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We have proposed the application of Exhaust Gas Recirculation (EGR) gas dissolved fuel which might improve spray atomization through effervescent atomization instead of high injection pressure. Since EGR gas is included in the spray of EGR gas dissolved fuel, it directly contributes to combustion, and the further reduction of NOx emissions is expected rather than the conventional external EGR. In our research, since highly contained in the exhaust gas and highly soluble in the fuel, CO2 was selected as the dissolved gas to simulate EGR gas dissolved. In this paper, the purpose is to evaluate the influence of the application of CO2 gas dissolved fuel on the combustion characteristics and emission characteristics inside the single cylinder, direct injection diesel engine. As a result, by use of the fuel, smoke was reduced by about 50 to 70%, but NOx reduction does not have enough effect.

For developing complicated after-treatment equipment for diesel-engine vehicles, such as urea-selective catalytic reduction (urea-SCR) systems, construction of a reaction model that can accurately predict ammonia (NH3) formation from urea is required. Hydrolysis of isocyanic acid (HNCO) is an important intermediate reaction in NH3 formation from urea. In our previous studies [1], a new rate constant for HNCO hydrolysis over fresh Cu-ZSM5 was derived using the measurements of the reaction rate of HNCO hydrolysis with high-purity HNCO formed from cyanuric acid. In this study, the reaction rates of the HNCO hydrolysis and NH3-SCR reactions were measured over a hydrothermally aged Cu-ZSM5 catalyst. A steady-state flow reactor equipped with a Fourier transform infrared spectrometer (FTIR) was employed to obtain the reaction rate of the HNCO hydrolysis and NH3-SCR reactions.

This study employed a diesel particulate generator (DPG), with an installed engine oil injector for soot and ash accumulation in a diesel particulate filter (DPF). Ash was generated by engine oil injection into the diesel burner flame. The amount of soot accumulation per loading varied from 0.5 g/L to 8 g/L while ash accumulation amount per loading was maintained at 0.5 g/L. Initially, ash accumulation distribution in the DPF was visualized using X-ray computed tomography (CT). It was revealed that the form of ash accumulation changed depending on the amount of soot accumulation before active regeneration, i.e., a large amount of soot accumulation resulted in plug ash, whereas a small amount of soot accumulation resulted in wall ash. To clarify ash accumulation mechanisms, soot and ash transport behavior in DPF during active regeneration process was directly observed using a high-speed camera through an optically accessible D-shaped cut DPF covered with a quartz glass plate.

In previous study, the model for flash-boiling spray of multicomponent fuel was constructed and was implemented into KIVA code. This model considered the detailed physical properties and evaporation process of multicomponent fuel and the bubble nucleation, growth and disruption in a nozzle orifice and injected fuel droplets. These numerical results using this model were compared with experimental data which were obtained in the previous study using a constant volume vessel. The spray characteristics from numerical simulation qualitatively showed good agreement with the experimental results. Especially, it was confirmed from both the numerical and experimental data that flash-boiling effectively accelerated the atomization and vaporization of fuel droplets. However, in this previous study, injection pressure was very low (up to 15 MPa), and the spray characteristics of high pressure injection could not be analyzed.

We have proposed the application of EGR gas dissolved fuel which might improve spray atomization through effervescent atomization instead of high injection pressure. In this paper, the purpose is to evaluate the influence of the application of CO2 gas dissolved fuel on the combustion characteristics and emissions inside the single cylinder, direct injection diesel engine. As a result, by use of the fuel, smoke was reduced by about 50 to 70%. The amount of NOx was reduced at IMEP=0.3 MPa, but it was increased at IMEP=0.9 MPa.

In-cylinder total sampling technique utilizing a single-cylinder diesel engine equipped with hydraulic valve actuation system has been developed. In this study, particulate matter (PM) included in the in-cylinder sample gas was collected on a quartz filter, and the polycyclic-aromatic hydrocarbons (PAHs) component and soot were subsequently quantified by thermal desorption-gas chromatograph mass spectrometry (TD-GCMS) and a carbon analyzer, respectively. Cylinder-averaged histories of PAHs and soot were obtained by changing the sampling timing. It was found that decreasing intake oxygen concentration suppresses in-cylinder soot oxidation, and the fuel with higher aromatic and naphthenic contents accelerates soot production.

This work investigated the mechanism of oil dilution by post injection to remove accumulated particulate matter on the diesel particulate filter of diesel engines. We developed a model to simulate post injection spray under low ambient gas pressure conditions. The model can predict the quantity of fuel mass adhered on the cylinder wall. The adhered fuel enters oil sump through the piston ring and cause oil dilution. The fuel in diluted oil evaporates during normal engine operations. We focus on the mechanism of fuel evaporation from diluted oil. The effects of engine speed and oil temperature on the evaporation were investigated. The results showed that the fuel evaporation rate increases with increasing engine speed and oil temperature. Furthermore, we developed an empirical model to predict the fuel evaporation rate of diluted oil through regression analysis with measured data.

To meet the strict emission regulations for diesel engines, an advanced processing device such as a Urea-SCR (selective catalytic reduction) system is used to reduce NOx emissions. The Real Driving Emissions (RDE) test, which is implemented in the European Union, will expand the range of conditions under which the engine has to operate [1], which will lead to the construction of a Urea-SCR system capable of reducing NOx emissions at lower and higher temperature conditions, and at higher space velocity conditions than existing systems. Simulations are useful in improving the performance of the urea-SCR system. However, it is necessary to construct a reliable NOx reduction model to use for system design, which covers the expanded engine operation conditions. In the urea-SCR system, the mechanism of ammonia (NH3) formation from injected aqueous urea solution is not clear. Thus, it is important to clarify this mechanism to improve the NOx reduction model.

White smoke emission is observed at the tailpipe of diesel vehicles when unburned hydrocarbons (HCs) are adsorbed on a diesel oxidation catalyst (DOC) under low exhaust gas temperature. The purpose of this study is to gain a better understanding of white smoke emission derived from HCs, and to reduce emission levels. First, the components of HCs and the particle size distribution of white smoke emission were analyzed. It was clarified that semi-volatile organic compounds (SVOC) and water are condensed around soluble organic fraction and the order of particle size in white smoke is submicron scale. Additionally, the correlation between the behavior of white smoke emission and the amount/quality of HCs adsorbed on a DOC were investigated by examining the change of zeolite content in the DOC. It was found that the heavy HCs ratio in adsorbed HCs on DOC increases with a decrease in zeolite content when DOC inlet gas temperature is 120 °C.

The CO2 gas dissolved fuel for the diesel combustion is effective to reduce the NOx emissions to achieve the internal EGR (Exhaust Gas Recirculation) effect by fuel. This method has supplied EGR gas to the fuel side instead of supply EGR gas to the intake gas side. The fuel has followed specific characteristics for the diesel combustion. When the fuel is injected into the chamber in low pressure, this CO2 gas is separated from the fuel spray. The distribution characteristics of the spray are improved and the improvement of the thermal efficiency by reduction heat loss in the combustion chamber wall, and reduce soot emissions by the lean combustion is expected. Furthermore, this CO2 gas decreases the flame temperature. Further, it is anticipated to reduce NOx emissions by the spray internal EGR effect.

In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.

Diesel Particulate Filter (DPF) is a very effective aftertreatment device to limit particulate emissions from diesel engines. As the amount of soot collected in the DPF increases, the pressure loss increases. Therefore, DPF regeneration needs to be performed. Injected fuel into the exhaust line upstream of the Diesel Oxidation Catalyst (DOC), hydrocarbons are oxidized on the DOC, which increases the exhaust gas temperature at the DPF inlet. It is also necessary that the injected fuel is completely vaporized before entering the DOC, and uniformly mixed with the exhaust gases in order to make the DOC work efficiency. However, ensuring complete evaporation and an optimum mixture distribution in the exhaust line are challenging. Therefore, it is important that the fuel spray feature is grasped to perform DPF regeneration effectively. The purpose of this study is the constructing a simulation model.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest as a combustion system that offers the advantages of high efficiency and low exhaust emissions. However, it is difficult to control the ignition timing in an HCCI combustion system owing to the lack of a physical means of initiating ignition like the spark plug in a gasoline engine or fuel injection in a diesel engine. Moreover, because the mixture ignites simultaneously at multiple locations in the cylinder, it produces an enormous amount of heat in a short period of time, which causes greater engine noise, abnormal combustion and other problems in the high load region. The purpose of this study was to expand the region of stable HCCI engine operation by finding a solution to these issues of HCCI combustion.

Internal combustion engines today are required to achieve even higher efficiency and cleaner exhaust emissions. Currently, research interest is focused on premixed compression ignition (Homogeneous Charge Compression Ignition, HCCI) combustion. However, HCCI engines have no physical means of initiating ignition such as a spark plug or the fuel injection timing and quantity. Therefore, it is difficult to control the ignition timing. In addition, combustion occurs simultaneously at multiple sites in the combustion chamber. As a result, combustion takes place extremely rapidly especially in the high load region. That makes it difficult for the engine to operate stably at high loads. This study focused on the fuel composition as a possible means to solve these problems. The effect of using fuel blends on the HCCI operating region and combustion characteristics was investigated using a single-cylinder test engine.

Fuel design approach has been proposed as the control technique of spray and combustion processes in diesel engine to improve thermal efficiency and reduce exhaust emissions. In order to kwow if this approach is capable of controlling spray flame structure and interaction between the flame and a combustion chamber wall, the present study investigated ignition and flame characteristics of dual-component fuels, while varying mixing fraction, fuel temperature and ambient conditions. Those characteristics were evaluated through chemiluminescence photography and luminous flame photography. OH radical images and visible luminous flame images were analyzed to reveal flame shape aspect ratio and its fractal dimension.

One of the authors has proposed to use the decay rate of EHRR, the effective heat release rate, d2Q/dθ2 as an index for the rapid local combustion [1]. In this study, EHRR profiles and the cylinder gas pressure oscillations of the low and high speed knock are analyzed by using this index. A delayed rapid local combustion, such as an autoignition with small burned mass fraction can be detected. In the cases of the low speed knock, it has been agreed that a rapid local combustion is an autoignition. Although whether the cylinder gas oscillation is provoked by an auto ignition in a certain cycle or not is an irregular phenomenon, the auto ignition takes place in almost all of the cycles in the knocking condition. Mixture mass fraction burned by an auto ignition is large. A small auto ignition may induce a secondary auto ignition, in many cases, mass burned by the secondary auto ignition is extremely large.

The ignition characteristics of each component of natural gas and the chemical kinetic factors determining those characteristics were investigated using detailed chemical kinetic calculations. Ethane (C2H6) showed a relatively short ignition delay time with high initial temperature; the heat release profile was slow in the early stage of the ignition process and rapid during the late stage. Furthermore, the ignition delay time of C2H6 showed very low dependence on O2 concentration. In the ignition process of C2H6, HO2 is generated effectively by several reaction paths, and H2O2 is generated from HO2 and accumulated with a higher concentration, which promotes the OH formation rate of H2O2 (+ M) = OH + OH (+ M). The ignition characteristics for C2H6 can be explained by H2O2 decomposition governing OH formation at any initial temperature.

The interaction between spark discharge and low-temperature oxidation (LTO) was investigated using an optical compression and expansion machine fueled with n-C7H16 or i-C8H18 for an equivalence ratio of 0.33. Charge pressure was adjusted so that the compression stoke could induce LTO for n-C7H16, but could not lead to high-temperature reactions. A spark was discharged in the field before, during, or after the LTO for n-C7H16 or in the field without LTO for i-C8H18. Reaction zones were induced in the field after the LTO, whereas no reaction zones were induced in the fields before the LTO and without LTO. Local ignitions were induced in the areas surrounding the propagating reaction zones. The reaction zone propagation with the low equivalence ratio must be a different phenomenon from conventional flame propagation. The reaction zones can compress or heat the surrounding areas containing H2O2 and CH2O, and accelerate an H2O2 regeneration loop in the pre-reaction zones.

Homogeneous Charge Compression Ignition (HCCI) has attracted a great deal of interest as a combustion system for internal combustion engines because it achieves high efficiency and clean exhaust emissions. However, HCCI combustion has several issues that remain to be solved. For example, it is difficult to control engine operation because there is no physical means of inducing ignition. Another issue is the rapid rate of heat release because ignition of the mixture occurs simultaneously at multiple places in the cylinder. The results of previous investigations have shown that the use of a blended fuel of DME and propane was observed that the overall combustion process was delayed, with that combustion became steep when injected propane much. This study focused on expanding the region of stable engine operation and improving thermal efficiency by using supercharging and blended fuels. The purpose of using supercharging were in order to moderated combustion.

Ignition, combustion and emissions characteristics of dual-component fuel spray were examined for ranges of injection timing and intake-air oxygen concentration. Fuels used were binary mixtures of gasoline-like component i-octane (cetane number 12, boiling point 372 K) and diesel fuel-like component n-tridecane (cetane number 88, boiling point 510 K). Mass fraction of i-octane was also changed as the experimental variable. The experimental study was carried out in a single cylinder compression ignition engine equipped with a common-rail injection system and an exhaust gas recirculation system. The results demonstrated that the increase of the i-octane mass fraction with optimizations of injection timing and intake oxygen concentration reduced pressure rise rate and soot and NOx emissions without deterioration of indicated thermal efficiency.