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As automotive exhaust emission levels reduce, there is a need for increased sensitivity of the NOx measurement. This paper documents work performed to increase the sensitivity of the existing Rosemount NGA 2000 CLD Analyzer. The effects of sample flow rate, ozone flow rate and ozone supply gas were explored. Limit of Detection (LOD) and Converter Efficiency were evaluated. The goal of this optimization has been to provide a cost effective and expeditious method to improve the low level NOx measurement. Changing the ozone generator supply gas from air to oxygen and increasing the sample and ozone flow rates resulted in a LOD improvement from 17 ppb to 8 ppb.

Copolymer materials have been used for the collection of vehicle exhaust gas samples since the inception of regulatory standards. Some of these copolymers contain N,N-dimethylacetamide (DMA), which is added to improve the physical properties of the copolymer and eliminate manufacturing problems. DMA is highly soluble in water, and in effect is rinsed from the emission bag surface by humid exhaust gas samples. This study shows that DMA can thus incorrectly add to test vehicle overall hydrocarbon emissions. The DMA contribution can be significant for lower level emission vehicles. This study introduces a new bag material, KYNAR®, which significantly reduces this interference.