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Technical Paper

Influence of Zn, Mo, P, S-contained Engine Oil Additives on Abnormal Combustion in a Spark Ignition Engine

2020-01-24
2019-32-0586
A Spark Ignition Engine has some kinds of problem to be solved over many years, one of them is abnormal combustion; Low-speed pre-ignition (LSPI) under low-speed, high-load driving conditions for vehicle, and pre-ignition under longterm operation without cleaning a combustion chamber for gas cogeneration. As a cause for abnormal combustion, engine oil droplets diluted by liquid fuel and peeled combustion deposits delivered from engine oil are proposed. In this study, experiments were conducted focusing on engine oil additives having different chemical structure and abnormal combustion behavior. A four-stroke side-valve single cylinder engine that allowed in-cylinder visualization of the combustion flame was used in the experiments. The experimental results showed that the influence of DTC additive on abnormal combustion is small and the zinc component contained in the DTP additives had the effect of advancing the autoignition timing.
Technical Paper

Influence of Calcium-Based Additives with Different Properties on Abnormal Combustion in an SI Engine

2016-11-08
2016-32-0007
Technologies for further improving vehicle fuel economy have attracted widespread attention in recent years. However, one problem with some approaches is the occurrence of abnormal combustion such as low-speed pre-ignition (LSPI) that occurs under low-speed, high-load operating conditions. One proposed cause of LSPI is that oil droplets diluted by the fuel enter the combustion chamber and become a source of ignition. Another proposed cause is that deposits peel off and become a source of ignition. A four-stroke air-cooled single-cylinder engine was used in this study to investigate the influence of Ca-based additives having different properties on abnormal combustion by means of in-cylinder visualization and absorption spectroscopic measurements. The results obtained for neutral and basic Ca-based additives revealed that the former had an effect on advancing the time of autoignition.
Journal Article

Influence of Ca-, Mg- and Na-Based Engine Oil Additives on Abnormal Combustion in a Spark-Ignition Engine

2015-11-17
2015-32-0771
One issue of downsized and supercharged engines is low-speed pre-ignition (LSPI) that occurs in the low-speed and high-load operating region. One proposed cause of LSPI is the influence of the engine oil and its additives. However, the effect of engine oil additives on pre-ignition and the mechanism involved are still not fully understood. This study investigated the influence of engine oil additives on abnormal combustion in a spark-ignition engine. A four-stroke air-cooled single-cylinder engine with a side valve arrangement was used in conducting combustion experiments. The research methods used were in-cylinder pressure analysis, in-cylinder visualization and absorption spectroscopic analysis. Engine oil additives were mixed individually at a fixed concentration into a primary reference fuel with an octane number of 50 and their effect on knocking was investigated.
Journal Article

Abnormal Combustion Induced by Combustion Chamber Deposits Derived from Engine Oil Additives in a Spark-Ignited Engine

2014-11-11
2014-32-0091
Although metallic compounds are widely known to affect combustion in internal combustion engines, the potential of metallic additives in engine oils to initiate abnormal combustion has been unclear. In this study, we investigated the influence of combustion chamber deposits derived from engine oil additives on combustion in a spark-ignited engine. We used a single-cylinder four-stroke engine, and measured several combustion characteristics (e.g., cylinder pressure, in-cylinder ultraviolet absorbance in the end-gas region, and visualized flame propagation) to evaluate combustion anomalies. To clarify the effects of individual additive components, we formed combustion products of individual additives in a combustion chamber prior to measuring combustion characteristics. We tested three types of metallic additives: a calcium-based detergent, a zinc-based antiwear agent, and a molybdenum-based friction modifier.
Journal Article

A Study on the Effect of a Calcium-Based Engine Oil Additive on Abnormal SI Engine Combustion

2014-11-11
2014-32-0092
Supercharged direct-injection engines are known to have a tendency toward abnormal combustion such as spontaneous low-speed pre-ignition and strong knock because they operate under low-speed, high-load conditions conducive to the occurrence of irregular combustion. It has been hypothesized that one cause of such abnormal combustion is the intrusion of engine oil droplets into the combustion chamber where they become a source of ignition. It has also been reported that varying the composition of engine oil additives can change susceptibility to abnormal combustion. However, the mechanisms involved are not well understood, and it is not clear how the individual components of engine oil additives affect autoignition. In this study, abnormal combustion experiments were conducted to investigate the effect on autoignition of a calcium-based additive that is typically mixed into engine oil to act as a detergent.
Journal Article

A Study on the Effect of Zn- and Mo-Based Engine Oil Additives on Abnormal SI Engine Combustion using In-Cylinder Combustion Visualization

2014-11-11
2014-32-0096
Spontaneous low-speed pre-ignition, strong knock and other abnormal combustion events that occur in supercharged direct-injection engines are viewed as serious issues. The effects of the engine oil and the components of engine oil additives have been pointed out as one cause of such abnormal combustion. However, the mechanisms involved have yet to be elucidated, and it is unclear how the individual components of engine oil additives influence autoignition. This study investigated the effect on autoignition of boundary lubricant additives that are mixed into the engine oil for the purpose of forming a lubricant film on metal surfaces. A high-speed camera was used to photograph and visualize combustion through an optical access window provided in the combustion chamber of the four-stroke naturally aspirated side-valve test engine. Spectroscopic measurements were also made simultaneously to investigate the characteristics of abnormal combustion in detail.
Technical Paper

A Study of Supercharged HCCI Combustion Using Blended Fuels of Propane and DME

2014-11-11
2014-32-0005
Homogeneous Charge Compression Ignition (HCCI) has attracted a great deal of interest as a combustion system for internal combustion engines because it achieves high efficiency and clean exhaust emissions. However, HCCI combustion has several issues that remain to be solved. For example, it is difficult to control engine operation because there is no physical means of inducing ignition. Another issue is the rapid rate of heat release because ignition of the mixture occurs simultaneously at multiple places in the cylinder. The results of previous investigations have shown that the use of a blended fuel of DME and propane was observed that the overall combustion process was delayed, with that combustion became steep when injected propane much. This study focused on expanding the region of stable engine operation and improving thermal efficiency by using supercharging and blended fuels. The purpose of using supercharging were in order to moderated combustion.
Journal Article

Analysis of Combustion Characteristics and Efficiency Improvement of a Supercharged HCCI Engine Achieved by Using the Different Ignition Characteristics of Gaseous Fuels

2012-10-23
2012-32-0075
This study focused on the use of a two-component fuel blend and supercharging as possible means of overcoming these issues of HCCI combustion. Low-carbon gaseous fuels with clean emissions were used as the test fuels. The specific fuels used were dimethyl ether (DME, cetane number of 55 or higher) that autoignites easily And exhibits pronounced low-temperature oxidation reactions, methane (cetane number of 0) that does not autoignite readily and is the main component of natural gas which is regarded as petroleum substitute, and propane (cetane number of 5) that is a principal component of liquefied petroleum gas. The results of previous investigations have shown that the use of a blended fuel of DME and methane produces a two-stage main combustion process under certain operating conditions, with the result that combustion is moderated.
Technical Paper

The Effects of the Compression Ratio, Equivalence Ratio, and Intake Air Temperature on Ignition Timing in an HCCI Engine Using DME Fuel

2005-10-12
2005-32-0002
Attention has recently been focused on homogeneous charge compression ignition combustion (HCCI) as an effective combustion process for resolving the essential nature of combustion. Meanwhile, dimethylether (DME) has attracted interest as a potential alternative fuel for compression ignition engines. Authors measured the combustion process of DME HCCI by using a spectroscopic method. A diesel engine was used as the test engine. The results of these analyses showed that changes in the compression ratio, intake air temperature and equivalence ratio influenced the ignition timing in the HCCI combustion process. This paper discusses these effects in reference to the experimental and calculated results.
Technical Paper

Measurement of Radical Behavior in Homogeneous Charge Compression Ignition Combustion Using Dimethyl Ether

2003-09-16
2003-32-0006
Attention has recently been focused on homogeneous charge compression ignition (HCCI) as an effective combustion process for resolving issues inherent to the nature of combustion. Dimethyl ether (DME; CH3OCH3) has attracted interest as a potential alternative fuel for compression ignition engines. We measured the HCCI process of DME in a test diesel engine by using a spectroscopic method. Simultaneous measurements were also done on exhaust emissions of hydrocarbons (HC), carbon monoxide (CO) and nitrogen oxides (NOx). Based on the experimental data, this paper discusses the relationship between the equivalence ratio and the observed tendencies.
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