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The subject of engine emissions is expected to be at the forefront of environmental regulations and consumers’ concerns for years to come. As technology develops to comply with new and different requirements in various regions of the world, understanding the fundamental principles of how engine emissions occur, and how they can be properly measured, is vitally important. Engine Emissions Measurement Handbook, developed and co-authored by HORIBA Automotive Test Systems team addresses the main aspects of this subject. Written with the technical user in mind, this title is a must-have for those involved in engine development and testing, and environmental researchers focusing on better ways to minimize emissions pollution.

The premixed charge compression ignition (PCCI) combustion in a compression ignition (Cl) engine is one of countermeasures against the very much severe regulation for exhaust gas of engine out. The authors have been proposed to use the fuel mixed with high volatility component and low volatility component to actualize PCCI combustion. This kind of fuel injected forms a fine and lean spray by the flash boiling phenomena which depends on the pressure and the temperature. The role of the former fuel is to decrease in the generation of particulate matters (PM) and that of the latter one is to break out the ignition. Thus, it is very much significant to find the distribution of vapor concentration of both fuels in a spray. This paper describes both distributions in a single diesel spray by use of the technique of laser induced fluorescence (LIF) in a constant volume chamber with high temperature at high pressure as the fundamental research.

The particulate matters (PM) containing in the exhaust gas through a CI engine affects strongly the human health. Thus, it is very significant to measure the mechanism of PM itself generation for actualization of a clean CI engine. On the standpoint mentioned above, the authors carried out the experiments of the characteristics of PM generated from a small high speed DI CI engine with a single cylinder. The variables were the equivalence ratio, the injection timing, the EGR rate and the sort of fuel. As a result, the effect of experimental condition on the distribution of PM is clear through experiments.

Three-dimensional large eddy simulation (LES) has been conducted for a diesel spray flame using KIVALES which is LES version of KIVA code. Modified TAB model, velocity interpolation model and rigid sphere model are used to improve the prediction of the fuel-mixture process in the diesel spray. Combustion is simulated using the Eddy-Dissipation model. CIP method was incorporated into the KIVALES in order to suppress the numerical instability on the combustible flow. The formation of soot and NO was simulated using Hiroyasu model and KIVA original model. Three different grid resolutions were used to examine the grid dependency. The result shows that the LES approach with 0.5 mm grid size is able to resolve the instantaneous spray with the intermittency in the spray periphery, the axi-symmetric shape and meandering flow after the end of injection as shown in the experimental results.

A Solid Particle Counting System (SPCS) has been developed according to the ECE draft regulation proposed by the particle measurement program (PMP). In the previous report the basic performance of the SPCS has been mentioned in detail [1, 2, 3, 4, 5 and 6]. It has been reported that the SPCS demonstrates very stable dilution of sample with air and the error of real time dilution factor is less than 6% up to the total dilution factor of 1000. Penetration of solid particles through the SPCS is over 95% and volatile particles removal efficiency is over 99%. In this study the SPCS has been used to investigate the soot emission behavior from different vehicles with different after-treatment technologies. Direct injection (DI) diesel vehicles without diesel particulate filter (DPF), and with different DPFs (catalyzed and non-catalyzed) have been tested. Direct injection gasoline (DIG) vehicle with oxidation and NOx reduction catalysts have also been tested.

A diesel engine operating in premixed charge compression ignition (PCCI) mode promises the reduction of engine-out emissions of NOx and particulate matter. A serious issue for PCCI operation with the early injection timing during the compression stroke is the difficulty of controlling the mixture formation process. In this study, a mixed fuel consisting of high volatility fuel and high ignitability one is applied in order to develop a control technique for the mixture preparation. In particular, we focuses on a flash boiling phenomenon of mixed fuel. For pure substance, the quality of flashing spray is dominated by the degree of superheat. In contrast, that of mixed fuel is affected much by low boiling point fuel.

Authors propose the reformulation technique of physical properties of Biodiesel Fuel (BDF) by mixing lower boiling point fuels. In this study, waste cooking oil methyl ester (B100), which have been produced in Kyoto city, is used in behalf of BDF. N-Heptane (C7H16) and n-Dodecane (C12H26) are used as low and medium boiling point fuel. Mixed fuel of BDF with lower boiling point fuels have lighter quality as compared with neat BDF. This result is based on the chemical-thermo dynamical liquid-vapor equilibrium theory. This paper describes fundamental spray and combustion characteristics of mixed fuel of B100 with lower boiling point fuels as well as the reformulation technique. By mixing lower boiling point fuel, lighter quality fuels can be refined. Thus, mixed fuels have higher volatility and lower viscosity. Therefore, vaporization of mixed fuel spray is promoted and liquid phase penetration of mixed fuel shortens as compared with that of neat BDF.

It is thought that the synthetic gas, including hydrogen and carbon monoxide, has a potential to be an alternative fuel for internal combustion engines, because a heating value of the synthetic gas is higher than one of hydrogen or natural gas. A purpose of this study is to acquire stable auto-ignition and combustion of the synthetic gas which is supposed to be applied into a direct-injection compression ignition engine. In this study, the effects of ambient gas temperatures and oxygen concentrations on auto-ignition characteristics of the synthetic gas with changing percentage of hydrogen (H2) or carbon monoxide (CO) concentrations in the synthetic gas. An electronically-controlled, hydraulically-actuated gas injector was used to control a precise injection timing and period of gaseous fuels, and the experiments were conducted in an optically accessible, constant-volume combustion chamber under simulated quiescent diesel engine conditions.

A new on-board portable emission measurement system (PEMS) for gaseous emissions has been designed and developed to meet CFR Part 1065 requirements. The new system consists of a heated flame ionization detector (HFID) for the measurement of total hydrocarbon, a heated chemiluminescence detector (HCLD) for the measurement of NOx, and a heated non-dispersive infra-red detector (HNDIR) for the measurement of CO and CO2. The oxygen interference and relative sensitivity of several hydrocarbon components have been optimized for the HFID. The CO2 and H2O quenching effect on the HCLD have been compensated using measured CO2 and H2O concentration. The spectral overlap and molecular interaction of H2O on the HNDIR measurement has also been compensated using an independent H2O concentration measurement. The basic performance of the new on-board emission measurement system has been verified accordingly with CFR part 1065 and all of the performances have met with CFR part 1065 requirement.

One of the effective ways to cope with the very severe future regulation of soot exhausted through a CI engine is the use of oxygenated fuel. This paper describes the experimental results of the soot generation of six kinds of oxygenated fuel and n-heptane whose cetane number is the almost the same as that of the gas oil by means of time resolved LII (TIRE-LII) and the classical two color method. The experiments were carried out in a constant volume chamber. The main result is that the oxygen content of the fuel is the much significant factor to decrease in the soot.

The prototype solid particle counting system (SPCS) has been used to study solid particle emission from gasoline and diesel vehicles. As recommended by the PMP draft proposal, exhaust is diluted by a Constant Volume Sampler (CVS). The SPCS takes the sample from the CVS tunnel. Transient test cycles such as EPA FTP 75, EPA HWFET (EPA Highway Fuel Economy Cycle), and NEDC (New European Driving Cycle) were tested. The repeatability of the instrument was evaluated on the diesel vehicle for three continuous days. The instrument exhibits good repeatability. The differences for the EPA ftp 75, the EPA HWFET, and the NEDC in three continuous tests are ± 3.5%. The instrument is very sensitive as well and detects the driving differences. A large number of solid particles are found during the hard acceleration from both the gasoline and the diesel vehicles. Solid particle emissions decrease quickly at deceleration and when vehicles approach constant speed.

A prototype solid particle counting system (SPCS) has been developed in Horiba. It measures the engine exhaust solid particle number emissions in real-time. The instrument is designed to follow the recommendation in the PMP proposal for solid particle number emissions measurement on Light-duty diesel vehicles. Two wide range continuous diluters, which were developed during this project, have been used as cold and hot diluters, respectively. The accuracy of the dilution ratio is normally ± 4% for the designed range. The instrument has low particle losses, and exhibits over 95% penetration for solid particles. The new instrument has functions such as, normal measurement, dilution ratio control, daily calibration for condensation particle counter (CPC), etc. These functions have been automated to make the instrument's operation simple.

Measurements of soot and SOF emitting from automobile engines by conventional gravimetric method and soxhlet extraction method are difficult and time-consuming processes. The composition in the filter substrate may change during time-consuming analysis. Therefore an accurate and real time measurement method for particulate matter is the key demand for automobile industry. This paper describes a new concept for analyzing PM, which includes measurement of soot and SOF separately, as well as the total PM emission from automobile engine continuously. The concept comprises of the real-time measurement of soot emission with a diffusion charger (DC) combined with a specific dilution system. A differential flame ionization detector with separate sample line temperatures (47°C and 191°C), have been applied for the SOF measurement. The total PM is then expressed as the sum of soot and SOF mass.

In response to the appearance of formal regulations, CFR part 1065 subpart J, a new in-use emission measurement system was developed, the OBS 2000. The OBS 2200 uses partial-vacuum analyzers. The heated flame ionization detector (HFID), heated chemiluminescence detector (HCLD) and heated non-dispersive infrared analyzer (HNDIR) are all upstream of the sample pump. This design decreases the response time of the analyzers, lowers power consumption and minimizes the overall dimensions of the system by avoiding the use of a heated sample pump. The size of the heated zones is also minimized to reduce power usage. Typical power consumption of analyzer unit is less than 500 W. The overall dimension of the main unit is 350mm (W) × 330mm (H) × 500mm (D). Analyzer linearity checks as required by new regulations [1] for all available ranges will be presented along with cut point accuracies relative to full scale and percentage of point.

This paper describes the soot behavior in a diesel flame. The experiments were carried out in a constant volume chamber with quiescent atmosphere. Parameters were the ambient temperature and the oxygen concentration. The integrated image of flame was taken, the natural emission of flame was detected and the KL factor was found by means of classical technique of laser light extinction. The results were discussed by use of the apparent rate of heat release. As a result, the ignition delay and the vortex with large scale generated in a diesel spray affect the soot behavior in a diesel flame.

Recently, after-treatment techniques for diesel engine emission have made remarkable progress with the development of suitable De-NOx catalysts. The urea-injection SCR system is one of the candidates for a high efficiency De-NOx method for diesel engine emissions. This system reduces NOx through a reaction with ammonia (NH3) that is generated from injected urea. In this system, it is very important to control the amount and timing of the urea injection so as to minimize the NH3 gas slip. Therefore, NH3 gas measurement is becoming important during the development of NOx after-treatment systems even though NH3 is not a target component of the current emission regulations. In this paper, a new NH3 gas analyzer utilizing a chemi-luminescence detection (CLD) method has been developed. The new NH3 analyzer consists of dual detectors (DCLDs) and a furnace for a NH3 oxidization catalyst. Real-time concentration of NH3 can be calculated from the difference of NOx readings of two detectors.

It is very significant to take the intermediate products in diesel combustion for understanding the generation of exhaust emissions like SOF, dry soot and so on. The products generated in a constant volume combustion chamber were sampled by pricking a sheet of polyester film installed in the chamber to freeze the chemical reaction. The gas was analyzed by a gas chromatography. The fuel used was n-heptane. It is able to explain the generation of exhaust emissions by the experimental results. The other objective is to simulate the intermediate products. It is capable of explaining the relation between the simulated and experimental results.

The mixed fuel composed of two kinds of fuel oil whose boiling temperature is different each other forms the fine spray with minute droplets when its condition crosses over the two-phase region. It is expected that the fuel with low volatility dominates the ignition delay and that with high volatility does the generation of particulate matter. The experiments were carried out in a rapid compression and expansion machine and in an actual high-speed small sized diesel engine by use of this kind of fuel. The experimental results prove this expectation.

A sulfur analyzer utilizing an ultraviolet fluorescent (UVF) detector has been developed to measure sulfur components in vehicle emissions. Generally, it is considered that an UVF detector cannot be used to measure sulfur components in vehicle emission due to a significant interference from NO in sample gases. In this study, an O3 injection technique has been developed to eliminate NO interference. Using this technique, the interference from NO has been reduced to less than 0.01 ppm with 3000 ppm NO. These result show a capability of utilizing UVF with this O3 injection technique to measure sulfur components in vehicle emissions including emissions with high concentrations of NO. An oxidation catalyst has also been evaluated to measure total reduced sulfur, TRS.

This paper describes the results of on-board measurement of engine performance and emissions in diesel vehicle operated with bio-diesel fuels. Here, two waste-cooking oils were investigated. One fuel is a waste-cooking oil methyl esters. This fuel is actually applied to a garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is a fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. Then, these 3 bio-diesel fuels were applied to the on-board experiments and the results were compared with gas oil operation case.