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Given the spread of natural gas engines in low-term toward decarbonization and the growing interest in gaseous mixtures as well as the use of hydrogen in Heavy-Duty (HD) engines, appropriate strategies are needed to maximize thermal efficiency and achieve near-zero emissions from these propulsor systems. In this context, some phenomena related to real-world driving operations, such as engine cut-off or misfire, can lead to inadequate control of the Air-to-Fuel ratio, key factor for Three-Way Catalyst (TWC) efficiency. Goal of the present research activity is to investigate the performance of a bio-methane-fueled HD engine and its Aftertreatment System (ATS), consisting of a Three-Way Catalyst, at different Air-to-Fuel ratio. An experimental test bench characterization, in different operating conditions of the engine workplan, was carried out to evaluate the catalyst reactivity to a defined pattern of the Air-to-Fuel ratio.

The forthcoming introduction of the EURO VII regulation requires urgent strategies and solutions for the reduction of sub-23 nm particle emissions. Although they have been historically considered as particulate matter-free, the high interest for Natural Gas (NG) Heavy-Duty engines in the transport sector, demands their compliance with the new proposed regulations. In order to obtain high conversion of gas pollutants and a strong abatement of the emitted particles, the use of Particle Filters in NG aftertreatment (CPF) in conjunction with the Three-Way Catalyst (TWC) may represent an attractive and feasible solution. Performances of a cordierite filter were explored through an extensive experimental campaign both in Steady-State conditions and during transient engine maneuvers that involved a whole analysis of the emitted particles in terms of number and mass.

Increasingly stringent pollutant and CO2 emission standards require the car manufacturers to investigate innovative solutions to further improve the fuel economy and environmental impact of their fleets. Nowadays, NOx emissions standards are stringent for spark-ignition (SI) internal combustion engines (ICEs) and many techniques are investigated to limit these emissions. Among these, an extremely lean combustion has a large potential to simultaneously reduce the NOx raw emissions and the fuel consumption of SI ICEs. Engines with pre-chamber ignition system are promising solutions for realizing a high air-fuel ratio which is both ignitable and with an adequate combustion speed. In this work, the combustion characteristics of an active pre-chamber system are experimentally investigated using a single-cylinder research engine. The engine under exam is a large bore heavy-duty unit with an active pre-chamber fuelled with compressed natural gas.

Research activities in the development of reliable computational models for aftertreatment systems are constantly increasing in the automotive field. These investigations are essential in order to get a complete understanding of the main catalytic processes which clearly have a great impact on tailpipe emissions. In this work, a 1D chemical reaction model to simulate the catalytic activity of a Pd/Rh Three-Way Catalyst (TWC) for a Natural Gas heavy-duty engine is presented. An extensive database of tests carried out with the use of a Synthetic Gas Bench (SGB) has been collected to investigate the methane abatement pathways, linked to the lambda variation and oxide formation on palladium surface. Specific steady-state tests have shown a dynamics of the methane conversion even at fixed λ and temperature conditions, essentially due to the Pd/PdO ratio.

A growing interest towards heavy-duty engines powered with NG, dictated by stringent regulations in terms of emissions, has made it essential to study a specific Three-Way Catalyst (TWC). Oxygen storage phenomena characterize the catalytic converter efficiency under real world driving operating conditions and, consequently, during strong dynamics in Air-to-Fuel ratio (AFR). A numerical “quasi-steady” model has been set-up to simulate the chemical process inside the reactor. A dedicated experimental campaign has been performed in order to evaluate the catalyst response to a defined λ variation, thus providing the data necessary for the numerical model validation. In fact, goal of the present research activity was to investigate the effect of very fast composition transitions of the engine exhaust typical of the mentioned driving conditions (including fuel cutoffs etc.) on the catalyst performance and on related emissions.

Diesel will continue to be an indispensable energy carrier for the car fleet CO2 emission targets in the short-term. This is particularly relevant for heavy-duty vehicles as for mid-size cars and SUVs. Looking at the latest technology achievements on the after-treatment systems, it can be stated that the concerning about the NOx emission gap between homologation test and real road use is basically solved, while the future challenge for diesel survival is to keep its competitiveness in the CO2 vs cost equation in comparison to other propulsion systems. The development of the combustion system design still represents an important leverage for further efficiency and emissions improvements while keeping the current excellent performance in terms of power density and low-end torque.

The combustion quality in modern diesel engines depends strictly on the quality of the air-fuel mixing and, in turn, from the quality of spray atomization process. So air-fuel mixing is strongly influenced by the injection pressure, geometry of the nozzle duct and the hydraulic characteristics of the injector. In this context, spray concepts alternative to the conventional multi-hole nozzles could be considered as solutions to the extremely high injection pressure increase to assure a higher and faster fuel-air mixing in the piston bowl, with the final target of increasing the fuel efficiency and reducing the engine emissions. The study concerns an experimental depiction of a spray generated through a prototype high-pressure hollow-cone nozzle, under evaporative and non-evaporative conditions, injecting the fuel in a constant-volume combustion vessel controlled in pressure and temperature up to engine-like gas densities in order to measure the spatial and temporal fuel patterns.

The paper describes the results achieved in developing a new diesel combustion system for passenger car application that, while capable of high power density, delivers excellent fuel economy through a combination of mechanical and thermodynamic efficiencies improvement. The project stemmed from the idea that, by leveraging the high fuel injection pressure of last generation common rail systems, it is possible to reduce the engine peak firing pressure (pfp) with great benefits on reciprocating and rotating components light-weighting and friction for high-speed light-duty engines, while keeping the power density at competitive levels. To this aim, an advanced injection system concept capable of injection pressure greater than 2500 bar was coupled to a prototype engine featuring newly developed combustion system. Then, the matching among these features have been thoroughly experimentally examined.

The interest in Natural Gas (NG) as alternative fuel for transportation is constantly growing, mostly due to its large availability and lower environmental impact with respect to gasoline or diesel fuel. In this scenario, the application of the Dual Fuel (DF) Diesel- Natural Gas (NG) combustion concept to light duty engines can represent an important route to increment the diffusion of natural gas use. Many studies have proven the benefits of DF with respect to conventional diesel combustion in terms of CO2, NOx, PM and PN emissions, with the main drawback of high unburned hydrocarbon, mainly at low/partial engine loads. This last aspect still prevents the application of DF mode to small displacement engines. In the present work, a 2.0 L Euro 5 compliant diesel engine, equipped with an advanced electronic closed-loop combustion control (CLCC) system, has been set up to operate in DF mode and tested on a dyno test bench.

Diesel particulate filter (DPF) is the most effective emission control device for reducing particle emissions (both mass, PM, and number, PN) from diesel engines, however many studies reported elevated emissions of nanoparticles (<50 nm) during its regeneration. In this paper the results of an extensive literature survey is presented. During DPF active regeneration, most of the literature studies showed an increase in the number of the emitted nanoparticles of about 2-3 orders of magnitude compared to the normal operating conditions. Many factors could influence their amount, size distribution, chemical-physical nature (volatiles, semi-volatiles, solid) and the duration of the regenerative event: i.e. DPF load and thermodynamic conditions, lube and fuel sulfur content, engine operative conditions, PN sampling and measurement methodologies.

In this paper, a parametric analysis on the main engine calibration parameters applied on gasoline Partially Premixed Combustion (PPC) is performed. Theoretically, the PPC concept permits to improve both the engine efficiencies and the NOx-soot trade-off simultaneously compared to the conventional diesel combustion. This work is based on the design of experiments (DoE), statistical approach, and investigates on the engine calibration parameters that might affect the efficiencies and the emissions of a gasoline PPC. The full factorial DoE analysis based on three levels and three factors (33 factorial design) is performed at three engine operating conditions of the Worldwide harmonized Light vehicles Test Cycles (WLTC). The pilot quantity (Qpil), the crank angle position when 50% of the total heat is released (CA50), and the exhaust gas recirculation (EGR) factors are considered. The goal is to identify an engine calibration with high efficiency and low emissions.

The present paper describes the results of a research activity aimed at studying the potential offered by the use of Hydrocracked fossil oil (HCK) and Hydrotreated Vegetable Oil (HVO) blends as premium fuels for next generation diesel engines. Five fuels have been tested in a light duty four cylinder diesel engine, Euro 5 version, equipped with closed loop control of the combustion. The set of fuels comprises four experimental fuels specifically formulated by blending high cetane HVO and HCK streams and oneEN590-compliant commercial diesel fuel representative of the current market fuel quality. A well consolidated procedure has been carried out to estimate, for the tested fuels, the New European Driving Cycle (NEDC) vehicle performance by means of the specific emissions at steady-state engine operating points.

Nowadays, alcohol fuels are of increasing interest as alternative transportation biofuels even in compression ignition engines because they are oxygenated and producible in a sustainable way. In this paper, the experimental research activity was conducted on a single cylinder research engine provided with a modern architecture and properly modified in a dual-fuel (DF) configuration. Looking at ethanol the as one of the future environmental friendly biofuels experimental campaign was aimed to evaluate in detail the effect of the use of the ethanol as port injected fuel in diesel engine on the size, morphology, reactivity and chemical features of the exhaust emitted soot particles. The engine tests were chosen properly in order to represent actual working conditions of an automotive light-duty diesel engine. A proper engine Dual-Fuel calibration was set-up respecting prefixed limits on in-cylinder peak firing pressure, cylinder pressure rise, fuel efficiency and gaseous emissions.

The present paper reassumes the results of an experimental study focused on the effects of the nozzle injector's coking varying the flow number (FN); the performance and emissions of an automotive Euro5 diesel engine have been analyzed using diesel fuel. As the improvement of the diesel engine performance requires a continuous development of the injection system and in particular of the nozzle design, in the last years the general trend among OEMs is lowering nozzle flow number and, as a consequence, nozzle holes size. The study carried out moves from the consideration that a reduction of the nozzle holes diameter could increase the impact of their coking process. For this purpose, an experimental campaign has been realized, testing the engine in steady state in three partial load operating points, representative of the European homologation driving cycle, and in full load conditions.

In this paper the characteristics of a mixture of glycerol-based ethers usable in a compression ignition engine are investigated, in terms of efficiency and emissions. Alternative pathways for the energetic exploitation of biodiesel derived glycerol became of increasing interest as the biodiesel production was increased worldwide. Because of its detrimental physical and chemical properties, raw glycerol is hardly usable in conventional internal combustion engines (ICE). However, etherification of glycerol with tert-butyl alcohol and isobutylene allows obtaining a mixture mainly composed of higher glycerol ethers (GEM) suitable for compression ignition engines. Thus, the aim of this research study was to test a mixture of mono-, di- and tri-tert-butyl ethers of glycerol in blend with a commercial diesel fuel in a compression ignition engine, evaluating the fuel efficiency and the impact on the pollutant emissions.

The EU emission standards for new rail Diesel engines are becoming even more stringent. EGR and SCR technologies can both be used to reduce NOx emissions; however, the use of EGR is usually accompanied by an increase in PM emissions and may require a DPF. On the other hand, the use of SCR requires on-board storage of urea. Thus, it is necessary to study these trade-offs in order to understand how these technologies can best be used in rail applications to meet new emission standards. The present study assesses the application of these technologies in Diesel railcars on a quantitative basis using one and three dimensional numerical simulation tools. In particular, the study considers a 560 kW railcar engine with the use of either EGR or SCR based solutions for NOx reduction. The NOx and PM emissions performances are evaluated over the C1 homologation cycle.

The present paper describes the results of a research project aimed at studying the impact of nozzle flow number on a Euro5 automotive diesel engine, featuring Closed-Loop Combustion Control. In order to optimize the trade-offs between fuel economy, combustion noise, emissions and power density for the next generation diesel engines, general trend among OEMs is lowering nozzle flow number and, as a consequence, nozzle hole size. In this context, three nozzle configurations have been characterized on a 2.0L Euro5 Common Rail Diesel engine, coupling experimental activities performed on multi-cylinder and optical single cylinder engines to analysis on spray bomb and injector test rigs. More in detail, this paper deeply describes the investigation carried out on the multi-cylinder engine, specifically devoted to the combustion evolution and engine performance analysis, varying the injector flow number.

Biofuel usage is increasingly expanding thanks to its significant contribution to a well-to-wheel (WTW) reduction of greenhouse gas (GHG) emissions. In addition, stringent emission standards make mandatory the use of Diesel Particulate Filter (DPF) for the particulate emissions control. The different physical properties and chemical composition of biofuels impact the overall engine behaviour. In particular, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value (LHV). More specifically, the PM emissions and the related DPF regeneration strategy are clearly affected by biofuel usage due mainly to its higher oxygen content and lower low heating value, respectively. The particle emissions, in fact, are lower mainly because of the higher oxygen content. Subsequently less frequent regenerations are required.

The combustion behaviour, the mechanisms of soot formation, and the emission performance of a mixture of polyoxymethylene dimethyl ethers (POMDME) oligomers with a number of oxymethylene units ranging from 3 to 5, both neat and blended at 12.5% and 50% levels with commercial diesel fuel have been investigated. The goals were a first evaluation of the POMDME impact on the diesel injector behaviour, on the combustion process as well as on the emission performance of a light duty engine. Then a brief screening on the capability to improve the NOx-PM trade-off using POMDME by means of the exhaust gas recirculation (EGR) rate increment was also assessed.

This paper illustrates the results of an experimental study on the impact of a low cetane number (CN) oxygenated fuel on the combustion process and emissions of a light-duty (LD) single-cylinder research engine. In an earlier study, it was concluded that cyclic oxygenates consistently outperformed their straight and branched counterparts at equal oxygen content and with respect to lowering soot emissions. A clear correlation was reported linking soot and CN, with lower CN fuels leading to more favorable soot levels. It was concluded that a lower CN fuel, when realized by adding low reactive cyclic oxygenates to commercial diesel fuel, manifests in longer ignition delays and thus more premixing. Ultimately, a higher degree of premixing, in turn, was thought to suppress soot formation rates.