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Journal Article

Effect of Decoration on Windshield Impact Resistance and Novel Decoration Solution Compatible with Chemical Strengthening

2022-03-29
2022-01-0263
Vehicle windshields typically include a black decorative pattern around their periphery and other regions. Examination of field failed parts has shown that windshields often break from impacts in these decoration zones; often with the fracture initiating from the decoration material itself. In this work, the effect of different glazing decoration materials on glass strength and laminate impact resistance was evaluated. The decoration materials investigated included traditional inorganic enamel frit, an organic ink, and a new enamel frit that is compatible with glass chemical strengthening. Ring-on-Ring strength tests were conducted and showed that inorganic enamel frit reduces strength of glass by over 50% compared to undecorated glass, while organic inks do not adversely affect strength. Tests of a newly developed decoration frit material, compatible for chemical strengthening processes, showed strength levels that were on par with undecorated, unstrengthened glass.
Technical Paper

Impact of Engine Oil Detergent on Low Speed Pre-Ignition (LSPI) and Fuel Economy Performance

2020-04-14
2020-01-1424
Low Speed Pre-Ignition (LSPI), also referred to as Stochastic Pre-Ignition (SPI), Superknock or Megaknock is an undesirable combustion phenomenon that limits the fuel economy, drivability, emissions and durability performance of modern turbocharged gasoline engines. Numerous studies have previously reported that the frequency of LSPI is sensitive to engine oil composition. One of these drivers is the concentration of Calcium, which is usually delivered in the form of a detergent in the additive package. Switching to completely all-Magnesium detergent and/or severely limiting the concentration of Ca in the engine oil have recently been proposed as potential means to reduce LSPI. In this work, we evaluate the impact of detergent type on LSPI performance as well as on other performance that the modern engine oil needs to deliver. Particularly the impact of detergent type on Fuel Economy performance is evaluated.
Technical Paper

The Effect of Friction Modifiers and DI Package on Friction Reduction Potential of Next Generation Engine Oils: Part II Aged Oils

2019-04-02
2019-01-0303
Engine oil plays an important role in improving fuel economy of vehicles by reducing frictional losses in an engine. Our previous investigation explored the friction reduction potential of next generation engine oils by looking into the effects of friction modifiers and dispersant Inhibitor packages when engine oil was fresh. However, engine oil starts aging the moment engine start firing because of high temperature and interactions with combustion gases. Therefore, it is more relevant to investigate friction characteristics of aged oils. In this investigation, oils were aged for 5000 miles in taxi cab application.
Technical Paper

Effect of Ash on Gasoline Particulate Filter Using an Accelerated Ash Loading Method

2018-04-03
2018-01-1258
Gasoline particulate filter (GPF) is considered a suitable solution to meet the increasingly stringent particle number (PN) regulations for both gasoline direct injection (GDI) and multi-port fuel injection (MPI) engines. Generally, GDI engines emit more particulate matter (PM) and PN. In recent years, GDI engines have gained significant market penetration in the automobile industry owing to better fuel economy and drivability. In this study, an accelerated ash loading method was tested by doping lubricating oil into the fuel for a GDI engine. Emission tests were performed at different ash loads with different driving cycles and GPF combinations. The results showed that the GPF could significantly reduce particle emissions to meet the China 6 regulation. With further ash loading, the filtration efficiency increased above 99% and the effects on fuel consumption and backpressure were found to be limited, even with an ash loading of up to 50 g/l.
Technical Paper

Optical Advantages of Thin Window Hybrid Windshields

2018-04-03
2018-01-0468
The adoption of head-up displays (HUDs) is increasing in modern automobiles. Yet integrating this technology into vehicles with standard windshield (WS) laminates can create negative effects for drivers, primarily due to the thickness of glass used. The double ghosting in HUD images is typically overcome by employing a wedged PVB between the two glass plies of the laminate. Another solution is to reduce the thickness of the glass without impacting the overall windshield toughness. Although this still requires the use of a wedged PVB to eliminate HUD ghosting, the thinner glass provides opportunity to increase the image size. However, reducing the thickness of a soda-lime glass (SLG) ply or plies in a conventional soda-lime glass (SLG) laminate can significantly impact the robustness of the laminate to external impact events.
Technical Paper

Continuously Variable Transmission (CVT) Fuel Economy

2017-10-08
2017-01-2355
Due to its simplicity and fuel economy benefit, continuously variable transmission (CVT) technology has gained a lot of attention in recent years. Market penetration of CVT technology is increasing rapidly compared to step-type automatic transmission technology. OEMs, Tier 1 suppliers, and lubricant suppliers are working to further improve the fuel economy benefit of CVTs. As a lubricant supplier, we want to understand the effects of fluid properties on CVT fuel economy (FE). We have formulated fluids that had KV100 ranges from 2-4 cSt to 7-9 cSt with various types and viscosities of base oils. Wide ranges of viscosity indexes, steel-on-steel friction, and other properties were tested. Full vehicle fuel economy tests were performed in a temperature controlled environment with a robotic driver. The test revealed that there was more than 3% overall FE variation compared to a reference fluid.
Technical Paper

Catalyzed Gasoline Particulate Filter (GPF) Performance: Effect of Driving Cycle, Fuel, Catalyst Coating

2017-10-08
2017-01-2366
Because of the increased use of gasoline direct engine (GDI) in the automobile industry, there is a significant need to control particulates from GDI engines based on emission regulations. One potential technical approach is the utilization of a gasoline particulate filter (GPF). The successful adoption of this emission control technology needs to take many aspects into consideration and requires a system approach for optimization. This study conducted research to investigate the impact of vehicle driving cycles, fuel properties and catalyst coating on the performance of GPF. It was found that driving cycle has significant impact on particulate emission. Fuel quality still plays a role in particulate emissions, and can affect the GPF performance. Catalyzed GPF is preferred for soot regeneration, especially for the case that the vehicle operation is dominated by congested city driving condition, i.e. low operating temperatures. The details of the study are presented in the paper.
Journal Article

A General Method for Fouling Injectors in Gasoline Direct Injection Vehicles and the Effects of Deposits on Vehicle Performance

2017-10-08
2017-01-2298
The ubiquity of gasoline direct injection (GDI) vehicles has been rapidly increasing across the globe due to the increasing demand for fuel efficient vehicles. GDI technology offers many advantages over conventional port fuel injection (PFI) engines, such as improvements in fuel economy and higher engine power density; however, GDI technology presents unique challenges as well. GDI engines can be more susceptible to fuel injector deposits and have higher particulate emissions relative to PFI engines due to the placement of the injector inside the combustion chamber. Thus, the need for reliable test protocols to develop next generation additives to improve GDI vehicle performance is paramount. This work discloses a general test method for consistently fouling injectors in GDI vehicles and engines that can accommodate multiple vehicle/engine types, injector designs, and drive cycles, which allows for development of effective GDI fuel additives.
Journal Article

Impact of Particle Characteristics and Engine Conditions on Deposit-Induced Pre-Ignition and Superknock in Turbocharged Gasoline Engines

2017-10-08
2017-01-2345
Low Speed Pre-Ignition (LSPI), also referred to as superknock or mega-knock is an undesirable turbocharged engine combustion phenomenon limiting fuel economy, drivability, emissions and durability performance. Numerous researchers have previously reported that the frequency of Superknock is sensitive to engine oil and fuel composition as well as engine conditions in controlled laboratory and engine-based studies. Recent studies by Toyota and Tsinghua University have demonstrated that controlled induction of particles into the combustion chamber can induce pre-ignition and superknock. Afton and Tsinghua recently developed a multi-physics approach which was able to realistically model all of the elementary processes known to be involved in deposit induced pre-ignition. The approach was able to successfully simulate deposit induced pre-ignition at conditions where the phenomenon has been experimentally observed.
Technical Paper

Assessment of Lightweight Automotive Glass Solutions on Interior Noise Levels & Sound Quality

2017-06-05
2017-01-1814
The automotive industry continues to develop technologies for reducing vehicle fuel consumption. Specifically, vehicle lightweighting is expected to be a key enabler for achieving fleet CO2 reduction targets for 2025 and beyond. Hybrid glass laminates that incorporate fusion draw and ion exchange innovations are thinner and thereby, offer more than 30% weight reduction compared to conventional automotive laminates. These lightweight hybrid laminates provide additional benefits, including improved toughness and superior optics. However, glazing weight reduction leads to an increase in transmission of sound through the laminates for certain frequencies. This paper documents a study that uses a systematic test-based approach to understand the sensitivity of interior vehicle noise behavior to changes in acoustic attenuation driven by installation of lightweight glass.
Technical Paper

Fluid Effects on Shifting Clutch Friction

2016-10-17
2016-01-2206
Good shift quality in automatic transmissions is important for fuel efficiency, driver comfort, and performance. Maintaining this performance over the life of the vehicle is also important. Typically lubricant development focuses on reducing viscosity and friction in order to reduce parasitic losses. In an automatic transmission other factors are also important for good performance, primarily due to the shifting clutches and the torque converter clutch. A high level of friction is desirable for torque capacity and a steady decrease in friction as sliding speed (rpm) decreases is necessary for both good shift feel and good friction system durability over the lifetime of the vehicle. Changes in the friction system over time that result in a lowering of the friction level, particularly at higher sliding speeds, compromise the performance of both types of clutches.
Technical Paper

Physicochemical Mechanisms for Fluoroelastomer Seal Failures

2016-10-17
2016-01-2272
Elastomer compatibility is an important property of lubricants. When seals degrade oil leakages may occur, which is a cause of concern for original equipment manufacturers (OEMs) because of warranty claims. Leakage is also a concern for environmental reasons. Most often, the mechanical properties and fitting of the oil seals is identified as the source of failure, but there are cases where the interaction between the lubricant and the seal material can be implicated. The performance of seal materials in tensile testing is a required method that must be passed in order to qualify lubricant additive packages. We conducted an extensive study of the interactions between these elastomeric materials and lubricant additive components, and their behavior over time. The physicochemical mechanisms that occur to cause seal failures will be discussed.
Journal Article

Formation of Intake Valve Deposits in Gasoline Direct Injection Engines

2016-10-17
2016-01-2252
Gasoline direct-injection (GDI) engines have a well-known propensity to form intake valve deposits (IVD), regardless of operator service, engine architecture, or cylinder configuration. Due to the lack of a fuel-washing process that is typical of Port Fuel Injected (PFI) engines, the deposits steadily accumulate over time and can lead to deterioration in combustion, unstable operation, valve-sticking, or engine failure. Vehicles using these engines are often forced to undergo expensive maintenance to mechanically remove the deposits, which eventually re-form. The deposit formation process has not been well-characterized and there is no standardized engine test to study the impact of fuel or lubricant formulation variables. To meet this need, a proprietary vehicle-based GDI-IVD test that is both repeatable and responsive to chemistry has been developed.
Technical Paper

Effect of Oil and Gasoline Properties on Pre-Ignition and Super-Knock in a Thermal Research Engine (TRE) and an Optical Rapid Compression Machine (RCM)

2016-04-05
2016-01-0720
High boost and direct injection are effective ways for energy saving in gasoline engines. However, the occurrence of super-knock at high load has become a main obstacle for further improving power density and fuel economy. It has been known that super-knock can be induced by pre-ignition, and oil droplet auto-ignition is found to be one of the possible mechanisms. In this study, experiments were conducted in a single-cylinder thermal research engine (TRE), in which different types of oil and surrogates were directly injected into the cylinder and then led to pre-ignition and super-knock. The effect of oil injection timing, oil injection quantity, different gasoline and different oil were tested. All the oil in this work could induce pre-ignition, even though their combustion phasing was much later than that in the case of n-hexadecane.
Journal Article

Reliability Evaluation of Thin, Lightweight Laminates for Windshield Applications

2016-04-05
2016-01-1401
The use of lightweight materials to produce automotive glazing is being pursued by vehicle manufacturers in an effort to improve fuel economy. As glazing’s become thinner, reduced rigidity means that the critical flaw size needed to create fracture becomes much smaller due to increased strain under load or impact. This paper documents experiments focused on the impact performance of several alternative thin laminate constructions under consideration for windshield applications (including conventional annealed soda-lime glass as well as laminates utilizing chemically strengthened glass), for the purpose of identifying new and unique failure modes that result from thickness reduction. Regulatory impact tests and experiments that focused on functional performance of laminates were conducted. Given the increased sensitivity to flaw size for thin laminates, controlled surface damage was introduced to parts prior to conducting the functional performance tests.
Technical Paper

High Porosity Substrates for Fast-Light-Off Applications

2015-04-14
2015-01-1009
Regulations that limit emissions of pollutants from gasoline-powered cars and trucks continue to tighten. More than 75% of emissions through an FTP-75 regulatory test are released in the first few seconds after cold-start. A factor that controls the time to catalytic light-off is the heat capacity of the catalytic converter substrate. Historically, substrates with thinner walls and lower heat capacity have been developed to improve cold-start performance. Another approach is to increase porosity of the substrate. A new material and process technology has been developed to significantly raise the porosity of thin wall substrates (2-3 mil) from 27-35% to 55% while maintaining strength. The heat capacity of the material is 30-38% lower than existing substrates. The reduction in substrate heat capacity enables faster thermal response and lower tailpipe emissions. The reliance on costly precious metals in the washcoat is demonstrated to be lessened.
Journal Article

Onboard Gasoline Separation for Improved Vehicle Efficiency

2014-04-01
2014-01-1200
ExxonMobil, Corning and Toyota have collaborated on an Onboard Separation System (OBS) to improve gasoline engine efficiency and performance. OBS is a membrane based process that separates gasoline into higher and lower octane fractions, allowing optimal use of fuel components based on engine requirements. The novel polymer-ceramic composite monolith membrane has been demonstrated to be stable to E10 gasoline, while typically providing 20% yield of ∼100 RON product when using RUL 92 RON gasoline. The OBS system makes use of wasted exhaust energy to effect the fuel separation and provides a simple and reliable means for managing the separated fuels that has been demonstrated using several generations of dual fuel test vehicles. Potential applications include downsizing to increase fuel economy by ∼10% while maintaining performance, and with turbocharging to improve knock resistance.
Journal Article

Lubricants for (Hybrid) Electric Transmissions

2013-04-08
2013-01-0298
In electric or hybrid electric transmissions, the transmission fluids can be in contact with the parts of the electric motors, for example, electrical windings in the stators in order to efficiently cool the electric motors and to insulate the electrical parts to prevent a short circuit of the electric motors. The transmission fluids must therefore have low electrical conductivities [1,2,3,4,5,6,7,8,9]. Transmission fluids contain dispersants, which can be reaction products of hydrocarbyl substituted carboxylic acids or anhydrides and amines. These dispersants can be further post-treated with boron and phosphorus compounds to improve friction and anti-wear properties. Certain dispersants, which have nitrogen content up to 10,000 ppm by weight, and boron plus phosphorus to nitrogen ((B+P)/N) weight ratios of from 0.1 to about 0.8 : 1.0, were found to be effective to provide low electrical conductivities less than 1,700 pS/m [10].
Technical Paper

Correlation of the Sequence VID Laboratory Fuel Economy Test to Real World Fuel Economy Improvements

2013-04-08
2013-01-0297
When gasoline-fueled vehicles are operated in consumer service, the oil used to lubricate the engine plays a key role in engine cooling, reducing friction, maintaining efficient operation, and optimizing fuel economy. The effects of normal vehicle operation on oil deterioration have a direct impact on fuel consumption. The authors have observed substantial differences between the deterioration of engine oil and resulting fuel economy under real-world driving conditions, and the deterioration of oils and resulting fuel economy in the standard laboratory test used to assess fuel economy in North America, the Sequence VID engine test (ASTM D7589). By analyzing the data from vehicles and comparing these data to the Sequence VID the authors have proposed and evaluated several changes to the Sequence VID test that improve the correlation with real-world operation and improve test discrimination.
Journal Article

Development of a Novel Vehicle-Based Method to Assess the Impact of Lubricant Quality on Passenger Car Energy Efficiency

2012-09-10
2012-01-1619
The traditional vehicle-based approach to measuring the effect of oil-related fuel economy has relied on separate oil-aging and measurement processes where oil-aging takes place using an established driving protocol like the EPA Approved Mileage Accumulation (AMA) Driving Schedule for vehicle aging, then at set mileage intervals fuel economy is assessed using procedures such as the EPA FTP75 and Highway Fuel Economy emission test protocols described in 40 CFR, Parts 86 and 600. These test methods are useful for producing discrete snapshots of fuel economy at set mileage intervals but are unable to provide continuous information about oil-related changes in fuel economy. During the tests, the vehicle's fuel economy is indirectly calculated using a carbon-balance method of the bagged sample of dilute tailpipe emissions that effectively integrates the fuel economy of the vehicle during the sample interval which varies between eight and fifteen minutes.
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