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In order to deeply investigate and improve the complete path from biofuel production to combustion, the cluster of excellence “Tailor-Made Fuels from Biomass” was installed at RWTH Aachen University in 2007. Recently, new pathways have been discovered to synthesize octanol [1] and di-n-butylether (DNBE). These molecules are identical in the number of included hydrogen, oxygen and carbon atoms, but differ in the molecular structure: for octanol, the oxygen atom is at the end of the molecule, whereas for DNBE it is located in the middle. In this paper the utilization of octanol and DNBE in a state-of-the-art single cylinder diesel research engine will be discussed. The major interest has been on engine emissions (NOx, PM, HC, CO, noise) compared to conventional diesel fuel.

Future vehicles will increasingly be required to improve their efficiency, reduce both regulated and CO₂ emissions, and maintain acceptable levels of driving, safety, and noise performance. To achieve this high level of performance, they will be configured with more advanced hardware, sensors, and control technologies that will also enable their operation on a broader range of fuel properties. These capabilities offer the potential to design future vehicles to operate on the most widely available and GHG-reducing fuels. In previous studies, fuel flexibility has been demonstrated on a compression ignition bench engine and vehicle equipped with an advanced engine management system, closed-loop combustion control, and air-path control strategies. An unresolved question is whether engines of this sort can operate routinely on market gasoline while achieving diesel-like efficiency and acceptable emissions and noise levels.

For on- and off-highway applications in 2012/2014 new legislative emissions requirements will be applied for both European (EURO 6/stage 4) and US (US 2010/Tier4 final) standards. Specifically the NOX-emission limit will be lowered down to 0.46 g/kWh (net power ≻ 56 kW (EU)/130 kW (US) - 560 kW). While for the previous emissions legislation various ways could be used to stay within the emissions limits (engine internal and aftertreatment measures), DeNOX-aftertreatment systems will be mandatory to reach future limits. In these kinds of applications fuel consumption of the engines is a very decisive selling argument for customers. Total cost of ownership needs to be as low as possible. The trade-off between fuel consumption and NOX emissions forces manufacturers to find an optimal solution, especially with regard to increasing fuel prices. In state-of-the-art calibration processes the aftertreatment system is considered separately from the calibration of the thermodynamics.

The HSDI Diesel engine contributes substantially to the decrease of fleet fuel consumption thus to the reduction of CO2 emissions. This results in the rising market acceptance which is supported by desirable driving performance as well as greatly improved NVH behavior. In addition to the above mentioned requirements on driving performance, fuel economy and NVH behavior, continuously increasing demands on emissions performance have to be met. From today's view the Diesel particulate trap presents a safe technology to achieve the required reduction of the particle emission of more than 95%. However, according to today's knowledge a further, substantial NOx engine-out emission reduction for the Diesel engine is counteracts with the other goal of reduced fuel consumption. To comply with current and future emission standards, Diesel engines will require DeNOx technologies.

The European research co-operation Lotus is presented. The main objectives of the project were i) to show the potential for a urea-based SCR system to comply with the EU standard of years 2005 and 2008 for heavy-duty Diesel engines for different driving conditions with optimal fuel consumption, ii) to reach 95 % conversion of NOx at steady state at full load on a Euro III engine, iii) to reach 75 % NOx reduction for exhaust temperatures between 200-300°C, and 85 % average NOx reduction between 200-500°C. The energy content of the consumed urea should not exceed 1.0 %, calculated as specific fuel consumption. These targets were met in May 2003 and the Lotus SCR system fulfilled the Euro V NOx legislative objectives for year 2008.