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Gaseous and particle emissions from a gasoline direct injection (GDI) and a port fuel injection (PFI) vehicle were measured at various ambient temperatures (22°C, -7°C, -18°C). These vehicles were driven over the U.S. Federal Test Procedure 75 (FTP-75) and US06 Supplemental Federal Test Procedure (US06) on Tier 2 certification gasoline (E0) and 10% by volume ethanol (E10). Emissions were analyzed to determine the impact of ambient temperature on exhaust emissions over different driving conditions. Measurements on the GDI vehicle with a gasoline particulate filter (GPF) installed were also made to evaluate the GPF particle filtration efficiency at cold ambient temperatures. The GDI vehicle was found to have better fuel economy than the PFI vehicle at all test conditions. Reduction in ambient temperature increased the fuel consumption for both vehicles, with a much larger impact on the cold-start FTP-75 drive cycle observed than for the hot-start US06 drive cycle.

Original equipment (OE) catalytic converters are designed to last the life of properly tuned and maintained vehicles. Many high mileage vehicles require a replacement converter because the original catalyst was damaged, destroyed, or removed, and the cost of a new OE converter on an older vehicle is difficult to justify. In the U.S., a federal aftermarket converter program has been in place since 1986 (California in 1988) and it has resulted in the replacement of over 50 million converters. Both Federal and California programs have required aftermarket converters to meet minimum performance and durability standards. Increasingly tighter emission standards and durability requirements for new light-duty vehicles have resulted in significant technology improvements in three-way automotive catalysts, however these advancements have not always made their way into aftermarket converters.

Gaseous compounds, particle number and size distribution measurements on a gasoline direct injection (GDI) vehicle and a port fuel injection (PFI) vehicle were conducted over the U.S. Federal Test Procedure 75 (FTP-75) and US06 Supplemental Federal Test Procedure (US06) on Tier 2 certification gasoline (E0) and a 10% by volume ethanol (E10). Overall the GDI test vehicle was observed to have lower fuel consumption than the PFI test vehicle by 6% and 3% for the FTP-75 and US06 drive cycles, respectively. When using E10, this GDI vehicle had a better fuel consumption than the PFI vehicle by 7% and 5% for the FTP-75 and US06 drive cycles, respectively. For particle emissions, the solid particle number emission rates for the GDI, equipped with a 3-way catalyst in its original equipment manufacturer configuration (i.e., stock GDI), were 10 and 31 times higher than the PFI vehicle for the FTP-75 and US06 drive cycles, respectively.

The U.S. Tier 2 emission regulations require sophisticated exhaust aftertreatment technologies for diesel engines. One of the projects under the U.S. Department of Energy's (DOE's) Advanced Petroleum Based Fuels - Diesel Emission Controls (APBF-DEC) activity focused on the development of a light-duty passenger car with an integrated NOx (oxides of nitrogen) adsorber catalyst (NAC) and diesel particle filter (DPF) technology. Vehicle emissions tests on this platform showed the great potential of the system, achieving the Tier 2 Bin 5 emission standards with new, but degreened emission control systems. The platform development and control strategies for this project were presented in 2004-01-0581 [1]. The main disadvantage of the NOx adsorber technology is its susceptibility to sulfur poisoning. The fuel- and lubrication oil-borne sulfur is converted into sulfur dioxide (SO2) in the combustion process and is adsorbed by the active sites of the NAC.

Significant particulate emission reductions of diesel engines can be achieved using diesel particulate filters (DPFs). Ceramic wall flow filters with a PM efficiency of >90% have proven to be effective components in emission control. The challenge for the application lies with the development and adaptation of a reliable regeneration strategy. The main focus is emission efficiency over the legally required durability periods, as well as over the useful vehicle life. It will be shown, that new DPF systems are characterized by a high degree of integration with the engine management system, to allow for initiation of the regeneration and its control for optimum DPF protection. Using selected cases, the optimum combination and tuning will be demonstrated for successful regenerations, taking into account DPF properties.

Preconverters and close-coupled main converters are viewed as key components in advanced emission systems to help the auto industry comply with tightened emission regulations in North America and Europe. Due to their close position to the exhaust manifold when compared to current main catalysts, the mechanical and thermal durability requirements on such close-coupled converters are significantly increased. A set of representative preconverter systems, with respect to back pressure and surface area, ceramic and metal substrate material was exposed to a 100 hour engine aging cycle, which is equivalent to approximately 80,000 kilometers under European driving conditions. This aging cycle is used by the German Autoconsortium (ZDAKW). In order to address the high thermal load in a close-coupled position, the preconverter inlet gas temperature has been elevated to a maximum of 950 °C at stoichiometry. Maximum preconverter midbed temperature has been found close to 1000 °C.

Ceramic preconverters have become a viable strategy to meet the California LEV and ULEV standards. To minimize cold start emissions the preconverter must light-off quickly and be catalytically efficient. In addition, it must also survive the more severe thermomechanical requirements posed by its close proximity to the engine. The viability of the ceramic preconverter system to meet both emissions and durability requirements has also been reported recently(1,2). This paper further investigates the impact preconverter design parameters such as cell density, composition, volume, and catalyst technology have on emissions and pressure drop. In addition, different preconverter/main converter configurations in conjunction with electrically heated catalyst systems are evaluated. The results demonstrate that ceramic preconverters substantially reduce cold start emissions. Their effectiveness depends on preconverter design and volume, catalyst technology, and the system configuration.