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Three-way catalysts are used in gasoline vehicles for simultaneous purifying nitrogen oxide, carbon monoxide, and hydrocarbon in recent years. However, the reduction of ammonia emission generated in the three-way catalyst is pressing issue. In EURO 7, ammonia will also be subject to the Real Driving Emissions regulation, and its emissions must be reduced. Previous studies have shown that ammonia emissions are higher under fuel-rich conditions, suggesting that differences in driving behavior have a significant impact on ammonia emissions in real-world driving, which includes various driving environments. In this study, driving tests were conducted on a direct- injection gasoline vehicle equipped with a three-way catalyst and Portable Emission Measurement System and Sensor-based Emission Measurement System to investigate the actual ammonia emissions on actual roads.

The Real Driving Emissions (RDE) test method has been introduced after 2017 to regulate the vehicle emissions in real-world driving situations by means of on-board emissions measurements. This paper aims to estimate the detailed on-board gaseous emissions from a light-duty direct-injection gasoline vehicle simultaneously using both portable emissions measurement system (PEMS) and sensor-based emissions measurement system (SEMS). Test route is typical urban route and tests environment factors followed the RDE regulation. Carbon dioxide (CO2), carbon monoxide (CO), nitrogen oxides (NOx), and ammonia (NH3) emissions were analyzed according to cold start once and followed by hot start conditions. The mass emissions of gas components were calculated based on the exhaust flowrate obtained from OBD parameters, NH3 emission was calculated based on NO sensor’s data. Two drivers participated in the tests and their emissions difference has been compared.

In recent years, particulate matter (PM) emitted from direct-injection gasoline vehicles is becoming an increasingly concerning problem. In addition, it is often reported that ammonia (NH3) is emitted from gasoline vehicles equipped with a three-way catalyst. These emissions might be largely emitted especially when driving in on-road driving conditions. In this study, we investigated the emissions, NOx, NH3, and PM/PN (particulate number) of a light-duty direct-injection gasoline vehicle when driving on actual roads. Using a small direct-injection gasoline vehicle equipped with a three-way catalyst, experiment was conducted 8 times on the same route, and these emissions were measured. In this study, vehicle specific power (VSP) was introduced, which can be calculated using vehicle parameters, vehicle speed, and road gradient. The effects of parameters acquired through on-board diagnostics (OBD) port and VSP on emissions were investigated.