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Water removal from Proton Exchange Membrane (PEM) Fuel Cell (FC) mainly involves two phenomena: some of the emerging droplets will roll on the Gas Diffusion Layer (GDL), others may impact channel walls and start sliding along the airflow direction. This different behaviour is linked to the hydrophobic/hydrophilic nature of the surface the water is moving on. In this paper, the walls of the channel of a FC were characterized by applying optical techniques. The deposition of droplets on the channel wall led to an evaluation of the proper range for Contact Angle Hysteresis (CAH = 55° - 45°), and due to the high wettability of the surface, droplets dimension was defined with a dimensionless parameter B/H. Under high crossflow condition (15 m/s) a sliding behaviour was observed. The channel features determined through image processing were used as boundary conditions for a 2D CFD two phase simulation employing the Volume of Fluid (VOF) model to keep track of the fluids interface.

In this work, a dynamic 0-D electro-thermal model of a lithium-polymer battery for automotive applications is presented. The model predicts the battery temperature during its charging/discharging phases under different environmental and operating conditions, by considering the requested power or current, the coolant flow rate and its temperature as model inputs. The model was first validated with experimental data carried out at the test bench where only the convective heat transfer between the battery and the ambient air was considered. The accuracy of the internal heat generation model was experimentally assessed for different current discharge rates. Then, a liquid cooling system was designed on purpose, assembled, and installed on the battery at the test bench for the improvement of the model predictions in liquid convection conditions.

Hydrogen is an energy vector with low environmental impact and will play a significant role in the future of transportation. Converting a spark ignition (SI) engine powered vehicle to H2 fueling has several challenges, but was overall found to be feasible with contained cost. Fuel delivery directly to the cylinder features numerous advantages and can successfully mitigate backfire, a major issue for H2 SI engines. Within this context, the present work investigated the specific fuel system requirements in port- (PFI) and direct-injection (DI) configurations. A 0D/1D model was used to simulate engine operating characteristics in several working conditions. As expected, the model predicted significant improvement of volumetric efficiency for DI compared to the PFI configuration. Boosting requirements were predicted to be at levels quite close to those for gasoline fueling.

In order to reduce fuel consumption and polluting emissions from engines, alternative fuels such as hydrogen could play an important role towards carbon neutrality. Moreover, dual-fuel (DF) technology has the potential to offer significant improvements in carbon dioxide emissions for transportation and energy sectors. The dual fuel concept (natural gas/diesel or hydrogen/diesel) represents a possible solution to reduce emissions from diesel engines by using low-carbon or carbon-free gaseous fuels as an alternative fuel. Moreover, DF combustion is a possible retrofit solution to current diesel engines by installing a PFI injector in the intake manifold while diesel is injected directly into the cylinder to ignite the premixed mixture. In the present study, dual fuel operation has been investigated in a single cylinder research engine.

The urban mobility electrification has been proposed as the main solution to the vehicle emission issues in the next years. However, internal combustion engines have still great potential to decarbonize the transport sector through the use of low/zero-carbon fuels. Alcohols such us methanol, have long been considered attractive alternative fuels for spark ignition engines. They have properties similar to those of gasoline, are easy to transport and store. Recently, great attention has been devoted to gaseous fuels that can be used in existing engine after minor modification allowing to drastically reduce the pollutant emissions. In this regard, this study tries to provide an overview on the use of alternative fuels, both liquid and gaseous in spark ignition engines, highlighting the benefits as well as the criticalities. The investigation was carried out on a small displacement spark ignition engine capable to operate both in port fuel and direct injection mode.

Hybrid electric vehicles are a suitable solution for the transition from fossil fuels-based transportation to electric mobility. They have the benefits of zero-emissions operation when only the electric engine is used preventing the typical range anxiety of full-electric vehicles. Also, they can have a low battery pack capacity and weight thanks to the continuous recharge from the internal combustion engine that becomes the only responsible for exhaust emissions. A practical solution to limit the combustion engine emissions is represented by the range extender configuration, where the engine works at a fixed operating point with the highest efficiency serving uniquely as a battery charger. In the face of the current world situation and future changes, research for alternative energy sources is crucial. Hydrogen can be used as an alternative fuel for common internal combustion engines; moreover, it has the great advantage of high efficiency (about 44%).

In the context of increasing efforts towards zero emissions transport, hydrogen represents a valid alternative to electric powertrains. Spark ignition (SI) engines are well suited for this alternative fuel and its specific application requires relatively minor changes with respect to added components. Limited range is one of the main issues with hydrogen as an energy source for transportation, due to its low energy density. The present study looked at the possibility of converting a small size passenger car powered by a turbocharged SI unit to hydrogen fueling. Taking the electric version of the vehicle as benchmark, the initial evaluation of the hydrogen SI alternative appears feasible with an additional gas container comparable in size to the gasoline tank. As a result, further investigation was aimed at actual engine operation in port fuel injection mode, with a focus on rated power and injection phasing effects.

Direct injection spark ignition engines represent an effective technology to achieve the goal of carbon dioxide emission reduction. Further reduction of the carbon footprint can be achieved by using carbon-neutral fuels. Oxygenated alcohols are well consolidated fuels for spark ignition engines providing also the advantages of knock resistance and low soot tendency production. Methanol and ethanol are possible candidates as alternative fuels to gasoline due to their similar properties. In this study a blend at 25 % v/v of ethanol in gasoline (E25) and a blend with 80% gasoline, 5 % v/v ethanol and 15% v/v of methanol (GEM) were tested. These blends were considered since E25 is already available at fuel pump in some countries. The GEM blend, instead, could represent a valid alternative in the next future. Experiments were carried out on a high performance, turbocharged 1.8 L direct injection spark ignition engine over the Worldwide Harmonized Light Vehicles Test Cycle.

The application of an alternative fuel such as hydrogen to internal combustion engines is proving to be an effective and flexible solution for reducing fuel consumption and polluting emissions from engines. An easy to use and immediate application solution is the dual fuel (DF) technology. It has the potential to offer significant improvements in carbon dioxide emissions from light compression ignition engines. The dual fuel concept (natural gas / diesel or hydrogen / diesel) represents a possible solution to reduce emissions from diesel engines by using low-carbon or carbon-free gaseous fuels as an alternative fuel. Moreover, DF combustion is a possible retrofit solution to current diesel engines by installing a PFI injector in the intake manifold while diesel is injected directly into the cylinder to ignite the premixed mixture. In the present study, dual fuel operation has been investigated in a single cylinder research engine.

Nowadays, the stricter regulations in terms of emissions have limited the use of diesel engines on urban roads. On the contrary, for marine and off-road applications the diesel engine still represents the most feasible solution for work production. In the last decades, dual fuel operation with methane supply has been widely investigated. Starting from previous studies on a research engine, where diesel-methane dual fuel combustion has been deepened both experimentally and numerically with the aid of a CFD code, the authors implemented and tested a kinetic mechanism. It is obtained from the combination of the well-established GRIMECH 3.0 and a detailed scheme for a diesel surrogate oxidation. Moreover, the Autoignition-Induced Flame Propagation model, included in the ANSYS Forte® software, is applied because it can be considered the most appropriate model to describe dual fuel combustion.

The battery efficiency is strongly affected by the operating temperature, granting the best performance in a limited range. Great attention is given to the design and the testing of materials for the battery heat dissipation. In the present study, the thermal behavior of a Li-polymer cell, which is part of a battery pack for electric vehicles, is investigated. The cell is provided with different coatings of carbon, graphene, and silicone, used in turn, to dissipate the heat generated during the operation in natural convection. The coating is placed only on one side of the battery while the other one is inspected via thermal imaging. Optical diagnostics in the infrared band are used to evaluate the bi-dimensional distribution of the battery surface temperature and the effect of the coatings. Different operating conditions are tested by varying the current demand.

In view of the new emission regulations seeking to lower the particle cut-off size down to the current 23 nm, an extensive comprehension on the nature of sub-23 nm particles is crucial. In this regard, a new challenge lies ahead considering an even more massive use of biofuels. The objective of this research study was to characterize the sub-23 nm particles and to evaluate their volatile organic fraction (VOF) from a high performance, 1.8 L gasoline direct injection (GDI) engine under the Worldwide harmonized Light vehicles Test Cycle (WLTC). Particle emissions were measured through an Engine Exhaust Particle Sizer (EEPS) capable of particle sizing and counting in the range 5.6 - 560 nm. The sampling and conditioning were performed by both a single diluter and the Dekati Engine Exhaust Diluter (DEED) a Particle Measurement Programme (PMP) compliant sample conditioning system.

Methane supply in diesel engines operating in dual fuel mode has demonstrated to be effective for the reduction of particulate matter and nitric oxides emissions from this type of engine. In particular, methane is injected into the intake manifold to form a premixed charge with air, while a reduced amount of diesel oil is still directly injected to ignite the mixture inside the cylinder. As a matter of fact, the liquid fuel burns following the usual diffusive combustion, so activating the gaseous fuel oxidation in a premixed flame. Clearly, the whole combustion process appears to be more complex to be described in a CFD simulation, mainly because it is not always possible to select in the 3-dimensional codes a different combustion model for each fuel and, also, because other issues arise from the interaction of the two fuels.

The electrochemical performance of a lithium-ion battery is strongly affected by the temperature. During charge and discharge cycles, batteries are subjected to an increment of temperature that can accelerate aging and loss of efficiency if critical values are reached. Knowing the thermal parameters that affect the heat exchange between the battery surface and the surrounding environment (air, cooling fins, plates, etc…) is fundamental to their thermal management. In this work, thermal imaging is applied to a laminated lithium-polymers battery as a non-invasive temperature-indication method. Measurements are taken during the discharge phase and the following cooling down until the battery reaches the ambient temperature. The 2d images are used to analyze the homogeneity of the temperature distribution on the battery surface. Then, experimental results are coupled with mathematical correlations.

Pollutant emission of vehicle cars is nowadays a fundamental aspect to take into account. In the last decays, the company have been forced to study new solutions, such as alternative fuel and learn burn mixture strategy, to reduce the vehicle’s pollutants below the limits imposed by emission regulations. Pre-chamber ignition system presents potential reductions in emission levels and fuel consumption, operating with lean burn mixtures and alternative fuels. As alternative fuels, methane is considered one of the most interesting. It has wider flammable limits and better anti-knock properties than gasoline. Moreover, it is characterized by lower CO2 emissions. The aim of this work is to study the evolution of the plasma jets in a different in-cylinder conditions. The activity was carried out in a research optical small spark ignition engine equipped alternatively with standard ignition system and per-chamber.

A growing number of electric vehicles (EV) and hybrid electric vehicles (HEV) in the present market depicts the rapid growing demand for energy storage systems. The battery’s main peculiarities must be the power density and reliability over time. The temperature strongly affects battery performance for low and high intensity. In particular, the management of the heat generated by the battery itself is one of the main aspects to handle to preserve the performance over time. The objective of this paper is to compare the surface temperature of the lithium-ion polymer battery at different discharging rates by infrared thermography. Thermal imaging is performed to detect the battery surface temperature distribution, focusing on its variation over time and the local inhomogeneity. Temperature measurements are then used to estimate the contributions of the different heat transfer mechanisms for the dissipation of the heat generated by the battery.

The analysis of heat losses in internal combustion engines (ICEs) is fundamental to evaluate and to improve engine efficiency. Detailed and reliable heat transfer models are required for more complex 1d-3d combustion models. At the same time, the thermal status of engine components, like pistons, is needed for an efficient design. Measurements of piston temperature during ICEs operation represent an important and challenging result to get for the aforementioned purposes. In the present work, temperature measurements collected at different engine speeds and loads, both in motored and fired modes, have been performed and used to set-up a theoretical correlation and 1d model of heat transfer through the optical window of the piston. The in-cylinder gas and external ambient temperature, together with the thermodynamic and material properties are given. The model has been first calibrated in some selected operating conditions and then validated in the remaining.

In the present study, dual fuel mode is investigated in a single cylinder optical compression ignition (CI) research engine. Methane is injected in the intake manifold while the diesel is delivered via the standard injector directly into the engine. The aim is to study by non-intrusive diagnostics the effect of increasing methane concentration at constant injected diesel amount during the combustion evolution from start of combustion. IR imaging is applied in cycle resolved mode. Three filters are adopted to detect from injection to combustion phase with high spatial and temporal resolution: OD1.45 (3-5.5 μm), band pass 3.3 μm (hydrocarbons) and band pass 4.2 μm (CO2). Using the band pass IR imaging qualitative information about fuel-vapor distribution and ignition locations during low and high temperature combustion have been provided.

Within the context of distributed power generation, small size systems driven by spark ignition engines represent a valid and user-friendly choice, that ensures good fuel flexibility. One issue is that such applications are run at part load for extensive periods, thus lowering fuel economy. Employing an inverter (fitted between the generator and load) allows engine operation within a wide range of crankshaft rotational velocity, therefore improving efficiency. For the purpose of evaluating the benefits of this technology within a co-generation framework, two configurations were modeled by using the GT-Power simulation software. After model calibration based on measurements on a small size engine for two-wheel applications, the downsized version was compared to a larger power unit operated at constant engine speed for a scenario that featured up to 10 kW rated power.

Internal combustion engines are characterized by high pressure and thermal loads on pistons and in cylinders. The heat generated by the combustion process is dissipated by means of water and oil cooling systems. For the best design and optimization of the engine components it is necessary to know the components temperature in order to estimate the thermal flows. The purpose of this work is to measure the piston sapphire window temperature in a research optically accessible engine by combining two different techniques: measurements with templugs and with thermography. The method is very simple and can provide a reliable value of temperature within a small interval. It fits well for applications inside the engine because of its low technical level requirements. It consists of application of temperature sensitive stickers on the target component that makes it a very robust method, not affected by piston movement.