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In pursuing sustainable automotive technologies, exploring alternative fuels for hybrid vehicles is crucial in reducing environmental impact and aligning with global carbon emission reduction goals. This work compares methanol and naphtha as potential suitable alternative fuels for running in a battery-driven light-duty hybrid vehicle by comparing their performance with the diesel baseline engine. This work employs a 0-D vehicle simulation model within the GT-Power suite to replicate vehicle dynamics under the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The vehicle choice enables the assessment of a delivery application scenario using distinct payload capacities: 0%, 25%, 50%, and 100%. The model is fed with engine maps derived from previous experimental work conducted in the same engine, in which a full calibration was obtained that ensures the engine's operability in a wide region of rotational speed and loads.

Ammonia has emerged as a promising carbon-free alternative fuel for internal combustion engines (ICE), particularly in large-bore engine applications. However, integrating ammonia into conventional engines presents challenges, prompting the exploration of innovative combustion strategies like dual-fuel combustion. Nitrous oxide (N2O) emissions have emerged as a significant obstacle to the widespread adoption of ammonia in ICE. Various studies suggest that combining exhaust gas recirculation (EGR) with adjustments in inlet temperature and diesel injection timing can effectively mitigate nitrogen oxides (NOx) emissions across diverse operating conditions in dual-fuel diesel engines.

In the perspective of a reduction of emissions and a rapid decarbonisation, especially for compression ignition engines, hydrogen plays a decisive role. The dual fuel technology is perfectly suited to the use of hydrogen, a fuel characterized by great energy potential. In fact, replacing, at the same energy content, the fossil fuel with a totally carbon free one, a significant reduction of the greenhouse gases, like carbon dioxide and total hydrocarbon, as well as of the particulate matter can be obtained. The dual fuel with indirect injection of gaseous fuel in the intake manifold, involves the problem of hydrogen autoignition. In order to avoid this difficulty, the optimal conditions for the injection of the incoming mixture into the cylinder were experimentally investigated. All combustion processes are carried out on a research engine with optical access. The engine speed has is set at 1500 rpm, while the EGR valve is deactivated.

Predicting and preventing combustion anomalies leads to safe and efficient operation of the hydrogen internal combustion engine. This research presents the application of three machine learning (ML) models – K-Nearest Neighbors (KNN), Random Forest (RF) and Logistic Regression (LR) – for the prediction of combustion anomalies in a hydrogen internal combustion engine. A small experimental dataset was used to train the models and posterior experiments were used to evaluate their performance and predicting capabilities (both in operating points -speed and load- within the training dataset and operating points in other areas of the engine map). KNN and RF exhibit superior accuracy in classifying combustion anomalies in the training and testing data, particularly in minimizing false negatives, which could have detrimental effects on the engine.

With the aim of decarbonizing the vehicles fleet, the use of hydrogen is promising solution. Hydrogen is an energy carrier, carbon-free, with high calorific value and with no CO2 and HC emissions burning in ICE. Hydrogen use in spark ignition engines has already been extensively investigated and optimized. On the other hand, its use in compression ignition engines has been little developed and, therefore, there is a lack of information regarding the combustion in ultra-lean conditions, typical of diesel engines. Several applications employ dual fuel combustion for the easy management of the PFI injection system to be applied in addition to the DI Common Rail system. However, this mode suffers from several problems regarding the management of the maximum flow rate of hydrogen into the intake. In particular, to avoid throwing hydrogen into the exhaust, injection must be started after the valve crossing.

The transport of goods and people by sea, today, must meet the need to reduce the consumption of fuel oil. In addition, it has to ensure operational reliability and vessel availability, to reduce maintenance costs and comply with emission legislation. To this end, it is necessary to apply a marine engine combustion control system already widely used in engines for land transport. This will allow the ship's engines to operate reliably and in compliance with the best performance for which it was designed. The combustion control could also ensure a more balanced operation of the cylinders and reduce the torsional vibrations of the entire engine, as well as the management of the engine according to the adopted fuel: diesel, dual fuel, methanol, ammonia. Generally, the control of combustion in engines is carried out through the use of pressure sensors that face directly into the combustion chamber.

Electrification of transport, together with the decarbonization of energy production are suggested by the European Union for the future quality of air. However, in the medium period, propulsion systems will continue to dominate urban mobility, making mandatory the retrofitting of thermal engines by applying combustion modes able to reduce NOx and PM emissions while maintaining engine performances. Low Temperature Combustion (LTC) is an attractive process to meet this target. This mode relies on premixed mixture and fuel lean in-cylinder charge whatever the fuel type: from conventional through alternative fuels with a minimum carbon footprint. This combustion mode has been subject of numerous modelling approaches in the engine research community. This study provides a theoretical comparative analysis between multi-zone (MZ) and Transported probability density function (TPDF) models applied to LTC combustion process.

Using renewable fuels is a reliable approach for decarbonization of combustion engines. iso-Butanol and n-butanol are known as longer chain alcohols and have the potential of being used as gasoline substitute or a renewable fraction of gasoline. The combustion behavior of renewable fuels in modern combustion engines and advanced combustion concepts is not well understood yet. Low-temperature combustion (LTC) is a concept that is a basis for some of the low emissions-high efficiency combustion technologies. Fuel ɸ-sensitivity is known as a key factor to be considered for tailoring fuels for these engines. The Lund ɸ-sensitivity method is an empirical test method for evaluation of the ɸ-sensitivity of liquid fuels and evaluate fuel behavior in thermal. iso-Butanol and n-butanol are two alcohols which like other alcohol exhibit nonlinear behavior when blended with (surrogate) gasoline in terms of RON and MON.

With a view to reducing the environmental impact of fossil fuels, advanced lignin-based biofuels could provide a valuable contribute, since lignin is the most abundant biopolymer on earth after cellulose. However, its thermophysical properties would hamper its use as a pure fuel. In this work we investigated the combustion behavior of sprays of a liquid lignin-methanol blend and evaluated its potential as a low-carbon marine fuel for large two-stroke engines. To this end, an experimental campaign was conducted in an optically accessible combustion chamber whose main dimensions correspond to those of a single cylinder for large two-stroke engines. The chamber is provided with optical accesses for optical diagnostics of the combustion process. The combustion of the mixture was ignited using a diesel pilot jet as the ignition source. Two marine injectors are mounted in the chamber, namely “main” and “pilot” injectors.

The last environmental regulations on passenger vehicles’ emissions harden constraints on designing powertrains. A promising solution consists in vehicle electrification leading to hybrid configurations: the tank-to-wheel pollutant emissions can be drastically reduced combining features of typical battery electric vehicles adding an Internal Combustion Engine (ICE) controlled as a Range Extender (REX). Furthermore, HC and CO/CO2 emissions can be avoided using green hydrogen as fuel for the ICE; moreover, in absence of a mechanical coupling between REX and wheels the best operating conditions in terms of maximum ICE efficiency may be easily achieved. In this work, a light quadricycle (EU L6e, classification) series hybrid vehicle with four in-wheel motors is studied for the application of a range extender system.

The growing concern about Greenhouse Gas (GHG) emissions led institutions to further reduce the limits on vehicle-related CO2 emissions. Therefore, car manufacturers are developing vehicles with low environmental impact, like Hybrid-Electric Vehicles (HEVs), which in the series architecture employ an Internal Combustion Engine (ICE) coupled with an electric generator for battery recharging, thus extending the range of a Battery Electric Vehicle (BEV). For this kind of application, small four-stroke Spark Ignition (SI) engines are preferred, as they are a proven and reliable solution to increase the driving range with very low environmental impact. In series hybrid-electric powertrains, the ICE is decoupled from the drive wheels, then it can operate in a steady-state high-efficiency working point, regardless of the power required by the mission profile. The benefits of lean combustion can be exploited to increase efficiency and reduce CO2 and NOx emissions.

Methanol is currently being evaluated as a promising alternative fuel for internal combustion engines, due to being attainable by carbon neutral or negative pathways (renewable energy and carbon capture technology). The low ignitability of methanol has made it attractive mostly as a fuel for spark ignition engines, however the low sooting properties of the fuel could potentially reduce the NOx-soot tradeoff present in compression ignition engines. In this work, using a 4-cylinder engine with compression ratio modified from 16:1 to 19:1, methanol combustion is evaluated under five operating conditions in terms of fuel consumption, criteria pollutants, CO2 emissions and engine efficiency in addition to the qualitative assessment of the combustion stability. It was found that combustion is stable at medium to high loads, with medium load NOx emissions levels at least 30% lower than the original diesel engine and comparable emissions at maximum load conditions.

Although in the latest years the use of compression ignition engines has been a thread of discussion in the automotive field, it is possible to affirm that it still will be a fundamental producer of mechanical power in other sectors, such as naval and off-road applications. However, the necessity of reducing emissions requires to keep on studying new solutions for this kind of engine. Dual fuel combustion concept with methane has demonstrated to be effective in preserving the performance of the original engine and reducing soot, but issues related to the low flame speed forced researcher to find an alternative fuel at low impact of CO2. Hydrogen, thanks to its chemical and physical properties, can be a perfect candidate to ensure a good level of combustion efficiency; however, this is possible only with a proper management of the in-cylinder mixture ignition by means of a pilot injection, preventing uncontrolled autoignition events as well.

In order to reduce fuel consumption and polluting emissions from engines, alternative fuels such as hydrogen could play an important role towards carbon neutrality. Moreover, dual-fuel (DF) technology has the potential to offer significant improvements in carbon dioxide emissions for transportation and energy sectors. The dual fuel concept (natural gas/diesel or hydrogen/diesel) represents a possible solution to reduce emissions from diesel engines by using low-carbon or carbon-free gaseous fuels as an alternative fuel. Moreover, DF combustion is a possible retrofit solution to current diesel engines by installing a PFI injector in the intake manifold while diesel is injected directly into the cylinder to ignite the premixed mixture. In the present study, dual fuel operation has been investigated in a single cylinder research engine.

The transportation industry has been scrutinized for its contribution towards the global greenhouse gas emissions over the years. While the automotive sector has been regulated by strict emission legislation globally, the emissions from marine transportation have been largely neglected. However, during the past decade, the international maritime organization focused on ways to lower the emission intensity of the marine sector by introducing several legislations. This sets limits on the emissions of different oxides of carbon, nitrogen and sulphur, which are emitted in large amounts from heavy fuel oil (HFO) combustion (the primary fuel for the marine sector). A 40% and 70% reduction per transport work compared to the levels of 2008 is set as target for CO2 emission for 2030 and 2050, respectively. To meet these targets, commonly, methanol, as a low-carbon fuel, and ammonia, as a zero-carbon fuel, are considered.

Focusing on coastal or inland navigation cities, where emissions from ships are not negligible concerning global ones, the possibility of reducing exhaust gas pollution would have more benefits for public health and air quality. Therefore, in recent years, increasing attention on environmental sustainability is driving the shipbuilding industry towards greener propulsion based on full-electric or hybrid-electric propulsion systems. This work is presented a parallel hybrid system composed of two electric motors, one internal combustion engine, and lithium battery storage. All motors are coupled to the propeller through a specially designed transmission system based on the High Sliding Gear theory (HSG). The hybrid-electric propulsion system is designed to extender the battery pack durability, ensuring a smooth profile of the required current, through the complementary action of the batteries and the internal combustion engine.

In this work, an ozone/air/gasoline mixture has been used as an alternative strategy to achieve a stable combustion in a spark ignition (SI) single cylinder PFI research engine. The air intake manifold has been modified to include four cells to produce ozone with different concentrations. In the research engine, various operating parameters have been monitored such as the in-cylinder pressure, temperature and composition of the exhaust gases, pressure and temperature of the mixture in the intake manifold, engine power and torque and specific fuel consumption. Experimental tests have been carried out under stoichiometric mixture conditions to observe the influence of ozone addition on the combustion process. The results show an advance and an increase of the in-cylinder pressure compared to the reference test-case, where a gasoline/air mixture is used. It is worth noting that, especially under stoichiometric condition, ozone concentration induces auto-ignition and knock.

The urban mobility electrification has been proposed as the main solution to the vehicle emission issues in the next years. However, internal combustion engines have still great potential to decarbonize the transport sector through the use of low/zero-carbon fuels. Alcohols such us methanol, have long been considered attractive alternative fuels for spark ignition engines. They have properties similar to those of gasoline, are easy to transport and store. Recently, great attention has been devoted to gaseous fuels that can be used in existing engine after minor modification allowing to drastically reduce the pollutant emissions. In this regard, this study tries to provide an overview on the use of alternative fuels, both liquid and gaseous in spark ignition engines, highlighting the benefits as well as the criticalities. The investigation was carried out on a small displacement spark ignition engine capable to operate both in port fuel and direct injection mode.

Hybrid electric vehicles are a suitable solution for the transition from fossil fuels-based transportation to electric mobility. They have the benefits of zero-emissions operation when only the electric engine is used preventing the typical range anxiety of full-electric vehicles. Also, they can have a low battery pack capacity and weight thanks to the continuous recharge from the internal combustion engine that becomes the only responsible for exhaust emissions. A practical solution to limit the combustion engine emissions is represented by the range extender configuration, where the engine works at a fixed operating point with the highest efficiency serving uniquely as a battery charger. In the face of the current world situation and future changes, research for alternative energy sources is crucial. Hydrogen can be used as an alternative fuel for common internal combustion engines; moreover, it has the great advantage of high efficiency (about 44%).

Direct injection spark ignition engines represent an effective technology to achieve the goal of carbon dioxide emission reduction. Further reduction of the carbon footprint can be achieved by using carbon-neutral fuels. Oxygenated alcohols are well consolidated fuels for spark ignition engines providing also the advantages of knock resistance and low soot tendency production. Methanol and ethanol are possible candidates as alternative fuels to gasoline due to their similar properties. In this study a blend at 25 % v/v of ethanol in gasoline (E25) and a blend with 80% gasoline, 5 % v/v ethanol and 15% v/v of methanol (GEM) were tested. These blends were considered since E25 is already available at fuel pump in some countries. The GEM blend, instead, could represent a valid alternative in the next future. Experiments were carried out on a high performance, turbocharged 1.8 L direct injection spark ignition engine over the Worldwide Harmonized Light Vehicles Test Cycle.