, this is followed by dehydrogenation and formation of benzene ring compounds through condensation polymerization. This is followed by the formation of PAH.
Technical Paper

An Investigation on the Simultaneous Reduction of Particulate and NOx by Controlling Both the Turbulence and the Mixture Formation in DI Diesel Engines

1993-10-01
932797
This paper presents experimental results of the reduction of both particulate and NOx emitted from direct injection diesel engines by a two stage combustion process. The primary combustion is made very rich to reduce NOx and then the particulate is oxidized by strong turbulence generated during the secondary combustion. The rich mixture is formed by low pressure fuel injection and a small cavity combustion chamber configuration. The strong turbulence is generated by a jet of burned gas from an auxiliary chamber installed at the cylinder head. The results showed that NOx was reduced significantly while maintaining fuel consumption and particulate emissions. An investigation was also carried out on the particulate reduction process in the combustion chamber with the turbulence by gas sampling and in-cylinder observation with an optical fiber scope and a high speed camera.
Technical Paper

A Study of a Compression Ignition Methanol Engine with Converted Dimethyl Ether as an Ignition Improver

1992-10-01
922212
Dimethyl ether (DME) can be converted easily from methanol in a catalytic reactor, and it has very good compression ignition characteristics. This paper presents experimental results on a compression ignition methanol engine with DME as an ignition improver. The results show that engine operation is sufficiently smooth with high efficiency without spark or glow plugs. In the experiments, two methods for DME introduction were investigated: an aspiration and a torch ignition method. The aspiration method introduces DME into the intake manifold, and is structurally simple but suffers from poor emission characteristics at partial loads, and a large amount of DME is required for ignition. With the torch ignition method, DME is introduced into a torch ignition chamber during the intake stroke, and significant reductions in both the necessary DME quantity and emissions were obtained. Engine operation was also attempted with DME-dissolved methanol fuel without ignition aids.
Technical Paper

Combustion Similarity for Different Size Diesel Engines: Theoretical Prediction and Experimental Results

1992-02-01
920465
This paper presents a theoretical and experimental study on the possibility of combustion similarity in differently sized diesel engines. Combustion similarity means that the flow pattern and flame distribution develop similarly in differently sized engines. The study contributes to an understanding and correlating of data which are presently limited to specific engine designs. The theoretical consideration shows the possibility of combustion similarity, and the similarity conditions were identified. To verify the theory, a comparison of experimental data from real engines was performed; and a comparison of results of a three dimensional computer simulation for different engine sizes was also attempted. The results showed good agreement with the theoretical predictions. THE PURPOSE of this research is to determine the possibility of the existence of combustion similarity in differently sized diesel engines, and to propose conditions for realizing model experiments.
Technical Paper

Reduction of Smoke and NOx by Strong Turbulence Generated During the Combustion Process in D.I. Diesel Engines

1992-02-01
920467
This paper presents results of experiments to reduce smoke emitted from direct Injection diesel engines by strong turbulence generated during the combustion process. The turbulence was created by jets of burned gas from an auxiliary chamber installed in the cylinder head. Strong turbulence, which was induced late in the combustion period, enhanced the mixing of air with unburned fuel and soot, resulting in a remarkable reduction of smoke and particulate; NOx did not show any increase with this system, and thermal efficiency was improved at high loads. The paper also shows that the combination of EGR and water injection with this system effectively reduces the both smoke and NOx.
Technical Paper

Catalytic Reduction of NOx in Actual Diesel Engine Exhaust

1992-02-01
920091
Copper ion-exchanged ZSM-5 zeolite catalyst, which reduces nitrogen oxides (NOx) in the presence of oxygen and hydrocarbons, was applied to actual diesel engine exhaust. Copper ion-exchanged ZSM-5 zeolite effectively reduced NOx by 25% in normal engine operation, and by 80% when hydrocarbons in the exhaust were increased. Water in the exhaust gas decreased the NOx reduction efficiency, but oxygen and sulfur appeared to have only a small effect. Maximum NOx reduction was observed at 400°C irrespective of hydrocarbon species, and did not decrease with space velocity up to values of 20,000 1/h. THE PURPOSE of this paper is to evaluate the possibilities and problems in catalytic reduction of NOx in actual diesel engine exhaust. Here, a copper ion-exchanged ZSM-5 zeolite (Cu-Z) catalyst was applied to diesel engine exhaust to examine the dependency of the NOx reduction efficiency on temperature and space velocity. The effects of oxygen, water and hydrocarbons were also examined.
Technical Paper

A Quantitative Analysis of Schlieren Photography for an Internal Combustion Engine Diagnostics

1991-02-01
910730
This report describes the possibility of quantitative analysis of Schlieren photographs as an internal combustion engine diagnostic. Using a recently developed photographic analysis system, it was attempted to analyze Schlieren photographs. Results showed simple integration calculations produced significant distortion in the analyzed results. To eliminate the distortion, some correction techniques were developed in this research. Accuracy of the analyzed results were evaluated roughly with uncertainty analysis. The results showed that this analysis technique can be one of the approximate diagnostics for the measurement of fuel vapor and density distribution in internal combustion engine research. SCHLIEREN photography is one of the most popular visualization techniques in the research of internal combustion engines. Although the photographs have density information in themselves, they are used mainly for the purpose of qualitative visualization.
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