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The optimal fuel for partially premixed combustion (PPC) is considered to be a gasoline boiling range fuel with an octane number around 70. Higher octane number fuels are considered problematic with low load and idle conditions. In previous studies mostly the intake air temperature did not exceed 30 °C. Possibly increasing intake air temperatures could extend the load range. In this study primary reference fuels (PRFs), blends of iso-octane and n-heptane, with octane numbers of 70, 80, and 90 are tested in an adapted commercial diesel engine under partially premixed combustion mode to investigate the potential of these higher octane number fuels in low load and idle conditions. During testing combustion phasing and intake air temperature are varied to investigate the combustion and emission characteristics under low load and idle conditions.

Owing to environmental and health concerns, tetraethyl lead was gradually phased out from the early 1970's to mid-1990's in most developed countries. Advances in refining, leading to more aromatics (via reformate) and iso-paraffins such as iso-octane, along with the introduction of (bio) oxygenates such as MTBE, ETBE and ethanol, facilitated the removal of lead without sacrificing RON and MON. In recent years, however, legislation has been moving in the direction of curbing aromatic and olefin content in gasoline, owing to similar concerns as was the case for lead. Meanwhile, concerns over global warming and energy security have motivated research into renewable fuels. Amongst which are those derived from biomass. The feedstock of interest in this study is lignin, which, together with hemicellulose and cellulose, is amongst the most abundant organic compounds on the planet.

Numerous previous studies have reported that the reduction of emissions by adapting oxygenated bio-fuels chiefly depend on the overall oxygen percentage of the blended oxygenates. However, the effect of molecular structures of the fuels has sometimes only been attributed to differences in auto-ignition quality (i.e. cetane number). In this paper, fuels with two kinds of molecular structures, namely linear and cyclic, have been studied. It reports on emissions tests on a modified in-line 6-cylinder DAF HD Diesel engine with several selected oxygenates mixed with diesel. Fuels in question here are from the non-oxygenates group: n-hexane and cyclohexane, and the oxygenate group: 1-hexanol and cyclohexanol. In order to isolate the effect of molecular structure, the blend compositions are chosen such that the overall oxygen fraction of all blends is the same.

Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

In an earlier study, a novel type of diesel fuel injector was proposed. This prototype injects fuel via porous (sintered) micro pores instead of via the conventional 6-8 holes. The micro pores are typically 10-50 micrometer in diameter, versus 120-200 micrometer in the conventional case. The expected advantages of the so-called Porous Fuel Air Mixing Enhancing Nozzle (PFAMEN) injector are lower soot- and CO2 emissions. However, from previous in-house measurements, it has been concluded that the emissions of the porous injector are still not satisfactory. Roughly, this may have multiple reasons. The first one is that the spray distribution is not good enough, the second one is that the droplet sizing is too big due to the lack of droplet breakup. Furthermore air entrainment into the fuel jets might be insufficient. All reasons lead to fuel rich zones and associated soot formation.

The wide range of diesel engine operating conditions demand for a robust combustion model to account for inherent changes. In this work, the Flamelet Generate Manifold (FGM) approach is applied, in STAR-CD framework, to simulate the conventional injection- and early injection-timing (PCCI like) combustion regimes. Igniting Counter flow Diffusion Flamelets (ICDFs) and Homogeneous Reactors (HRs) are used to tabulate chemistry for conventional and PCCI combustion modes, respectively. The validation of the models with experimental data shows that the above consideration of chemistry tabulation results in accurate ignition delay predictions. The study reveals that a moderate amount of 5 different pressure levels is necessary to include in the FGM database to capture the ignition delay in both combustion regimes.

Mixing is inhibited both by the relatively low volatility of conventional diesel fuel and the short premixing time due to high fuel reactivity (i.e. cetane number (CN)). Consequently, in this research two promising oxygenates which can be produced from 2nd generation biomass -ethanol from cellulose and anisole from lignin - will be blended to gasoline, further doped with ignition improver. This will result in a diesel-like CN, but with a higher gasoline-like volatility. There is, however, also a more practical motivation for this study. In Europe, the dieselization trend is resulted in a growing excess of gasoline, which is currently largely exported to the USA at additional transport costs. Boosting the cetane number of gasoline into the diesel range with ignition improvers is a promising route to more efficiently consume European refinery products within Europe.

In this paper, the soot-NOx trade-off and fuel efficiency of various aromatic oxygenates is investigated in a modern DAF heavy-duty diesel engine. All oxygenates were blended to diesel fuel such that the blend oxygen concentration was 2.59 wt.-%. The oxygenates in question, anisole, benzyl alcohol and 2-phenyl ethanol, have similar heating values and cetane numbers, but differ in the position of the functional oxygen group relative to the aromatic ring. The motivation for this study is that in lignin, a widely available and low-cost biomass feedstock, similar aromatic structures are found with varying position of the oxygen group to the aromatic ring. From the results it becomes clear that both the soot-NOx trade-off and the volumetric fuel economy (i.e. ml/kWh) is improved for all oxygenates in all investigated work points.

The Flamelet Generated Manifold (FGM) method is a promising technique in engine combustion modeling to include tabulated chemistry. Different methodologies can be used for the generation of the manifold. Two approaches, based on igniting counterflow diffusion flamelets (ICDF) and homogeneous reactors (HR) are implemented and compared with Engine Combustion Network (ECN) experimental database for the baseline n-heptane case. Before analyzing the combustion results, the spray model is optimized after performing a sensitivity study with respect to turbulence models, cell sizes and time steps. The standard High Reynolds (Re) k-ε model leads to the best match of all turbulence models with the experimental data. For the convergence of the mixture fraction field an appropriate cell size is found to be smaller than that for an adequate spray penetration length which appears to be less influenced by the cell size.

In earlier research, a new class of bio-fuels, so-called cyclic oxygenates, was reported to have a favorable impact on the soot-NOx trade-off experience in diesel engines. In this paper, the soot-NOx trade-off is compared for two types of cyclic oxygenates. 2-phenyl ethanol has an aromatic and cyclohexane ethanol a saturated or aliphatic ring structure. Accordingly, the research is focused on the effect of aromaticity on the aforementioned emissions trade-off. This research is relevant because, starting from lignin, a biomass component with a complex poly-aromatic structure, the production of 2-phenyl ethanol requires less hydrogen and can therefore be produced at lower cost than is the case for cyclohexane ethanol.

Two of the most pressing challenges of the automotive sector are reduction of fuel consumption and corresponding emission of greenhouse gases, especially when taking into account the growing degree of luxury in modern passenger cars, which increases the auxiliary load on the engine. Preferably, this increase in auxiliary load is compensated by the recovery of waste energy. To accomplish this, a technology called WEDACS (Waste Energy Driven Air Conditioning System) is being developed to recover throttling losses. WEDACS uses a turbine to induce provide the engine with the same air mass flow rate as a throttle valve while producing mechanical energy and cold air. An alternator coupled to this turbine converts mechanical energy into electrical energy and the cold air is used to cool A/C fluid. This way the load of both the engine mounted alternator and A/C compressor is reduced or eliminated, resulting in higher efficiency.

The main goal of this paper is to acquire more insight into the relationship between wall and piston impingement of liquid fuel and unburnt hydrocarbon emissions (UHC) emissions, under early direct injection (EDI) premixed charge compression ignition (PCCI) operating conditions. To this end, the vaporization process is modeled for various operating conditions using a commercial CFD code (StarCD). Predicted values for liquid core penetration, or liquid length LL , have been successfully checked against experimental data from literature over a wide range of operating conditions. Next, the correlation between the CFD results for wall and piston impingement and measured UHC emissions is studied. The diesel fuel used in the experiments is modeled as n-dodecane and n-heptadecane, representing the low and high end of the diesel boiling range, respectively. A distinction is made between liquid spray impingement on the piston surface and cylinder liner.

A study on the modeling of fuel sprays in diesel engines will be presented. First, modeling of non-reacting diesel spray formation is studied in Fluent and Star-CD. The main objective however is to model combustion of the spray using a generic approach. This is achieved by applying a detailed chemistry tabulation method, called FGM (Flamelet Generated Manifold). Using this approach will make additional ignition modeling, which is conventional, obsolete. The FGM method is implemented in Fluent and Star-CD. Subsequently, constant volume spray combustion and full engine cycle simulations are performed. Spray formation is modeled with Lagrangian type models that are available in Fluent and Star-CD, and also with a 1D Euler-Euler spray model that is implemented and applied in 3D Fluent simulations. The results are compared with EHPC (Eindhoven High Pressure Cell) experiments, data from Sandia National Laboratories and IFP (Institut Français du Pétrole).

A transparent HSDI CI engine was used together with a high speed camera to analyze the liquid phase spray geometry of the fuel types: Swedish environmental class 1 Diesel fuel (MK1), Soy Methyl Ester (B100), n-Heptane (PRF0) and a gas-to-liquid derivate (GTL) with a distillation range similar to B100. The study of the transient liquid-phase spray propagation was performed at gas temperatures and pressures typical for start of injection conditions of a conventional HSDI CI engine. Inert gas was supplied to the transparent engine in order to avoid self-ignition at these cylinder gas conditions. Observed differences in liquid phase spray geometry were correlated to relevant fuel properties. An empirical relation was derived for predicting liquid spray cone angle and length prior to ignition.

In the port injected Spark Ignition (SI) engine, the single greatest part load efficiency reducing factor are energy losses over the throttle valve. The need for this throttle valve arises from the fact that engine power is controlled by the amount of air in the cylinders, since combustion occurs stoichiometrically in this type of engine. In WEDACS (Waste Energy Driven Air Conditioning System), a technology patented by the Eindhoven University of Technology, the throttle valve is replaced by a turbine-generator combination. The turbine is used to control engine power. Throttling losses are recovered by the turbine and converted to electrical energy. Additionally, when air expands in the turbine, its temperature decreases and it can be used to cool air conditioning fluid. As a result, load of the alternator and air conditioning compressor on the engine is decreased or even eliminated, which increases overall engine efficiency.

One of the challenges with conventional diesel engines is the emission of soot. To reduce soot emission whilst maintaining fuel efficiency, an important pathway is to improve the fuel-air mixing process. This can be achieved by creating small droplets in order to enhance evaporation. Furthermore, the distribution of the droplets in the combustion chamber should be optimized, making optimal use of in-cylinder air. To deal with these requirements a new type of injector is proposed, which has a porous nozzle tip with pore diameters between 1 and 50 μm. First, because of the small pore diameters the droplets will also be small. From literature it is known that (almost) no soot is formed when orifice diameters are smaller than 50 μm. Second, the configuration of the nozzle can be chosen such that the whole cylinder can be filled with fine droplets (i.e., spray angle nearly 180°).

An HSDI Diesel engine was fuelled with standard Swedish environmental class 1 Diesel fuel (MK1), Soy methyl ester (B100) and n-heptane (PRF0) to study the effects of both operating conditions and fuel properties on engine performance, resulting emissions and spray characteristics. All experiments were based on single injection diesel combustion. A load sweep was carried out between 2 and 10 bar IMEPg. For B100, a loss in combustion efficiency as well as ITE was observed at low load conditions. Observed differences in exhaust emissions were related to differences in mixing properties and spray characteristics. For B100, the emission results differed strongest at low load conditions but converged to MK1-like results with increasing load and increasing intake pressures. For these cases, spray geometry calculations indicated a longer spray tip penetration length. For low-density fuels (PRF0) the spray spreading angle was higher.