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Plug-in hybrid electric vehicles have the potential of combining the benefits of electric vehicle in terms of low emissions and internal combustion engine vehicles in terms of vehicle range. With the addition of a renewable fuel, the CO2 potential reduction increase even more. The last trends for PHEV are small combustion engine known as range extender, with battery package between full hybrid and electric powertrains. Thus, allowing an improvement in vehicle’s range, reducing battery materials while converting fuel energy through a highly efficient path. Although these vehicles have been proved to be a convenient strategy for decarbonizing the light vehicles, the use of alternative fuels is poorly studied. In this work, hydrous ethanol is chosen because is already available in some countries, such as USA and Brazil, and have an ultra-low well-to-tank CO2 emission.

In several regions, such as Europe, California, among others, the switch to Electric Vehicles (EVs) has been heavily pushed by policymakers for their high powertrain efficiency and zero tailpipe emissions compared to conventional Internal Combustion Engine Vehicles (ICEVs). Consequently, only zero tailpipe emission vehicles will be sold in Europe from 2035 for the passenger cars and vans segment. But an EV does emit CO2 emissions across its life cycle, mainly during production, and the Well-to-Tank (WTT) phase, i.e., from the electricity generation used to charge the batteries. Nonetheless, due to the high efficiency of the electric powertrain, the energy consumption is significantly less, making the cost of operation significantly low for EVs. Thus, clean electricity grid and cheap energy costs can make EVs one of the best options for decarbonizing transportation systems.

The increasingly stringent emissions regulations together with the demand of highly efficient vehicles from the customers, lead to rapid developments of distinct powertrain solutions, especially when the electrification is present in a certain degree. The combination of electric machines with conventional powertrains diversifies the powertrain architectures and brings the opportunity to save energy in greater extents. On the other hand, alternative combustion modes as reactivity controlled compression ignition (RCCI) have shown to provide simultaneous ultra-low NOx and soot emissions with similar or better thermal efficiency than conventional diesel combustion (CDC). In addition, it is necessary to introduce more renewable fuels as ethanol to reduce the total CO2 emitted to the atmosphere, also called well-to-wheel (WTW) emission, in the transport sector.

Despite syngas is a promising alternative fuel for internal combustion engines (ICEs), its extensive adoption has not been adequately investigated so far. The dedicated literature offers several fundamental studies dealing with H2/CO blends burning at high pressure and room temperature, as well as preheated mixture at low pressure. However, these thermodynamic states are far from the operational conditions typical of ICEs. Therefore, it is essential to investigate the syngas combustion process at engine-like conditions to shed light on this fuel performance, in order to fully benefit from syngas characteristics in ICE application. One of the key properties to characterize a combustion process is laminar flame speed, which is also used by the most widespread turbulent combustion models.

Uncertainty of fuel supply in the energy sector and environmental protection concerns have motivated studies on clean and renewable alternative fuels for vehicles as well as stationary applications. Among all fuel candidates, hydrogen is generally believed to be a promising alternative, with significant potential for a wide range of operating conditions. In this study, a comparison was carried out between CH4, two CH4/H2 blends and two mixtures of CO and H2, the last one taken as a reference composition representative of syngas. It is imperative to fully understand and characterize how these fuels behave in various conditions. In particular, a deep knowledge of how hydrogen concentrations affect the combustion process is necessary, given that it represents a fundamental issue for the optimization of internal combustion engines. To this aim, flame morphology and combustion stability were studied in a SI engine under lean burn conditions.