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For the purpose of developing onboard gasoline reforming technology for higher octane number fuel on demand, octane number enhancement of gasoline surrogate by aerobic oxidation using N-hydroxyphthalimide catalyst was investigated. At first, octane numbers of the oxygen-containing products from alkane and aromatic compound were estimated using a fuel ignition analyzer. As a result, not only alcohol but also ketones and aldehydes have higher octane numbers than the original alkanes and aromatic compound. Next, gasoline surrogate was oxidized aerobically with N-hydroxyphthalimide derivative catalyst and cobalt catalyst at conditions below 100 °C. As a result, fuel molecules were oxidized to produce alcohols, ketones, aldehydes, and carboxylic acids. N-hydroxyphthalimide derivative catalyst with higher solubility in gasoline surrogate has higher oxidation ability. Furthermore, the estimated octane number of the oxidized gasoline surrogate improves 17 RON.

Compression ignition combustion with a lean mixture has high potential in terms of high theoretical thermal efficiency and low NOx emission characteristics due to low combustion temperatures. In particular, a Dual-Fuel concept is proposed to achieve high ignition timing controllability and an extended operation range. This concept controls ignition timing by adjusting the fraction of two fuels with different ignition characteristics. However, a rapid combustion process after initial ignition cannot be avoided due to the homogenous nature of the fuel mixture, because the combustion process depends entirely on the high reaction rate of thermal ignition. In this study, the effect of mixture stratification in the cylinder on the combustion process after ignition based on the Dual-Fuel concept was investigated. Port injection of one fuel creates the homogeneous mixture, while direct injection of the other fuel prepares a stratified mixture in the cylinder at the compression stroke.

In practical lean burn engines used to date, the use of a stratified air-fuel configuration, with a comparatively rich mixture in the vicinity of the spark plugs, has resulted in the stable combustion of an overall lean mixture. However, because a comparatively rich mixture is burned during the first half of combustion, NOx emissions are not reduced sufficiently. This research focused on a form of lean burn with homogeneous premixture that would be able to balance low NOx emissions with combustion controllability. It is widely known that homogeneous lean premixed gas has poor flame propagation characteristics. To determine the dominant cause of this, this study investigated the combustion properties of a single-cylinder engine while changing the compression ratio and intake temperature. As a result, the primary cause of combustion fluctuation, the abnormal cycle has a low TDC temperature compared to that of other cycles.

Gasoline includes various kinds of chemical species. Thus, the reaction model of gasoline components that includes the low-temperature oxidation and ignition reaction is necessary to investigate the method to control the combustion process of the gasoline engine. In this study, a gasoline combustion reaction model including n-paraffin, iso-paraffin, olefin, naphthene, alcohol, ether, and aromatic compound was developed. KUCRS (Knowledge-basing Utilities for Complex Reaction Systems) [1] was modified to produce paraffin, olefin, naphthene, alcohol automatically. Also, the toluene reactions of gasoline surrogate model developed by Sakai et al. [2] including toluene, PRF (Primary Reference Fuel), ethanol, and ETBE (Ethyl-tert-butyl-ether) were modified. The universal rule of the reaction mechanisms and rate constants were clarified by using quantum chemical calculation.

The methodology of lubricity evaluation for DME fuel was established by special modified HFRR (High-Frequency Reciprocating Rig) such as Multi-Pressure/Temperature HFRR (MPT-HFRR). The obtained results were summarized as follows: The HFRR method is adaptable with DME fuel. There is no effect of the test pressure (up to 1.8 MPa) and the test temperature (up to 100°C) of MPT-HFRR on wear scar diameter. The results with MPT-HFRR can be applied at the sliding parts of the injection needle and the fuel supply pump's plungers which are secured lubricity by the boundary lubrication mode mainly and the mixed lubrication mode partially. Using the fatty-acid-based lubricity improver in amounts of approximately 100 ppm, the lubricity of DME, which has a lack of self-lubricity, is ensured as same as the diesel fuel equivalent level. There is a big deviation of measured wear scar diameter when the LI concentration is not enough.

DME as a fuel for compression ignition (diesel) engines has been actively studied for about ten years due to its characteristically low pollution and reputation as a “smokeless fuel”. During this time, the practical application is taking shape based on necessary tasks such as analysis of injection and combustion, engine performance, and development of experimental vehicles. At this moment, standardization of DME as a fuel was started under ISO in 2007. There are concerns regarding the impurities in DME regarding the mixing during production and distribution as well as their effect on additives for lubricity and odor. In this report, the effect of DME fuel impurities on performance of a DME powered diesel engine was investigated. The platform was a DME engine with common-rail fuel injection and was evaluated under partial load stable mode and Japanese transient mode (JE05) testing parameters.

The tasks to improve diesel emissions and fuel consumption must be accomplished with urgency. However, due to the trade-off relationship between NOx emissions, soot emissions and fuel consumption, clean diesel combustion should be achieved by both innovative combustion and fuel technologies. The objective of this study is to extend the clean diesel combustion operating range (Engine-out emission: NOx ≺ 0.2 g/kWh, Soot ≺ 0.02 g/kWh). In this study, performance of a single-cylinder test engine equipped with a hydraulic valve actuation system and an ultra-high pressure fuel injection system was investigated. Also evaluated, were the effects of fuel properties such as auto-ignitability, volatility and aromatic hydrocarbon components, on combustion performance. The results show that applying a high EGR (Exhaust gas recirculation) rate can significantly reduce NOx emission with an increase in soot emission.

It is important in the application of bio-ethanol in homogeneous-charge compression ignition (HCCI) engines to investigate the HCCI combustion characteristics of ethanol. As the inhibitory mechanism of ethanol on HCCI combustion is a key factor, simulated chemical reactions are necessary. In this study, chemical reaction simulations in the combustion chamber of a rapid compression machine (RCM) were performed in order to investigate the inhibitory mechanism of ethanol on the HCCI combustion of heptane. The sensitivity analysis results suggested that the OH radical consumption reaction by ethanol that occurs would inhibit the cool flame reaction of heptane. Furthermore, visualization of HCCI combustion with the RCM was conducted using a quartz glass combustion chamber head and ICCD camera. As a result, the cool flame luminescence intensity of heptane was reduced by the addition of ethanol.

It has been clarified that diesel fuel properties have a great effect on the exhaust emissions and fuel consumption of a conventional diesel combustion regime. And as other diesel combustion regimes are applied in order to improve exhaust emissions and fuel consumption, it can be supposed that the fuel properties also have significant effects. The purpose of this study is to propose the optimum diesel fuel properties for a premixed compression ignition (PCI) combustion regime. In this paper, the effect of the auto-ignitability of diesel fuels on exhaust emissions and fuel consumption was evaluated using a heavy-duty single-cylinder test engine. In all experiments, fuels were injected using an electronically controlled, common-rail diesel fuel injector, and most experiments were conducted under high EGR conditions in order to reduce NOx emissions.

Bio-ethanol is one of the candidates for automotive alternative fuels. For reduction of carbon dioxide emissions, it is important to investigate its optimum combustion procedure. This study has explored effect of ethanol fuels on HCCI-SI hybrid combustion using dual fuel injection (DFI). Steady and transient characteristics of the HCCI-SI hybrid combustion were evaluated using a single cylinder engine and a four-cylinder engine equipped with two port injectors and a direct injector. The experimental results indicated that DFI has the potential for optimizing ignition timing of HCCI combustion and for suppressing knock in SI combustion under fixed compression ratio. The HCCI-SI hybrid combustion using DFI achieved increasing efficiency compared to conventional SI combustion.

Bio-ethanol is one of the most promising alternative fuels for vehicles. It is important for the spread of bio-ethanol to investigate its ignition quality and its optimum combustion procedure. It is particularly important for the application of bio-ethanol to a homogeneous-charge compression ignition (HCCI) engine to investigate the HCCI combustion characteristics of ethanol. In this study, the inhibiting effects of ethanol on the HCCI combustion of heptane were investigated by using a rapid compression machine (RCM) under various conditions. The results indicate that ethanol effectively retarded the hot ignition period of HCCI combustion due to its effective retardation of the cool flame period. The hot ignition peak period for 30 wt% ethanol/70 wt% heptane was more delayed than that of PRF having an octane number of 60 under the ϕ=0.4 condition.

The performance of a medium duty DME truck was evaluated by field tests and engine bench tests. The DME vehicle was given a public license plate on October 2004, after which running tests were continued on public roads and a test course. The DME vehicle could run the whole distance, about 500 km, without refueling. The average diesel equivalent fuel consumption of the fully loaded DME truck was 5.75 km/l, running at 80 km/h on public highways. Remedying several malfunctions that occurred in the power-train subsystems enhanced the vehicle performance and operation. The DME vehicle accumulated 13,000 km as of August, 2006 with no observed durability trouble of the fuel injection pump. Disassembly and inspection of the fuel injectors after 7,700 km operation revealed a few differences in the nozzle tip and the needle compared to diesel fuel operation. However, the injectors were used again after cleanup.

In this study, diesel exhaust emission characteristics were investigated as GTL (Gas To Liquid) fuel was applied to a heavy-duty diesel truck which had been developed to match a Japanese new long-term exhaust emission regulation (NOx < 2.0 g/kWh, PM < 0.027 g/kWh). The results in this study show that although the test vehicle has advanced technologies (e.g. high pressure fuel injection, oxidation catalyst, and urea-SCR aftertreatment system, etc.) which are applied to reduce diesel emissions, the neat GTL fuel has a great advantage to reduce particulate matter emissions and poly aromatic hydrocarbons. And regarding nano-size PM emissions, nuclei mode particles emitted during idling are significantly decreased by using the GTL fuel.

Biodiesel fuel has attracted much attention as a carbon neutral fuel because it is made from vegetable oil. Especially in Southeast Asia, there are numerous biofuel resources, such as palm oil and coconut oil, and it is desirable to utilize these for CO2 reduction. In this paper, we evaluate the properties of biodiesel fuel and biodiesel blended diesel oil. The low temperature performance of palm oil methyl ester (PME) is poor and it affects low temperature performance, even if the PME blending rate is low. The oxidation stability is a very important property of biodiesel fuel because degraded biodiesel fuel produces organic acids and polymeric substances. PME contains mainly saturated fatty acids methyl esters, so the oxidation stability is better than other fats and oils. When containing antioxidants such as beta carotene, biodiesel's oxidation stability is improved.

In this study, measurement methods of aldehydes and volatile organic compounds (VOCs) from off-road engine have been investigated. Also, their emission characteristics have been evaluated. By using high-performance liquid chromatograph (HPLC), aldehydes could be measured with small variation. Major aldehydes from off-road engine are formaldehyde and acetaldehyde. Total aldehydes emission is not necessarily low compared to THC emission. The emission characteristics of aldehydes are similar to that of CO, THC and PM. For VOCs sampling, sampling tube with absorbent was better than sampling bag because some kinds of VOCs tend to become absorbed on the sampling bag. Except for 1,3-butadiene, VOCs could be measured with small variation by using gas chromatography-mass spectrometer (GC-MS). Benzene, toluene and xylene were major species found in VOCs. The emission characteristics of VOCs were also similar to ones of CO, THC and PM.

A new method for controlling fuel ignition quality has been developed. A cetane improver, such as organic peroxide, is added to a base fuel to create a fuel with higher ignition quality. The cetane improver in the fuel is then decomposed using a catalyst. This process lowers the ignition quality. To demonstrate this concept, the effects of a cumene hydroperoxide (CHP) addition and its catalytic decomposition on fuel ignition quality were investigated. It was found that addition of CHP improved ignition quality in the base fuel, and that following catalytic decomposition, the ignition quality was reduced below that of the base fuel.

Dimethyl ether (DME) has been attracting notable attention as a clean alternative fuel for diesel engines. The authors developed a medium duty DME truck, and investigated aspects of vehicle performance such as engine power, exhaust characteristics, fuel consumption, noise, in-vehicle systems, and so on. Results indicated that higher engine torque and power could be achieved with DME compared to diesel fuel operation of the base engine at any engine speed. Results also showed that emissions decreased dramatically, to 27% for NOx, 74% for HC, 95% for CO and 94% for PM (Particulate Matter) compared to maximum allowed Japanese 2003 emission regulations. The operating noise of the DME vehicle was slightly lower than the base vehicle with diesel fuel, because the combustion noise with DME was decreased compared to with diesel fuel operation. The DME vehicle was given a public license plate in October 2004, after which running test continued on public roads and on a test course.

In this report, trace levels of harmful substances, such as formaldehyde, acetaldehyde, SO2, benzene and so on, emitted from a DME fueled direct injection (DI) compression ignition (CI) engine were measured using a Fourier Transform Infrared (FTIR) emission analyzer. Results showed that the NO portion of NOx emissions with DME exceeded diesel fuel operation levels. DME fueling caused greater amounts of water than with diesel fuel operation. DME fueling was also associated with higher formaldehyde emissions than with diesel fuel operation. However, using an oxidation catalyst, formaldehyde could be decreased to a negligible level.

In this study, a MPT-HFRR (Multi-Pressure/Temperature High-Frequency Reciprocating Rig) was manufactured based on a diesel fuel lubricity test apparatus. The MPT-HFRR was designed to be used for conventional test methods as well as for liquefied gas fuel tests. Lubricity tests performed on a calibration standard sample under both atmospheric pressure and high pressure produced essentially constant values, so it was determined that this apparatus could be used for assessing the lubricity of fuel. Using this apparatus, the improvement of lubricity due to the addition of a DME (Dimethyl Ether) fuel additive was investigated. It was found that when 50ppm or more of a fatty acid lubricity improver was added, the wear scar diameter converged to 400μm or less, and a value close to the measured result for Diesel fuel was obtained. The lubricity obtained was considered to be generally satisfactory.

The engine performance and exhaust characteristics of the DME-powered diesel engine with an injection system developed for DME were investigated. The injection pump is an inline type that can inject double amount of DME fuel compared to the base injection pump because the calorific value of DME is about half lower than that of diesel fuel. The effect of injection timing on engine performances such as thermal efficiency, engine torque, and exhaust characteristics were investigated. Maximum torque and power with DME could be achieved the same or greater level compared to diesel fuel operation. Considering over all engine performances, the best dynamic injection timings without EGR were -3, -3, -6 and -9 deg. ATDC in 1120, 1680, 2240 and 2800 rpm engine speeds respectively in this experiment.