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In the next ILSAC passenger car motor oil specification the Sequence IIIG engine test, as well as two versions of the Thermo-Oxidation Engine Oil Simulation Test (TEOST) have been proposed as tests to determine the ability of crankcase oils to control engine deposits. The Sequence IIIG engine test and the TEOST MHT test are designed to assess the ability of lubricants to control piston deposits and the TEOST 33 test is designed to assess the ability of lubricants to control turbocharger deposits. We have previously characterized the chemical composition of Sequence IIIG piston deposits using thermogravimetric, infrared and SEM/EDS analyses. Sequence IIIG piston deposits contain a significant amount of carbonaceous material and the carbonaceous material is more prevalent on sections of the pistons that should encounter higher temperatures. Furthermore, the carbonaceous material appears to be a deposit formed by the Sequence IIIG fuel.

Deposit formation is an issue of great significance in a broad range of applications where lubricants are exposed to high temperatures. Lube varnish causes valve-sticking, bearing failure and filter blockage which can lead to considerable equipment downtime and high maintenance costs. Recently this has become a pressing issue in the stationary power generation industry. In order to investigate the chemistry leading to varnish, three samples of varnish-coated components from the lube/hydraulic systems of gas turbines from the field were obtained, along with information on the commercially available formulated oils which were used. Samples of these three fresh oils were analysed by a variety of chromatographic and spectroscopic techniques, which confirmed chemical identity of aminic and/or phenolic antioxidants, corrosion inhibitors and antiwear components. The varnish-coated turbine components were also investigated by these methods.

This paper provides an overview of driveline fluids, in particular automatic transmission fluids (ATFs), and is intended to be a general reference for those working with such fluids. Included are an introduction to driveline fluids, highlighting what sets them apart from other lubricants, a history of ATF development, a description of key physical ATF properties and a comparison of ATF fluid specifications. Also included are descriptions of the chemical composition of such fluids and the commonly used basestocks. A section is included on how to evaluate used driveline oils, describing common test methods and some comments on interpreting the test results. Finally the future direction of driveline fluid development is discussed. A glossary of terms is included at the end.