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Technical Paper

Understanding Catalyst Overheating Protection (COP) as a Source of Post-TWC Ammonia Emissions from Petrol Vehicle

2022-08-30
2022-01-1032
TWC exposure to extreme temperature could result in irreversible damage or thermal failure. Thus, a strategy embedded in the engine control unit (ECU) called catalyst overheating protection (COP) will be activated to prevent TWC overheating. When COP is activated, the command air-fuel ratio will be enriched to cool the catalyst monolith down. Fuel enrichment has been proven a main prerequisite for ammonia formation in hot TWCs as a by-product of NOx reduction. Hence, COP events could theoretically be a source of post-catalyst ammonia from petrol vehicles, but this theory is yet to be confirmed in published literature. This paper validated this hypothesis using a self-programmed chassis-level test. The speed of the test vehicle was set to constant while the TWC temperature was raised stepwise until a COP event was activated.
Technical Paper

The Application of Solid Selective Catalytic Reduction on Heavy-Duty Diesel Engine

2017-10-08
2017-01-2364
Urea SCR technology is the most promising technique to reduce NOx emissions from heavy duty diesel engines. 32.5wt% aqueous urea solution is widely used as ammonia storage species for the urea SCR process. The thermolysis and hydrolysis of urea produces reducing agent ammonia and reduces NOx emissions to nitrogen and water. However, the application of urea SCR technology has many challenges at low temperature conditions, such as deposits formation in the exhaust pipe, lack deNOx performance at low temperature and freezing below -12°C. For preventing deposits formation, aqueous urea solution is hardly injected into exhaust gas stream at temperature below 200°C. The aqueous urea solution used as reducing agent precursor is the main obstacle for achieving high deNOx performances at low temperature conditions. This paper presents a solid SCR technology for control NOx emissions from heavy duty diesel engines.
Technical Paper

Calculations and Test Measurements of In-Cylinder Combustion Velocity of Hydrogen - Air Mixtures Considering the Effect of Flame Instability

2017-03-28
2017-01-0780
The combustion characteristics of hydrogen-air mixtures have significance significant impact on the performance and control of hydrogen-fueled internal combustion engines and the combustion velocity is an important parameter in characterizing the combustion characteristics of the mixture. A four-cylinder hydrogen internal combustion engine was used to study hydrogen combustion; the combustion characteristics of a hydrogen mixture were experimentally studied in a constant-volume incendiary bomb, and the turbulent premixed combustion characteristics of hydrogen were calculated and analyzed. Turbulent hydrogen combustion comes under the folded laminar flame model. The turbulent combustion velocity in lean hydrogen combustion is related not only to the turbulent velocity and the laminar burning velocity, but also to the additional turbulence term caused by the instability of the flame.
Journal Article

Combustion and Emission Characteristics of a Heavy-Duty Diesel Engine at Idle at Various Altitudes

2013-04-08
2013-01-1516
This present paper described an experimental study on the combustion and emission characteristics of a diesel engine at idle at different altitudes. Five altitudes ranging from 550m to up to 4500m were investigated. Combustion parameters including in-cylinder pressure and temperature, heat release, fuel mass burning and so forth, together with emission factors including CO, HC, NOx and PM were tested and analyzed. The result of on-board measurement manifested that in-cylinder pressure descended consistently with the rising of altitude, while both the maximum in-cylinder temperature and exhaust temperature ascended with the altitude. It was found that ignition delay was lengthened at higher altitude, but the combustion duration became shorter. The crank angle towards 90% fuel burnt has hardly changed with the variation of altitude. As for heat release, the difference of slopes observed at different altitudes was quite slight.
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