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A high-fidelity multi-step global kinetic Selective Catalytic Reduction (SCR) model which can predict SCR performance in engine exhaust systems is desirable for optimizing the SCR system, designing on-vehicle control systems and on-board diagnostic (OBD) functions. In this study, a Cu-zeolite SCR catalyst in the exhaust of a 2010 Cummins 6.7L ISB diesel engine was experimentally studied under both steady-state and transient conditions. Steady-state engine tests spanned SCR inlet temperatures from 250 to 400°C with a constant space velocity of 60 khr-1. A 1-D Cu-zeolite model originally developed from reactor data was improved and calibrated to the steady-state engine experimental data. The calibrated model is capable of predicting NO/NO₂ reduction, NH₃ slip, and NH₃ storage associated phenomena.

Active regeneration experiments were carried out on a production 2007 Cummins 8.9L ISL engine and associated diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF) aftertreatment system. The effects of SME biodiesel blends were investigated to determine the particulate matter (PM) oxidation reaction rates for active regeneration. The experimental data from this study will also be used to calibrate the MTU-1D CPF model [1]. The experiments covered a range of CPF inlet temperatures using ULSD, B10, and B20 blends of biodiesel. The majority of the tests were performed at a CPF PM loading of 2.2 g/L with in-cylinder dosing, although 4.1 g/L and a post-turbo dosing injector were also investigated. The PM reaction rate was shown to increase with increasing percent biodiesel in the test fuel as well as increasing CPF temperature.

A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO₂ oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.

Active regeneration experiments were performed on a production diesel aftertreatment system containing a diesel oxidation catalyst and catalyzed particulate filter (CPF) using blends of soy-based biodiesel. The effects of biodiesel on particulate matter oxidation rates in the filter were explored. These experiments are a continuation of the work performed by Chilumukuru et al., in SAE Technical Paper No. 2009-01-1474, which studied the active regeneration characteristics of the same aftertreatment system using ultra-low sulfur diesel fuel. Experiments were conducted using a 10.8 L 2002 Cummins ISM heavy-duty diesel engine. Particulate matter loading of the filter was performed at the rated engine speed of 2100 rpm and 20% of the full engine load of 1120 Nm. At this engine speed and load the passive oxidation rate is low. The 17 L CPF was loaded to a particulate matter level of 2.2 g/L.

A quasi-steady 1-dimensional computer model of a catalyzed particulate filter (CPF) capable of simulating active regeneration of the CPF via diesel fuel injection upstream of a diesel oxidation catalyst (DOC) or other means to increase the exhaust gas temperature has been developed. This model is capable of predicting gaseous species concentrations (HC's, CO, NO and NO2) and exhaust gas temperatures within and after the CPF, for given input values of gaseous species and PM concentrations before the CPF and other inlet variables such as time-varying temperature of the exhaust gas at the inlet of the CPF and volumetric flow rate of exhaust gas.

Active regeneration experiments were performed on a Cummins 2007 aftertreatment system by hydrocarbon dosing with injection of diesel fuel downstream of the turbocharger. The main objective was to characterize the thermal oxidation rate as a function of temperature and particulate matter (PM) loading of the catalyzed particulate filter (CPF). Partial regeneration tests were carried out to ensure measureable masses are retained in the CPF in order to model the oxidation kinetics. The CPF was subsequently re-loaded to determine the effects of partial regeneration during post-loading. A methodology for gathering particulate data for analysis and determination of thermal oxidation in a CPF system operating in the engine exhaust was developed. Durations of the active regeneration experiments were estimated using previous active regeneration work by Singh et al. 2006 [1] and were adjusted as the experiments progressed using a lumped oxidation model [2, 3].

In this paper, a model-based linear estimator and a non-linear control law for an Fe-zeolite urea-selective catalytic reduction (SCR) catalyst for heavy duty diesel engine applications is presented. The novel aspect of this work is that the relevant species, NO, NO2 and NH3 are estimated and controlled independently. The ability to target NH3 slip is important not only to minimize urea consumption, but also to reduce this unregulated emission. Being able to discriminate between NO and NO2 is important for two reasons. First, recent Fe-zeolite catalyst studies suggest that NOx reduction is highly favored by the NO 2 based reactions. Second, NO2 is more toxic than NO to both the environment and human health. The estimator and control law are based on a 4-state model of the urea-SCR plant. A linearized version of the model is used for state estimation while the full nonlinear model is used for control design.

Steady-state particulate loading experiments were conducted on an advanced production catalyzed particulate filter (CPF), both with and without a diesel oxidation catalyst (DOC). A heavy-duty diesel engine was used for this study with the experiments conducted at 20, 40, 60 and 75 % of full load (1120 Nm) at rated speed (2100 rpm). The data obtained from these experiments were used and are necessary for calibrating the MTU 1-D 2-Layer CPF model. These experimental and modeling results were compared to previous research conducted at MTU that used the same engine but an earlier development version of the combination of DOC and CPF. The motivation for the comparison of the two systems was to determine whether the reformulated production catalysts performed as good or better than the early development catalysts. The results were compared to understand the filtration and oxidation differences between the two DOC+CPF and the CPF-only aftertreatment systems.

A Cummins ISB 5.9 liter medium-duty engine with cooled EGR has been used to study an early extrusion of an advanced ceramic uncatalyzed diesel particulate filter (DPF). Data for the advanced ceramic material (ACM) and an uncatalyzed cordierite filter of similar dimensions are presented. Pressure drop data as a function of mass loadings (0, 4, and 6 grams of particulate matter (PM) per liter of filter volume) for various flow rate/temperature combinations (0.115 - 0.187 kg/sec and 240 - 375 °C) based upon loads of 15, 25, 40 and 60% of full engine load (684 N-m) at 2300 rpm are presented. The data obtained from these experiments were used to calibrate the MTU 1-D 2-Layer computer model developed previously at MTU. Clean wall permeability determined from the model calibration for the ACM was 5.0e-13 m2 as compared to 3.0e-13 m2 for cordierite.

An experimental and modeling study was conducted to study the passive regeneration of a catalyzed particulate filter (CPF) by the oxidation of particulate matter (PM) via thermal and Nitrogen dioxide/temperature-assisted means. Emissions data in the exhaust of a John Deere 6.8 liter, turbocharged and after-cooled engine with a low-pressure loop EGR and a diesel oxidation catalyst (DOC) - catalyzed particulate filter (CPF) in the exhaust system was measured and used for this study. A series of experiments was conducted to evaluate the performance of the DOC, CPF and DOC+CPF configurations at various engine speeds and loads.

A one-dimensional, two layer computational model was developed to predict the behavior of a clean and particulate-loaded catalyzed wall-flow diesel particulate filter (CPF). The model included the mechanisms of particle deposition inside the CPF porous wall and on the CPF wall surface, the exhaust flow field and temperature field inside the CPF, as well as the particulate catalytic oxidation mechanisms accounting for the catalyst-assisted particulate oxidation by the catalytic coating in addition to the conventional particulate thermal oxidation. The paper also develops the methodology for calibrating and validating the model with experimental data. Steady state loading experiments were performed to calibrate and validate the model.

A 2-dimensional numerical model (MTU-FILTER) for a single channel of a honeycomb ceramic diesel particulate trap has been developed. The mathematical modeling of the filtration, flow, heat transfer and regeneration behavior of the particulate trap is described. Numerical results for the pressure drop and particulate mass were compared with existing experimental results. Parametric studies of the diesel particulate trap were carried out. The effects of trap size and inlet temperature on the trap performance are studied using the trap model. An approximate 2-dimensional analytical solution to the simplified Navier-Stokes equations was used to calculate the velocity field of the exhaust flow in the inlet and outlet channels. Assuming a similarity velocity profile in the channels, the 2-dimensional Navier-Stokes equations are approximated by 1-dimenisonal conservation equations, which is similar to those first developed by Bissett.

A thermal management system for heavy duty diesel engines is presented for maintaining acceptable and constant engine temperatures over a wide range of operational conditions. It consists of a computer controlled variable speed coolant pump, a position controlled thermostat, and a model-based control strategy. An experimentally validated, diesel engine cooling system simulation was used to demonstrate the thermal management system's capability to reduce power consumption. The controller was evaluated using a variety of operating scenarios across a wide range of loads, vehicle speeds, and ambient temperatures. Three metrics were used to assess the effects of the computer controlled system: engine temperature, energy savings, and cab temperature. The proposed control system provided very good control over the engine coolant temperatures while maintaining engine metal temperatures within a desired range.

Various measurement techniques were employed to quantify sulfuric acid deposition levels and concentration of sulfuric acid in the condensate from the recirculated exhaust gas heat exchanger of a 1995 Cummins M11 heavy-duty diesel engine. Methods employed included a modified version of the sulfur species sampling system developed by Kreso et al. (1)*, rinsing the heat exchanger, and experiments employing a condensate collection device (CCD). The modified sampling system was applied to the inlet and outlet of the heat exchanger in order to quantify the changes in various sulfur compounds. Doped sulfur fuel (3300 to 4000 ppm S) was used to increase the concentrations of the various oxides of sulfur (SOx). These tests were performed at mode 9 of the old EPA 13-mode test cycle (1800 RPM, 932N*m) with 17-20% exhaust gas recirculation (EGR) at two EGR outlet temperatures: 160°C and 103°C.

The Vehicle Engine Cooling System Simulation (VECSS) computer code has been developed at the Michigan Technological University to simulate the thermal response of the cooling system of an on-highway heavy duty diesel powered truck under steady and transient operation. This code includes an engine cycle analysis program along with various components for the four main fluid circuits for cooling air, cooling water, cooling oil, and intake air, all evaluated simultaneously. The code predicts the operation of the response of the cooling circuit, oil circuit, and the engine compartment air flow when the VECSS is operated using driving cycle data of vehicle speed, engine speed, and fuel flow rate for a given ambient temperature, pressure and relative humidity.

A model for calculating the trap pressure drop, various particulate properties, filtration characteristics and trap temperatures was developed during the steady-state and transient cycles using the theory originated by Opris and Johnson, 1998. This model was validated with the data obtained from the steady-state cycles run with an IBIDEN SiC diesel particulate filter. To evaluate the trap experimental filtration efficiency, raw exhaust samples were taken upstream and downstream of the trap. A trap scaling and equivalent comparison model was developed for comparing different traps at the same volume and same filtration area. Using the model, the trap pressure drop data obtained from different traps were compared equivalently at the same trap volume and same filtration area. The pressure drop performance of the IBIDEN SiC trap compared favorably to the previously tested NoTox SiC and the Cordierite traps.

A 2-D CFD model was developed to describe the heat transfer, and reaction kinetics in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state as well as the transient behavior of the flow and heat transfer during the trap regeneration processes. The trap temperature profile was determined by numerically solving the 2-D unsteady energy equation including the convective, heat conduction and viscous dissipation terms. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations (Opris, 1997). The reaction kinetics were described using a discretized first order Arrhenius function. The 2-D term describing the reaction kinetics and particulate matter conservation of mass was added to the energy equation as a source term in order to represent the particulate matter oxidation. The filtration model describes the particulate matter accumulation in the trap.

A 2-D computational model was developed to describe the flow and filtration processes, in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state trap loading, as well as the transient behavior of the flow and filtration processes. The theoretical model includes the effect of a copper fuel additive on trap loading and transient operation. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations. The filtration theory incorporated in the time dependent numerical code included the diffusion, inertia, and direct interception mechanisms. Based on a measured upstream particle size distribution, using the filtration theory, the downstream particle size distribution was calculated. The theoretical filtration efficiency, based on particle size distribution, agreed very well (within 1%) with experimental data for a number of different cases.

A computer simulation of the turbocharged direct- injection diesel engine was developed to enhance the capabilities of the Vehicle Engine Cooling System Simulation (VECSS) developed at Michigan Technological University. The engine model was extensively validated against Detroit Diesel Corporation's (DDC) Series 60 engine data. In addition to the new engine model a charge-air-cooler model was developed and incorporated into the VECSS. A Freightliner truck with a Detroit Diesel's Series 60 engine, Behr McCord radiator, AlliedSignal/Garrett Automotive charge air cooler, Kysor DST variable speed fan clutch and other cooling system components was used for the study. The data were collected using the Detroit Diesel Electronic Controls (DDEC)-Electronic Control Module (ECM) and Hewlett Packard data acquisition system. The enhanced model's results were compared to the steady state TTD (top tank differential) data.

In this study, the effects of an oxidation catalytic converter (OCC) on regulated and unregulated emissions from a 1991 prototype Cummins I.10-310 diesel engine fueled with a 0.01 weight percent sulfur fuel were investigated. The OCC's effects were determined by measuring and comparing selected raw exhaust emissions with and without the platinum-based OCC installed in the exhaust system, with the engine operated at three steady-state modes. It was found that the OCC had no significant effect on oxides of nitrogen (NOX) and nitric oxide (NO) at any mode, but reduced hydrocarbon (HC) emmissions by 60 to 70 percent. The OCC reduced total particulate matter (TPM) levels by 27 to 54 percent, primarily resulting from 53 to 71 percent reductions of the soluble organic fraction (SOF). The OCC increased sulfate (SO42-) levels at two of the three modes (modes 9 and 10), but the overall SO42- contribution to TPM was less than 6 percent at all modes due to the low sulfur level of the fuel.