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A new generation of low heat capacitance Thermal Barrier Coatings (TBCs) has been developed under U.S. Dept. of Energy / Advanced Research Projects Agency - Energy (ARPA-E) sponsored research. The TBCs developed under this project have significantly lower thermal conductivity of < 0.35 W/m-K, thermal heat capacitance of < 500 kJ/m3-K, and density of <0.35 g/cm3. Two different binder types were used for thermal barrier coatings applied by High Velocity Low Pressure (HVLP) spraying to the piston, cylinder head, and valve combustion surfaces of a small natural gas engine. The effects of thermal barrier coatings on engine efficiency and knock characteristics were studied in a small, high compression ratio, spark-ignition, internal combustion engine operating on methane number fuels from 60 to 100. The new TBCs with low thermal conductivity and low thermal heat capacities have been shown to increase overall engine efficiency through reduced heat transfer to the piston and cylinder head.

Dual-fuel reactivity controlled compression ignition (RCCI) combustion is a promising method to achieve high efficiency with near-zero NOx and soot emissions; however, the requirement to carry two fuels on board limits practical application. Advancements in catalytic reforming have demonstrated the ability to generate syngas (a mixture of CO and hydrogen) from a single hydrocarbon stream. This syngas mixture can then be used as the low reactivity fuel stream to enable single fuel RCCI combustion. The present effort uses a combination of engine experiments and system level modeling to investigate reformed fuel RCCI combustion. The impact of reformer composition is investigated by varying the syngas composition from 10% H2 to approximately 80% H2. The results of the investigation show that reformed fuel RCCI combustion is possible over a wide range of H2/CO ratios.

Engine experiments were carried out on a heavy-duty single-cylinder engine to investigate the effects of Gasoline Compression Ignition on emissions and performance of a heavy-duty engine operating at a high load condition. Comparisons between gasoline fueled operation and diesel fueled operation are presented using a single, near top dead center injection. Although the fuel’s cetane numbers are very different, the combustion characteristics of the two fuels at high load are similar, with the gasoline-fueled case showing less than two crank angle degree longer ignition delay. Gasoline operation showed lower soot production at similar levels of NOx, initiating study of the impact of exhaust gas recirculation which spanned a range of NOx levels covering the range from minimal urea dosing to high urea dosing. A conventional soot-NOx tradeoff was found to exist with gasoline as exists with diesel.

Advancements in catalytic reforming have demonstrated the ability to generate syngas (a mixture of CO and hydrogen) from a single hydrocarbon stream. This syngas mixture can then be used to replace diesel fuel and enable dual-fuel combustion strategies. The role of port-fuel injected syngas, comprised of equal parts hydrogen and carbon monoxide by volume was investigated experimentally for soot reduction benefits under a transient load change at constant speed. The syngas used for the experiments was presumed to be formed via a partial oxidation on-board fuel reforming process and delivered through gaseous injectors using a custom gas rail supplied with bottle gas, mounted in the swirl runner of the intake manifold. Time-based ramping of the direct-injected fuel with constant syngas fuel mass delivery from 2 to 8 bar brake mean effective pressure was performed on a multi-cylinder, turbocharged, light-duty engine to determine the effects of syngas on transient soot emissions.

A genetic algorithm (GA) optimization methodology is applied to the design of the combustion system of a heavy-duty (HD) Diesel engine fueled with dimethyl ether (DME). The study has two objectives, the optimization of a conventional diffusion-controlled combustion system aiming to achieve US2010 targets and the optimization of a stoichiometric combustion system coupled with a three way catalyst (TWC) to further control NOx emissions and achieve US2030 emission standards. These optimizations include the key combustion system related hardware, bowl geometry and injection nozzle design as input factors, together with the most relevant air management and injection settings. The GA was linked to the KIVA CFD code and an automated grid generation tool to perform a single-objective optimization. The target of the optimizations is to improve net indicated efficiency (NIE) while keeping NOx emissions, peak pressure and pressure rise rate under their corresponding target levels.

The aim of the present work is to provide further guidance into better understanding the production mechanisms of soot emissions in Spark-Ignition SI engines fueled with compressed natural gas. In particular, extensive experimental investigations were designed with the aim to isolate the contribution of the fuel from that of lubricant oil to particle emissions. This because the common thought is that particulate emerging from the engine derives mainly from fuel, otherwise the contribute of lubricant oil cannot be neglected or underestimated, especially when the fuel itself produces low levels of soot emissions, such as in the case of premixed natural gas. The fuel-derived contribution was studied by analyzing the influence that natural gas composition has on soot emitted from a single cylinder Spark-Ignition (SI) engine. To achieve this purpose, methane/propane mixtures were realized and injected into the intake manifold of a Single-Cylinder SI engine.

Heavy-duty vehicles, currently the second largest source of fuel consumption and carbon emissions are projected to be fastest growing mode in transportation sector in future. There is a clear need to increase fuel efficiency and lower emissions for these engines. The Opposed-Piston Engine (OP Engine) has the potential to address this growing need. In this paper, results are presented for a 9.8L three-cylinder two-stroke OP Engine that shows the potential of achieving 55% brake thermal efficiency (BTE), while simultaneously satisfying emission targets for tail pipe emissions. The two-stroke OP Engines are inherently more cost effective due to less engine parts. The OP Engine architecture presented in this paper can meet this performance without the use of waste heat recovery systems or turbo-compounding and hence is the most cost effective technology to deliver this level of fuel efficiency.

Past research has shown that reactivity controlled compression ignition (RCCI) combustion offers efficiency and NOx and soot advantages over conventional diesel combustion at mid load conditions. However, at high load and low speed conditions, the chemistry timescale of the fuel shortens and the engine timescale lengthens. This mismatch in timescales makes operation at high load and low speed conditions difficult. High levels of exhaust gas recirculation (EGR) can be used to extend the chemistry timescales; however, this comes at the penalty of increased pumping losses. In the present study, targeting the high load - low speed regime, computational optimizations of RCCI combustion were performed at 20 bar gross indicated mean effective pressure (IMEP) and 1300 rev/min. The two fuels used for the study were gasoline (low reactivity) and diesel (high reactivity).

A simple, cheap and effective way of measuring the pressure inside the cylinders of internal combustion engines is proposed in this paper. It is well known that the in-cylinder pressure is one of the most significant variables describing the combustion status in internal combustion engines; therefore, if the measured value of the actual pressure in the combustion chamber is used as a feedback variable for closed loop monitoring and control techniques, it will be possible both to improve engine performances and to reduce fuel consumptions and emissions. However, to date such a pressure-based control strategy has been limited by costs, reliability and lifetime of commercially available cylinder pressure sensors. To overcome these limitations, the present paper proposes a very simple and low cost experimental device for measuring the pressure inside the combustion chamber, developed for engine control and monitoring applications.

Due to the new challenge of meeting number-based regulations for particulate matter (PM), a numerical and experimental study has been conducted to better understand particulate formation in engines fuelled with compressed natural gas. The study has been conducted on a Heavy-Duty, Euro VI, 4-cylinder, spark ignited engine, with multipoint sequential phased injection and stoichiometric combustion. For the experimental measurements two different instruments were used: a condensation particle counter (CPC) and a fast-response particle size spectrometer (DMS) the latter able also to provide a particle size distribution of the measured particles in the range from 5 to 1000 nm. Experimental measurements in both stationary and transient conditions were carried out. The data using the World Harmonized Transient Cycle (WHTC) were useful to detect which operating conditions lead to high numbers of particles. Then a further transient test was used for a more detailed and deeper analysis.

A novel 2-zone combustion chamber concept (patent pending) was developed using multi-dimensional modeling. At minimum volume, an axial projection in the piston divides the volume into distinct zones joined by a communication channel. The projection provides a means to control the mixture formation and combustion phasing within each zone. The novel combustion system was applied to reactivity controlled compression ignition (RCCI) combustion in both light-duty and heavy-duty diesel engines. Results from the study of an 8.8 bar BMEP, 2600 RPM operating condition are presented for the light-duty engine. The results from the heavy-duty engine are at an 18.1 bar BMEP, 1200 RPM operating condition. The effect of several major design features were investigated including the volume split between the inner and outer combustion chamber volumes, the clearance (squish) height, and the top ring land (crevice) volume.

Control of the timing and magnitude of heat release is one of the biggest challenges for premixed compression ignition, especially when attempting to operate at high load. Single-fuel strategies such as partially premixed combustion (PPC) use direct injection of gasoline to stratify equivalence ratio and retard heat release, thereby reducing pressure rise rate and enabling high load operation. However, retarding the heat release also reduces the maximum work extraction, effectively creating a tradeoff between efficiency and noise. Dual-fuel strategies such as reactivity controlled compression ignition (RCCI) use premixed gasoline and direct injection of diesel to stratify both equivalence ratio and fuel reactivity, which allows for greater control over the timing and duration of heat release. This enables combustion phasing closer to top dead center (TDC), which is thermodynamically favorable.

While Low Temperature Combustion (LTC) strategies such as Reactivity Controlled Compression Ignition (RCCI) exhibit high thermal efficiency and produce low NOx and soot emissions, low load operation is still a significant challenge due to high unburnt hydrocarbon (UHC) and carbon monoxide (CO) emissions, which occur as a result of poor combustion efficiencies at these operating points. Furthermore, the exhaust gas temperatures are insufficient to light-off the Diesel Oxidation Catalyst (DOC), thereby resulting in poor UHC and CO conversion efficiencies by the aftertreatment system. To achieve exhaust gas temperature values sufficient for DOC light-off, combustion can be appropriately phased by changing the ratio of gasoline to diesel in the cylinder, or by burning additional fuel injected during the expansion stroke through post-injection.

The present experimental engine efficiency study explores the effects of intake pressure and temperature, and premixed and global equivalence ratios on gross thermal efficiency (GTE) using the reactivity controlled compression ignition (RCCI) combustion strategy. Experiments were conducted in a heavy-duty single-cylinder engine at constant net load (IMEPn) of 8.45 bar, 1300 rev/min engine speed, with 0% EGR, and a 50% mass fraction burned combustion phasing (CA50) of 0.5°CA ATDC. The engine was port fueled with E85 for the low reactivity fuel and direct injected with 3.5% 2-ethylhexyl nitrate (EHN) doped into 91 anti-knock index (AKI) gasoline for the high-reactivity fuel. The resulting reactivity of the enhanced fuel corresponds to an AKI of approximately 56 and a cetane number of approximately 28. The engine was operated with a wide range of intake pressures and temperatures, and the ratio of low- to high-reactivity fuel was adjusted to maintain a fixed speed-phasing-load condition.

Reactivity Controlled Compression Ignition (RCCI) is an engine combustion strategy that utilizes in-cylinder fuel blending to produce low NOx and PM emissions while maintaining high thermal efficiency. The current study investigates RCCI and conventional diesel combustion (CDC) operation in a light-duty multi-cylinder engine over transient operating conditions using a high-bandwidth, transient capable engine test cell. Transient RCCI and CDC combustion and emissions results are compared over an up-speed change from 1,000 to 2,000 rev/min. and a down-speed change from 2,000 to 1,000 rev/min. at a constant 2.0 bar BMEP load. The engine experiments consisted of in-cylinder fuel blending with port fuel-injection (PFI) of gasoline and early-cycle, direct-injection (DI) of ultra-low sulfur diesel (ULSD) for the RCCI tests and the same ULSD for the CDC tests.

Real transportation fuels, such as gasoline and diesel, are mixtures of thousands of different hydrocarbons. For multidimensional engine applications, numerical simulations of combustion of real fuels with all of the hydrocarbon species included exceeds present computational capabilities. Consequently, surrogate fuel models are normally utilized. A good surrogate fuel model should approximate the essential physical and chemical properties of the real fuel. In this work, we present a novel methodology for the formulation of surrogate fuel models based on local optimization and sensitivity analysis technologies. Within the proposed approach, several important fuel properties are considered. Under the physical properties, we focus on volatility, density, lower heating value (LHV), and viscosity, while the chemical properties relate to the chemical composition, hydrogen to carbon (H/C) ratio, and ignition behavior. An error tolerance is assigned to each property for convergence checking.

Previous work has demonstrated the capabilities of gasoline compression ignition to achieve engine loads as high as 19.5 bar BMEP with a production multi-cylinder diesel engine using gasoline with an anti-knock index (AKI) of 87. In the current study, the low load limit of the engine was investigated using the same engine hardware configurations and 87 AKI fuel that was used to achieve 19.5 bar BMEP. Single injection, “minimum fueling” style injection timing and injection pressure sweeps (where fuel injection quantity was reduced at each engine operating condition until the coefficient of variance of indicated mean effective pressure rose to 3%) found that the 87 AKI test fuel could run under stable combustion conditions down to a load of 1.5 bar BMEP at an injection timing of −30 degrees after top dead center (°aTDC) with reduced injection pressure, but still without the use of intake air heating or uncooled EGR.

3-D Computational Fluid Dynamics (CFD) simulations have been performed to study particulate formation in a Spark-Ignition (SI) engine under premixed conditions. A semi-detailed soot model and a chemical kinetic model, including poly-aromatic hydrocarbon (PAH) formation, were coupled with a spark ignition model and the G equation flame propagation model for SI engine simulations and for predictions of soot mass and particulate number density. The simulation results for in-cylinder pressure and particle size distribution (PSDs) are compared to available experimental studies of equivalence ratio effects during premixed operation. Good predictions are observed with regard to cylinder pressure, combustion phasing and engine load. Qualitative agreements of in-cylinder particle distributions were also obtained and the results are helpful to understand particulate formation processes.

A comprehensive biodiesel combustion model is presented for use in multi-dimensional engine simulations. The model incorporates realistic physical properties in a vaporization model developed for multi-component fuel sprays and applies an improved mechanism for biodiesel combustion chemistry. Previously, a detailed mechanism for methyl decanoate and methyl-9-decenoate was reduced from 3299 species to 85 species to represent the components of biodiesel fuel. In this work, a second reduction was performed to further reduce the mechanism to 69 species. Steady and unsteady spray simulations confirmed that the model adequately reproduced liquid penetration observed in biodiesel spray experiments. Additionally, the new model was able to capture expected fuel composition effects with low-volatility components and fuel blend sprays penetrating further.

Diesel fuels are complex mixtures of thousands of hydrocarbons. Since modeling their combustion characteristics with the inclusion of all hydrocarbon species is not feasible, a hybrid surrogate model approach is used in the present work to represent the physical and chemical properties of three different diesel fuels by using up to 13 and 4 separate hydrocarbon species, respectively. The surrogates are arrived at by matching their distillation profiles and important properties with the real fuel, while the chemistry surrogates are arrived at by using a Group Chemistry Representation (GCR) method wherein the hydrocarbon species in the physical property surrogates are grouped based on their chemical classes, and the chemistry of each class is represented by using up to two hydrocarbon species.