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The improvement of the indicated thermal efficiency of an argon power cycle (replacing nitrogen with argon in the combustion reaction) is investigated in a CFR engine at high compression ratios in homogeneous charge compression ignition (HCCI) mode. The study combines the two effects that can increase the thermodynamic efficiency as predicted by the ideal Otto cycle: high specific heat ratio (provided by argon), and high compression ratios. However, since argon has relatively low heat capacity (at constant volume), it results in high in-cylinder temperatures, which in turn, leads to the occurrence of knock. Knock limits the feasible range of compression ratios and further increasing the compression ratio can cause serious damage to the engine due to the high pressure rise rate caused by advancing the combustion phasing.

A new approach for investigating combustion behavior of practical fuels under homogeneous charge compression ignition (HCCI) conditions was developed with the help of a cooperative fuel research (CFR) engine. The method uses a set of two pressure-temperature diagrams and two charts, each with an octane number scale based on primary reference fuels (PRF), created from experimental results by sweeping the intake temperature. The two pressure-temperature diagrams report conditions leading to the start of the low temperature combustion and the start of the main combustion, respectively. Additional two charts -- required compression ratio and fraction of low temperature heat release charts -- describe global combustion behavior and the importance of the low temperature combustion. Each diagram and chart, together with their respective octane number scale, allow to examine the combustion behavior of practical fuels by comparing their combustion behavior with those of the PRFs.

Due to their physical and chemical properties, alcohols such as ethanol and methanol when blended with gasoline provide high anti-knock quality and hence efficient engines. However, there are few promising properties of 1-butanol similar to conventional gasoline which make it a favorable choice for internal combustion engines. Previously the author showed that by blending ethanol and methanol with low octane fuels, non-linear increase in the HCCI fuel number occurs in HCCI combustion mode. Very few studies have been conducted on the use of 1-butanol in HCCI combustion mode, therefore for this work, 1-butanol with a RON 96 was selected as the high octane fuel. Three low octane fuels with octane number close to 70 were used as a base fuel. Two of the low octane fuels are Fuels for Advanced Combustion Engines (FACE gasolines), more specifically FACE I and FACE J and also primary reference fuel (PRF 70) were selected.

Future internal combustion engines demand higher efficiency but progression towards this is limited by the phenomenon called knock. A possible solution for reaching high efficiency is Octane-on-Demand (OoD), which allows to customize the antiknock quality of a fuel through blending of high-octane fuel with a low octane fuel. Previous studies on Octane-on-Demand highlighted efficiency benefits depending on the combination of low octane fuel with high octane booster. The author recently published works with ethanol and methanol as high-octane fuels. The results of this work showed that the composition and octane number of the low octane fuel is significant for the blending octane number of both ethanol and methanol. This work focuses on toluene as the high octane fuel (RON 120). Aromatics offers anti-knock quality and with high octane number than alcohols, this work will address if toluene can provide higher octane enhancement.

The blending behavior of ethanol in five different hydrocarbon base fuels with octane numbers of approximately 70 and 84 was examined under Spark-Ignited (SI) and Homogeneous Charge Compression Ignited (HCCI) operating conditions. The Blending octane number (BON) was used to characterize the blending behavior on both a volume and molar basis. Previous studies have shown that the blending behavior of ethanol generally follows several well-established rules. In particular, non-linear blending effects are generally observed on a volume basis (i.e. BON > RON or MON of pure ethanol; 108 and 89, respectively), while linear blending effects are generally observed on a molar basis (i.e. BON = RON or MON of pure ethanol). This work firstly demonstrates that the non-linear volumetric blending effects traditionally observed under SI operating conditions are also observed under HCCI operating conditions.

The blending of ethanol with PRF (Primary reference fuel) 84 was investigated and compared with FACE (Fuels for Advanced Combustion Engines) A gasoline surrogate which has a RON of 83.9. Previously, experiments were performed at four HCCI conditions but the chemical effect responsible for the non-linear blending behavior of ethanol with PRF 84 and FACE A was not understood. Hence, in this study the experimental measurements were simulated using zero-dimensional HCCI engine model with detailed chemistry in CHEMKIN PRO. Ethanol was used as an octane booster for the above two base fuels in volume concentration of 0%, 2%, 5% and 10%. The geometrical data and the intake valve closure conditions were used to match the simulated combustion phasing with the experiments. Low temperature heat release (LTHR) was detected by performing heat release analysis.

Homogeneous Charge Compression Ignition (HCCI) is generally considered as an efficient solution to reduce fuel consumption and meet the pollutant requirements of internal combustion engines. Furthermore, the HCCI combustion strategy delivers drastically reduced levels of NOx and particulate matter, and combined with a post treatment device, low levels of unburned hydrocarbons (HC) and carbon monoxide (CO) can be achieved. However, affordable and widely used three-way catalytic converters require the engine to be run under stoichiometric conditions. Running an HCCI engine under an increased equivalence ratio leads to advanced combustion phasing and an excessive in-cylinder pressure rate that can affect engine operation. The dilution effect of Exhaust Gas Recirculation (EGR) represents a way to delay ignition of the mixture and reduce excessive in-cylinder pressure gradients.

Homogeneous Charge Compression Ignition (HCCI) is among the new generation of combustion modes which can be applied to internal combustion engines. It is currently the topic of numerous studies in various fields. Due to its operating process, HCCI ensures a good efficiency, similar to that of compression ignition (CI) engines, and low particulate and nitric oxide (NOx) emissions. However, before promoting the use of this kind of engine, several challenges must be addressed, in particular controlling the combustion. Recent work showed that the combustion phasing can be controlled using low concentrations of ozone, an oxidizing chemical species. As ozone generators become increasingly compact, the integration of this kind of device in passenger cars can be considered. The present study investigates the effect of ozone on the combustion of different fuel mixtures. The engine was fuelled with various blends: a 95%methane/5%propane mixture and three different methane/hydrogen mixtures.

Nowadays, the main objectives in the automobile engine field are to reduce fuel consumption and pollutant emissions. HCCI engines can be a good solution to meet pollutant emission requirements and to achieve high combustion efficiency. However, before an HCCI engine is used as a conventional engine, several problems must be overcome, in particular control of the progression of combustion. Many studies have been conducted into possible control methods. A new strategy consists in using oxidizing chemical species such as ozone to seed the intake of a HCCI engine. As increasingly smaller ozonizers are now being designed, this kind of device could be integrated on a vehicle and on a HCCI engine, in order to control combustion phasing and promote the future use of this engine as a conventional engine. In the present study, experiments on a HCCI engine fuelled with iso-octane were carried out with ozone seeding in the intake.

As an alternative to second generation ethanol, valeric esters can be produced from lignocellulose through levulinic acid. While some data on these fuels are available, only few experiments have been performed to analyze their combustion characteristics under engine conditions. Using a traditional spark ignition engine converted to mono-cylinder operation, we have investigated the engine performances and emissions of methyl and ethyl valerates. This paper compares the experimental results for pure valeric esters and for blends of 20% of esters in PRF95, with PRF95 as the reference fuel. The esters propagate faster than PRF95 which requires a slight change of ignition timing to optimise the work output. However, both the performances and the emissions are not significantly changed compared to the reference. Accordingly, methyl and ethyl valerate represent very good alternatives as biofuels for SI engines.

To limit pollutants from transport and to reach a low level of exhaust emission, Low Temperature Combustion (LTC) modes such as Homogeneous Charge Compression Ignition (HCCI) are being studied. HCCI process is based on the auto-ignition of a highly diluted air/fuel mixture. It allows very low level of NOx and particulate emissions. But several problems must be solved: firstly the limited combustion range, the difficulty to control the combustion process, the noise but also the high HC and CO emissions. Two ways appear as very promising to improve HCCI combustion: engine technology and fuel formulation. In this work, attention is paid on initiation and HCCI combustion control through fuel formulation. This article shows the effect of acetal addition (and in particular butylal addition) in a Diesel base fuel. It seems to be difficult to have only an “HCCI engine” because the operation zone of the engine is too small. More likely, it will be a Diesel/HCCI engine.