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Technical Paper

Fuel Property Effects of a Broad Range of Potential Biofuels on Mixing Control Compression Ignition Engine Performance and Emissions

2021-04-06
2021-01-0505
Conventional diesel engines will continue to hold a vital role in the heavy- and medium-duty markets for the transportation of goods along with many other uses. The ability to offset traditional diesel fuels with low-net-carbon biofuels could have a significant impact on reducing the carbon footprint of these vehicles. A prior study screened several hundred candidate biofuel blendstocks based on required diesel blendstock properties and identified 12 as the most promising. Eight representative biofuel blendstocks were blended at a 30% volumetric concentration with EPA certification ultra-low-sulfur diesel (ULSD) and were investigated for emissions and fuel efficiency performance. This study used a single cylinder engine (based on the Ford 6.7L engine) using Conventional Diesel Combustion (CDC), also known as Mixing Control Compression Ignition (MCCI). The density, cetane number, distillation curve and sooting tendency (using the yield sooting index method) of the fuels were measured.
Journal Article

Heat of Vaporization Measurements for Ethanol Blends Up To 50 Volume Percent in Several Hydrocarbon Blendstocks and Implications for Knock in SI Engines

2015-04-14
2015-01-0763
The objective of this work was to measure knock resistance metrics for ethanol-hydrocarbon blends with a primary focus on development of methods to measure the heat of vaporization (HOV). Blends of ethanol at 10 to 50 volume percent were prepared with three gasoline blendstocks and a natural gasoline. Performance properties and composition of the blendstocks and blends were measured, including research octane number (RON), motor octane number (MON), net heating value, density, distillation curve, and vapor pressure. RON increases upon blending ethanol but with diminishing returns above about 30 vol%. Above 30% to 40% ethanol the curves flatten and converge at a RON of about 103 to 105, even for the much lower RON NG blendstock. Octane sensitivity (S = RON - MON) also increases upon ethanol blending. Gasoline blendstocks with nearly identical S can show significantly different sensitivities when blended with ethanol.
Journal Article

Analysis of Ethanol Fuel Blends

2013-11-20
2013-01-9071
In the last three years, three quality surveys on ethanol-blended fuels intended for use in flex-fuel vehicles have been published. Two of these surveys cover Flex-Fuel quality, and the third encompasses the quality of mid-level ethanol blends (MLEBs) from blender pumps. The purpose of these surveys was to report on the quality of the fuels and provide a snapshot in time of fuel quality. This study examines the larger picture portrayed by these surveys and looks for broader trends in fuel quality. The analysis found that compliance with vapor pressure specification limits for Flex Fuel improved from 40% to 66% in Class 1, from 31% to 43% in Class 2, and from 12% to 30% in Class 3 between 2008 and 2010. Failures on other critical properties, such as acidity, pHe, water, and inorganic chloride were less than 6% in these studies. The 2010 Flex Fuel samples readily met the ethanol content specification, with 88%, 92%, and 95% compliance for Classes 1, 2, and 3, respectively.
Technical Paper

Characteristics of Exhaust Emissions from a Heavy-Duty Diesel Engine Retrofitted to Operate in Methane/Diesel Dual-Fuel Mode

2013-09-08
2013-24-0181
The need for a cleaner and less expensive alternative energy source to conventional petroleum fuels for powering the transportation sector has gained increasing attention during the past decade. Special attention has been directed towards natural gas (NG) which has proven to be a viable option due to its clean-burning properties, reduced cost and abundant availability, and therefore, lead to a steady increase in the worldwide vehicle population operated with NG. The heavy-duty vehicle sector has seen the introduction of natural gas first in larger, locally operated fleets, such as transit buses or refuse-haulers. However, with increasing expansion of the NG distribution network more drayage and long-haul fleets are beginning to adopt natural gas as a fuel.
Technical Paper

Greenhouse Gas Emissions of MY 2010 Advanced Heavy Duty Diesel Engine Measured Over a Cross-Continental Trip of USA

2013-09-08
2013-24-0170
The study was aimed at assessing in-use emissions of a USEPA 2010 emissions-compliant heavy-duty diesel vehicle powered by a model year (MY) 2011 engine using West Virginia University's Transportable Emissions Measurement System (TEMS). The TEMS houses full-scale CVS dilution tunnel and laboratory-grade emissions measurement systems, which are compliant with the Code of Federal Regulation (CFR), Title 40, Part 1065 [1] emissions measurement specifications. One of the specific objectives of the study, and the key topic of this paper, is the quantification of greenhouse gas (GHG) emissions (CO2, N2O and CH4) along with ammonia (NH3) and regulated emissions during real-world operation of a long-haul heavy-duty vehicle, equipped with a diesel particulate filter (DPF) and urea based selective catalytic reduction (SCR) aftertreatment system for PM and NOx reduction, respectively.
Technical Paper

The Impacts of Mid-level Biofuel Content in Gasoline on SIDI Engine-out and Tailpipe Particulate Matter Emissions

2010-10-25
2010-01-2125
In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.
Journal Article

Impacts of Biodiesel Fuel Blends Oil Dilution on Light-Duty Diesel Engine Operation

2009-06-15
2009-01-1790
Increasing interest in biofuels—specifically, biodiesel as a pathway to energy diversity and security—have necessitated the need for research on the performance and utilization of these fuels and fuel blends in current and future vehicle fleets. One critical research area is related to achieving a full understanding of the impact of biodiesel fuel blends on advanced emission control systems. In addition, the use of biodiesel fuel blends can degrade diesel engine oil performance and impact the oil drain interval requirements. There is limited information related to the impact of biodiesel fuel blends on oil dilution. This paper assesses the oil dilution impacts on an engine operating in conjunction with a diesel particle filter (DPF), oxides of nitrogen (NOx) storage, a selective catalytic reduction (SCR) emission control system, and a 20% biodiesel (soy-derived) fuel blend.
Technical Paper

Weight Effect on Emissions and Fuel Consumption from Diesel and Lean-Burn Natural Gas Transit Buses

2007-08-05
2007-01-3626
Transit agencies across the United States operate bus fleets primarily powered by diesel, natural gas, and hybrid drive systems. Passenger loading affects the power demanded from the engine, which in turn affects distance-specific emissions and fuel consumption. Analysis shows that the nature of bus activity, taking into account the idle time, tire rolling resistance, wind drag, and acceleration energy, influences the way in which passenger load impacts emissions. Emissions performance and fuel consumption from diesel and natural gas powered buses were characterized by the West Virginia University (WVU) Transportable Emissions Testing Laboratory. A comparison matrix for all three bus technologies included three common driving cycles (the Braunschweig Cycle, the OCTA Cycle, and the ADEME-RATP Paris Cycle). Each bus was tested at three different passenger loading conditions (empty weight, half weight, and full weight).
Technical Paper

Laser Spark Plug Development

2007-04-16
2007-01-1600
To meet the ignition system needs of large bore high pressure lean burn natural gas engines a laser diode side pumped passively Q-switched laser igniter was designed and tested. The laser was designed to produce the optical intensities needed to initiate ignition in a lean burn high brake mean effective pressure (BMEP) engine. The experimentation explored a variety of optical and electrical input parameters that when combined produced a robust spark in air. The results show peak power levels exceeding 2 MW and peak focal intensities above 400 GW/cm2. Future research avenues and current progress with the initial prototype are presented and discussed.
Technical Paper

Effects of Average Driving Cycle Speed on Lean-Burn Natural Gas Bus Emissions and Fuel Economy

2007-01-23
2007-01-0054
Although diesel engines still power most of the heavy-duty transit buses in the United States, many major cities are also operating fleets where a significant percentage of buses is powered by lean-burn natural gas engines. Emissions from these buses are often expressed in distance-specific units of grams per mile (g/mile) or grams per kilometer (g/km), but the driving cycle or route employed during emissions measurement has a strong influence on the reported results. A driving cycle that demands less energy per unit distance than others results in higher fuel economy and lower distance-specific oxides of nitrogen emissions. In addition to energy per unit distance, the degree to which the driving cycle is transient in nature can also affect emissions.
Technical Paper

Quantification of Biodiesel Content in Fuels and Lubricants by FTIR and NMR Spectroscopy

2006-10-16
2006-01-3301
The use of biodiesel requires the development of proper quantification procedures for biodiesel content in blends and in lubricants (fuel dilution in oil). Although the ester carbonyl stretch at 1746 wavenumbers (cm-1) is the most prominent band in the IR spectrum of biodiesel, it is difficult to use for quantification purposes due to a severe fluctuation of absorption strength from sample to sample, even at the same biodiesel content. We have demonstrated that the ester carbonyl fluctuation is not caused by variation in the ester alkyl chain length; but is most likely caused by the degree of hydrogen bonding of the ester functional group with water in the sample. Water molecules can form complexes with the ester compound affecting the strength of the ester carbonyl band. The impact of water on quantification of the biodiesel content of blends was significant, even for B100 samples that met the proposed ASTM D6751 water limit of 500 ppm by D6304 (Karl Fischer Methdod).
Technical Paper

Quality Assurance of Exhaust Emissions Test Data Measured Using Portable Emissions Measurement System

2005-10-24
2005-01-3799
Beginning 2007, heavy-duty engine certification would require that in-use emissions from vehicles be measured under ‘real-world’ operating conditions using on-board measurement devices. An on-board portable emissions measurement system called Mobile Emissions Measurement System (MEMS) was developed at West Virginia University (WVU) to record in-use, continuous and brake-specific emissions from heavy-duty diesel-powered vehicles. The objective of this paper is to present a preliminary development of a test data quality assurance methodology for emissions measured using the any portable emissions measurement system (PEMS). The first stage of the methodology requires ensuring the proper operation of the different sensors and transducers during data collection. The second stage is data synchronization and pre-processing. The next stage is systematic checking of possible errors from transducers and sensors.
Technical Paper

Design of a Portable Micro-Dilution Tunnel Particulate Matter Emissions Measurement System

2005-10-24
2005-01-3795
The Federal Test Procedure (FTP) for heavy-duty engines requires the use of a full-flow tunnel based constant volume sampler (CVS). These are costly to build and maintain, and require a large workspace. A small portable micro-dilution system that could be used on-board, for measuring emissions of in-use, heavy-duty vehicles would be an inexpensive alternative. This paper presents the rationale behind the design of such a portable particulate matter measuring system. The presented micro-dilution tunnel operates on the same principle as a full-flow tunnel, however given the reduced size dilution ratios can be more easily controlled with the micro dilution system. The design targets dilution ratios of at least four to one, in accordance with the ISO 8178 requirements. The unique features of the micro-dilution system are the use of only a single pump and a porous sintered stainless steel tube for mixing dilution air and raw exhaust sample.
Technical Paper

Impact of Vehicle Weight on Truck Behavior and Emissions, using On-Board Measurement

2005-10-24
2005-01-3788
On-board emissions measurement for heavy-duty vehicles has taken on greater significance because new standards now address in-use emissions levels in the USA. Emissions compliance must be shown in a “Not-to-exceed” (NTE) zone that excludes engine operation at low power. An over-the-road 1996 Peterbilt tractor was instrumented with the West Virginia University Mobile Emissions Measurement System (MEMS). The researchers determined how often the truck entered the NTE, and the emissions from the vehicle, as it was driven over different routes and at different test weights (20,740 lb, 34,640 lb, 61,520 lb, and 79,700 lb) The MEMS interfaced with the truck ECU, while also measuring exhaust flowrate, and concentrations of carbon dioxide (CO2) and oxides of nitrogen (NOx) in the exhaust. The four test routes that were employed included varying terrain types in order to simulate a wide range of on-road driving conditions. One route (called the Bruceton route) included a sustained hill climb.
Technical Paper

Comparison of Averaging Techniques Employed in Calculating Not-to-Exceed Emissions for Heavy-Duty Vehicles

2005-10-24
2005-01-3787
Certification of heavy-duty diesel requires engines to be tested on an engine dynamometer and meet certification in accordance with specific procedures and cycles. However, real-world emissions have been observed to be significantly different from in-laboratory testing. The brake-specific emissions from vehicles are influenced by various operating parameters such as engine speed, load, traffic flow and ambient conditions, hence, vary from the values obtained from the certification tests. In the future, US EPA and other state regulating bodies will require the engine manufacturers to measure in-use emissions from vehicles operating under “real-world” operating conditions. A test vehicle instrumented with West Virginia University's (WVU) Mobile Emissions Measurement System (MEMS), a portable onboard tailpipe emissions measurement system, was used to obtain engine operating conditions, vehicle speed and in-use emission rates of CO2 and NOx.
Technical Paper

Fischer-Tropsch Diesel Fuels - Properties and Exhaust Emissions: A Literature Review

2003-03-03
2003-01-0763
Natural gas, coal, and biomass can be converted to diesel fuel through Fischer-Tropsch (F-T) processes. Variations of the F-T process and/or product work-up can be used to tailor the fuel properties to meet end-users needs. Regardless of feedstock or process, F-T diesel fuels typically have a number of very desirable properties. This review describes typical F-T diesel fuel properties, discusses how these fuel properties impact pollutant emissions, and draws together data from known engine and chassis dynamometer studies of emissions. The comparison of fuel properties reveals that F-T diesel fuel is typically one of two types - a very high cetane number (>74), zero aromatic product or a moderate cetane (∼60), low aromatic (≤15%) product. The very high cetane fuels typically have less desirable low temperature properties while the moderate cetane fuels have cold flow properties more typical of conventional diesel fuels.
Technical Paper

Speciation of Organic Compounds from the Exhaust of Trucks and Buses: Effect of Fuel and After-Treatment on Vehicle Emission Profiles

2002-10-21
2002-01-2873
A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).
Technical Paper

Measurement of Brake-specific NOX Emissions using Zirconia Sensors for In-use, On-board Heavy-duty Vehicle Applications

2002-05-06
2002-01-1755
Emissions tests for heavy -duty diesel-fueled engines and vehicles are normally performed using engine dynamometers and chassis dynamometers, respectively, with laboratory grade gaseous concentration measurement analyzers and supporting test equipment. However, a considerable effort has been recently expended on developing in-use, on-board tools to measure brake-specific emissions from heavy -duty vehicles with the highest degree of accuracy and precision. This alternative testing methodology would supplement the emissions data that is collected from engine and chassis dynamometer tests. The on-board emissions testing methodology entails actively recording emissions and vehicle operating parameters (engine speed and load, vehicle speed etc.) from vehicles while they are operating on the road. This paper focuses on in-use measurements of NOX with zirconium oxide sensors and other portable NOX detectors.
Technical Paper

Determination of In-Use Brake-Specific Emissions from Off-Road Equipment Powered by Mechanically Controlled Diesel Engines

2002-05-06
2002-01-1756
Exhaust emissions from off-highway diesel engines are a significant contributor of both oxides of nitrogen (NOx) and particulate matter (PM) to air inventories. Yet, emissions research activities aimed solely at the off-highway arena have been minimal - largely overshadowed by the extensive efforts directed toward the on-highway sector. However, with current trends indicating that the performance of these off-highway vehicles will become increasingly more scrutinized by federal regulatory agencies, augmentation of current research efforts will be necessary. The global objective for this study was to collect vehicle activity information for diesel-powered off-highway vehicles while they were operated in the field. Engine speed and raw exhaust CO2 concentrations were recorded and then used to create engine dynamometer test cycles. The engine was exercised according to these cycles in the laboratory so that the mass emissions rates of exhaust gas pollutants could be measured.
Technical Paper

Mutagenic Potential of Particulate Matter from Diesel Engine Operation on Fischer-Tropsch Fuel as a Function of Engine Operating Conditions and Particle Size

2002-05-06
2002-01-1699
Further growth of diesel engines in the light-duty and heavy-duty vehicular market is closely linked to the potential health risks of diesel exhaust. The California Air Resources Board and the Office of Environmental Health Hazard Assessment have identified diesel exhaust as a toxic air contaminant. The International Agency for Research on Cancer concluded that diesel particulate is a probable human carcinogen [1]. Cleaner burning liquid fuels, such as those derived from natural gas via the Fischer-Tropsch (FT) process, offer a potentially economically viable alternative to standard diesel fuel while providing reduced particulate emissions. Further understanding of FT operation may be realized by investigating the differences in toxicity and potential health effects between particulate matter(PM) derived from FT fuel and that derived from standard Federal diesel No. 2 (DF).
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