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This work elaborates the transferability of electrode diffusion coefficients gained from fitting procedures in frequency domain to an electrochemical battery model run in time domain. An electrochemical battery model of an NMC622 half-cell electrode is simulated with sinusoidal current excitations at different frequencies. The current and voltage signals are analyzed in frequency domain via Nyquist and Bode plots. The frequency domain analysis of time domain simulations is applied to assess the numerical convergence of the simulation and the sensitivity on particle diameter, electrode and electrolyte diffusion coefficients. The simulated frequency spectra are used to fit the electrode diffusion coefficient by means of different electrical equivalent circuit models and the electrochemical battery model itself. The fitted diffusion coefficients from the different electrical equivalent circuit models deviate by one order of magnitude from the a priori known reference data.

Fast charging of batteries at cold conditions faces the challenge of promoting undesired cell degradation phenomena such as lithium plating. The occurrence of lithium plating is strongly related to local surface potentials and temperatures involving the scales of the electrode surface, the unit cell and the entire module or pack. A multi-scale, multi-domain model is presented, enhancing a Newman based unit cell model with consistent models for heat generation and lithium plating and integrating this 1D+1D approach into a thermal 3D model on module level. The basic equations are presented and three different plating models from literature are discussed. The thermal model is assessed in open-loop simulations and the different plating approaches are compared in charge/discharge simulations at different operating conditions. The full multi-scale, multi-domain model is applied as a virtual sensor for model-based control of fast charging at cold conditions.

Approaching engineering limits for the thermal design of battery modules requires virtual prototyping and appropriate models with respect to physical depth and computational effort. A multi-scale and multi-domain model describes the electrochemical behavior of a single battery unit cell in 1D+1D at the level of intra-cell phenomena, and it applies a 3D thermal model at module level. Both models are connected within a common vehicle simulation platform. The models are discussed with special emphasis on battery degradation such as solid electrolyte interphase layer formation, decomposition and lithium plating. The performance of the electrochemical model is assessed by discharge cycles and repeated charge/discharge simulations. The thermal module model is compared to CFD reference data and studied with respect to its grid sensitivity.

Direct injection Diesel engines are a propulsion technology that is continuously developed to meet emission standards. Great optimization potential lies in the combustion process itself. The application of closed loop combustion control allows reacting online to environmental conditions and stabilizing the combustion regarding performance and emissions. Dedicated real-time plant models help to develop and calibrate control algorithms in office and hardware in the loop environments. The present work describes a real-time capable, crank-angle resolved engine, cylinder and combustion model. The cylinder applies an 0D, two-zone approach and a phenomenological combustion model describes ignition delay, premixed and diffusive combustion. The latter is enhanced by a quasi-dimensional description of the injection spray. The model is validated with dedicated measurements. The plant model is applied in two use-cases for closed loop combustion control.

Modern Diesel engines require an integrated development of combustion strategies, air management and exhaust aftertreatment. This study presents a comprehensive simulation approach with the aim to support engine development activities in the virtual environment. A real-time capable engine, vehicle and control model is extended by three key features. First, a pollutant production model is embedded in a two-zone cylinder model. Second, a framework for catalytic pollutant conversion is built focusing on modern diesel exhaust aftertreatment systems. Third, an extended species transport model is introduced considering the transport of pollutants through the air path. The entire plant model is validated on the example of a passenger car Diesel engine. The predicted engine behavior is compared with steady-state measurements. The NO formation model is investigated for a series of steady-state and transient operating conditions.