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Technical Paper

Assessment of Condensation Particle Counter-Based Portable Solid Particle Number System for Applications with High Water Content in Exhaust

2024-04-22
2024-01-5048
The Particle Number–Portable Emission Measurement System (PN-PEMS) came into force with Euro VI Phase E regulations starting January 1, 2022. However, positive ignition (PI) engines must comply from January 1, 2024. The delay was due to the unavailability of the PN-PEMS system that could withstand high concentrations of water typically present in the tailpipe (TP) of CNG vehicles, which was detrimental to the PN-PEMS systems. Thus, this study was designed to evaluate the condensation particle counter (CPC)-based PN-PEMS measurement capabilities that was upgraded to endure high concentration of water. The PN-PEMS measurement of solid particle number (SPN23) greater than 23 nm was compared against the laboratory-grade PN systems in four phases. Each phase differs based upon the PN-PEMS and PN system location and measurements were made from three different CNG engines. In the first phase, systems measured the diluted exhaust through constant volume sampler (CVS) tunnel.
Technical Paper

Particulate filter performance mapping for in-service conformity

2024-04-09
2024-01-2382
The proposed Euro-7 regulations are expected to build on the significant emissions reductions that have already been achieved using advanced Euro VI compliant after treatment systems (ATS). The introduction of in-service conformity (ISC) requirements during Euro VI paved the way for enabling compliance during real-world driving conditions. The diverse range of applications and resulting operating conditions greatly impact ATS design and the ability of the diesel particulate filter (DPF) to maintain performance under the most challenging boundary conditions including cold starts, partial/complete regenerations, and high passive soot burn operation. The current study attempts to map the particle number (PN) filtration performance of different DPF technologies under a variety of in-use cycles developed based on field-data from heavy duty Class-8 / N3 vehicles.
Technical Paper

Evaluation of Uncoated Gasoline Particulate Filter Performance for US EPA MY27+ Particulate Mass Emissions Regulation

2024-04-09
2024-01-2383
The gasoline particulate filter (GPF) represents a practical solution for particulate emissions control in light-duty gasoline-fueled vehicles. It is also seen as an essential technology in North America to meet the upcoming US EPA tailpipe emission regulation, as proposed in the “Multi-pollutant Rule for Model Year 2027”. The goal of this study was to introduce advanced, uncoated GPF products and measure their particulate mass (PM) reduction performance within the existing US EPA FTP vehicle testing procedures, as detailed in Code of Federal Regulations (CFR) part 1066. Various state-of-the-art GPF products were characterized for their microstructure properties with lab-bench checks for pressure drop and filtration efficiency, then pre-conditioned with an EPA-recommended 1500 mile on-road break-in, and finally were tested on an AWD vehicle chassis-dyno emissions test cell at both 25°C and -7°C ambient conditions.
Technical Paper

Next Generations of Gasoline Particulate Filters for Catalyzed Applications

2024-04-09
2024-01-2384
Gasoline particulate filters (GPF) have become a standard aftertreatment component in Europe, China, and since recently, India, where particulate emissions are based on a particle number (PN) standard. The anticipated evolution of regulations in these regions towards future EU7, CN7, and BS7 standards further enhances the needs with respect to the filtration capabilities of the GPFs used. Emission performance has to be met over a broader range in particle size, counting particles down to 10nm, and over a broader range of boundary conditions. The requirements with respect to pressure drop, aiming for as low as possible, and durability remain similar or are also enhanced further. To address these future needs new filter technologies have been developed. New technologies for uncatalyzed GPF applications have been introduced in our previous publications.
Technical Paper

Sulfur Impact on Methane Steam Reforming over the Stoichiometric Natural Gas Three-Way Catalyst

2024-04-09
2024-01-2633
The steam reforming of CH4 plays a crucial role in the high-temperature activity of natural gas three-way catalysts. Despite existing reports on sulfur inhibition in CH4 steam reforming, there is a limited understanding of sulfur storage and removal dynamics under various lambda conditions. In this study, we utilize a 4-Mode sulfur testing approach to elucidate the dynamics of sulfur storage and removal and their impact on three-way catalyst performance. We also investigate the influence of sulfur on CH4 steam reforming by analyzing CH4 conversions under dithering, rich, and lean reactor conditions. In the 4-Mode sulfur test, saturating the TWC with sulfur at low temperatures emerges as the primary cause of significant three-way catalyst performance degradation. After undergoing a deSOx treatment at 600 °C, NOx conversions were fully restored, while CH4 conversions did not fully recover.
Technical Paper

Performance Comparison Analysis between Biodiesel and Diesel over a Commercial DOC Catalyst

2024-04-09
2024-01-2707
Biodiesel is a promising alternative to traditional diesel fuel due to its similar combustion properties to diesel and lower carbon emissions on a well-to-wheel basis. However, combusting biodiesel still generates hydrocarbon (HC), CO, NOx and particulate matter (PM) emissions, similar to those from traditional diesel fuel usage. Therefore, aftertreatment systems will be required to reduce these emissions to meet increasingly stringent emission regulations to minimize the impact to the environment. Diesel oxidation catalysts (DOC) are widely used in modern aftertreatment systems to convert unburned HC and CO, to partially convert NO to NO2 to enhance downstream selective catalytic reaction (SCR) catalyst efficiency via fast SCR and to periodically clean-up DPF via controlled soot oxidation. In this work, we focus on the performance difference between biodiesel and diesel over a commercial DOC catalyst to identify the knowledge gap during the transition from diesel fuel to biodiesel.
Technical Paper

3-D Multiphase Flow Simulation of Coolant Filling and Deaeration Processes in an Engine Coolant System

2024-01-16
2024-26-0310
The thermal performance of an engine coolant system is efficient when the engine head temperature is maintained within its optimum working range. For this, it is desired that air should not be entrapped in the coolant system which can lead to localized hot spots at critical locations. However, it is difficult to eliminate the trapped air pockets completely. So, the target is to minimize the entrapped air as much as possible during the coolant filling and deaeration processes, especially in major components such as the radiator, engine head, pump etc. The filling processes and duration are typically optimized in an engine test stand along with design changes for augmenting the coolant filling efficiency. However, it is expensive and time consuming to identify air entrapped locations in tests, decide on the filling strategy and make the design changes in the piping accordingly.
Technical Paper

Challenges of Particulate Number above 10nm Emissions for a China 6 Compliant Vehicle to Meet Future Regulation

2023-04-11
2023-01-0377
As the official proposal for emission regulation Euro 7 has been released by European Commission, PN above 10nm is taken into consideration for the ultrafine particulate emissions control. The challenges of GPF filtration efficiency emerge for the light-duty manufactures to meet the future emission standards. In the present study, a China 6 compliant vehicle was tested to reveal its performance over the China 6 standards and potential to meet the upcoming Euro 7. Three GPF product types (Gen 1, Gen 2, and concept Gen 3) were mounted to the tested vehicle. WLTC tests were conducted on chassis dynamometer in laboratory as well as a self-designed aggressive cycle (“Base Cycle”) tests. To explore the GPFs performance for PN emissions above 10nm against the proposed limit 6.0E11 #/km, PN emission above 10nm were measured in our laboratory tests for both engine out and tailpipe as well as the PN emission above 23nm.
Technical Paper

The Influences of Testing Conditions on DOC Light-Off Experiments

2023-04-11
2023-01-0372
Diesel oxidation catalyst (DOC) is one of the critical catalyst components in modern diesel aftertreatment systems. It mainly converts unburned hydrocarbon (HC) and CO to CO2 and H2O before they are released to the environment. In addition, it also oxidizes a portion of NO to NO2, which improves the NOx conversion efficiency via fast SCR over the downstream selective catalytic reduction (SCR) catalyst. HC light-off tests, with or without the presence of NOx, has been typically used for DOC evaluation in laboratory. In this work, we aim to understand the influences of DOC light-off experimental conditions, such as initial temperature, initial holding time, HC species, with or without the presence of NOx, on the DOC HC light-off behavior. The results indicate that light-off test with lower initial temperature and longer initial holding time (at its initial temperature) leads to higher DOC light-off temperature.
Technical Paper

Year in Review: Progress towards Decarbonizing Transport and Near-Zero Emissions

2023-04-11
2023-01-0396
As in the past several years, we provide here an overview of recent major regulatory and technological changes for reducing emissions from the transport and off-road sector. In the past, this review was focused mostly on improvement in engine efficiency and tailpipe emissions of criteria pollutants. However, starting last year [1] we have increased the scope to broadly address the increased focus on greenhouse gas emissions and the emergence of various non-conventional fuel pathways to achieve the various decarbonization goals. There are two broad themes that are emerging, and which we describe here. Firstly, that we are approaching the implementation of the last of the major regulations on criteria pollutant emissions from cars and trucks, led by Europe, through Euro 7 standards and US, through multi-pollutant standards for light- and heavy-duty vehicles.
Technical Paper

Experimental and Modeling Study on the Thermal Aging Impact on the Performance of the Natural Gas Three-Way Catalyst

2023-04-11
2023-01-0375
The prediction accuracy of a three-way catalyst (TWC) model is highly associated with the ability of the model to incorporate the reaction kinetics of the emission process as a lambda function. In this study, we investigated the O2 and H2 concentration profiles of TWC reactions and used them as critical inputs for the development of a global TWC model. We presented the experimental data and global kinetic model showing the impact of thermal degradation on the performance of the TWC. The performance metrics investigated in this study included CH4, NOx, and CO conversions under lean, rich, and dithering light-off conditions to determine the kinetics of oxidation reactions and reduction/reforming/water-gas shift reactions as a function of thermal aging. The O2 and H2 concentrations were measured using mass spectrometry to track the change in the oxidation state of the catalyst and to determine the mechanism of the reactions under these light-off conditions.
Journal Article

Laboratory sulfation of an ammonia slip catalyst with a real-world SO2 concentration

2023-04-11
2023-01-0380
Upcoming, stricter diesel exhaust emissions standards will likely require aftertreatment architectures with multiple diesel exhaust fluid (DEF) introduction locations. Managing NH3 slip with technologies such as an ammonia slip catalyst (ASC) will continue to be critical in these future aftertreatment systems. In this study, we evaluate the impact of SO2 exposure on a state-of-the-art commercially available ASC. SO2 is co-fed at 0.5 or 3 ppmv to either approximate or accelerate a real-world exhaust SO2 impact. ASC performance during sulfur co-feeding is measured under a wide variety of simulated real-world conditions. Results indicate that the loss of NO conversion during SCR is dependent on the cumulative SO2 exposure, regardless of the inlet SO2 concentration. Meanwhile, N2O formation under SCR conditions is nonlinearly affected by SO2 exposure, with formation increasing during 0.5 ppmv SO2 exposure but decreasing in the presence of 3 ppmv SO2.
Technical Paper

Impact of Chemical Contaminants on Stoichiometric Natural Gas Engine Three-Way Catalysts with High Mileage History

2022-03-29
2022-01-0542
Stoichiometric natural gas engines with three-way catalysts emit less NOx and CH4 due to their higher efficiency compared to lean-burn natural gas engines. Although hydrothermal aging of three-way catalysts has been extensively studied, a deeper understanding beyond hydrothermal aging is needed to explain real-world performance, especially for natural gas engines with near-zero NOx emissions. In this investigation, field-aged three-way catalysts were characterized to identify the contribution of chemical aging to their overall performance. It was found that the sulfur species on the field-aged TWCs were entirely distributed along the catalyst length, showing a decreasing trend, whereas phosphorous contamination was mainly observed at the inlet section of the three-way catalysts, and the phosphorous concentration declined sharply along the axial length.
Technical Paper

Calculation Methods Impact on Real-Driving-Emissions Particulate Number Evaluation: Moving Averaging Window in China 6 vs. Raw Mileage Averaging in Euro 6d

2022-03-29
2022-01-0567
RDE test has been introduced to the light-duty vehicle certification process in both China 6 and Euro 6d standards. The RDE test shall be performed on-road with PEMS, which is developed to complement the current laboratory certification of vehicles and ensure cars to deliver low emissions under more realistic on-road driving conditions. Particulate matter has been highly perceived as a significant contributor to human health risks and thus strictly regulated globally. For the RDE evaluation, the MAW method used by the China 6 standard is usually found less stringent than the RMA method used by the Euro 6d standard. In the present study, both of the MAW and RMA methods were applied to different driving cycles and operating conditions, which met the general RDE test requirements, yet resulted in different evaluated PN results.
Technical Paper

Advanced Tire to Vehicle Connectivity for Safety and Fuel Economy of Automated Heavy-Duty Trucks

2022-03-29
2022-01-0881
Safety, fuel economy and uptime are key requirements for the operation of heavy-duty line-haul trucks within a fleet. With the penetration of connectivity and automation technologies, energy optimal and safe operation of the trucks are further improved through Advanced Driver Assistance System (ADAS) features and automated technologies as in truck platooning. Understanding the braking capability of the vehicle is very important for optimal ADAS and platooning control system design and integration. In this paper, the importance of tire connectivity and tire conditions on truck stopping distance are demonstrated through testing. The test data is further utilized to develop tire models for integration in an optimal vehicle automation for platooning. New ways to produce and use the tire related information in real-time optimal control of platooning trucks are proposed and the contribution of tire information in fuel economy is quantified through simulations.
Journal Article

An Evaluation of an Unhealthy Part Identification Using a 0D-1D Diesel Engine Simulation Based Digital Twin

2022-03-29
2022-01-0382
Commercial automotive diesel engine service and repair, post a diagnostic trouble code trigger, relies on standard troubleshooting steps laid down to identify or narrow down to a faulty engine component. This manual process is cumbersome, time-taking, costly, often leading to incorrect part replacement and most importantly usually associated with significant downtime of the vehicle. Current study aims to address these issues using a novel in-house simulation-based approach developed using a Digital Twin of the engine which is capable of conducting in-mission troubleshooting with real world vehicle/engine data. This cost-effective and computationally efficient solution quickly provides the cause of the trouble code without having to wait for the vehicle to reach the service bay. The simulation is performed with a one-dimensional fluid dynamics, detailed thermodynamics and heat transfer-based diesel engine model utilizing the GT-POWER engine performance tool.
Journal Article

Review of Vehicle Engine Efficiency and Emissions

2022-03-29
2022-01-0540
This review covers advances in regulations and technologies in the past year in the field of vehicular emissions. We cover major developments towards reducing criteria pollutants and greenhouse gas emissions from both light- and heavy-duty vehicles and off-road machinery. To suggest that the transportation is transforming rapidly is an understatement, and many changes have happened already since our review last year [1]. Notably, the US and Europe revised the CO2 standards for light-duty vehicles and electrification mandates were introduced in various regions of the world. These have accelerated plans to introduce electrified powertrains, which include hybrids and pure electric vehicles. However, a full transformation to electric vehicles and the required grid decarbonization will take time, and policy makers are accordingly also tightening criteria pollutant standards for internal combustion engines.
Journal Article

Effect of Decoration on Windshield Impact Resistance and Novel Decoration Solution Compatible with Chemical Strengthening

2022-03-29
2022-01-0263
Vehicle windshields typically include a black decorative pattern around their periphery and other regions. Examination of field failed parts has shown that windshields often break from impacts in these decoration zones; often with the fracture initiating from the decoration material itself. In this work, the effect of different glazing decoration materials on glass strength and laminate impact resistance was evaluated. The decoration materials investigated included traditional inorganic enamel frit, an organic ink, and a new enamel frit that is compatible with glass chemical strengthening. Ring-on-Ring strength tests were conducted and showed that inorganic enamel frit reduces strength of glass by over 50% compared to undecorated glass, while organic inks do not adversely affect strength. Tests of a newly developed decoration frit material, compatible for chemical strengthening processes, showed strength levels that were on par with undecorated, unstrengthened glass.
Technical Paper

A Study of Emission Durability and Ash Accumulation of “Advanced Three-way Catalyst Integrated on Gasoline Particulate Filter” for BS6 (Stage2) Applications

2021-09-22
2021-26-0182
India BS6 Stage2 (2023) regulations demand all gasoline direct injection (GDI) vehicles to meet particulate number emissions (PN) below 6x10+11# per km. Gasoline particulate filters (GPF) are a proven technology and enable high PN filtration efficiencies throughout the entire vehicle lifetime. One challenge for GPF applications could be the changing emission performance characteristics as a function of mileage due to collected ash and/or soot deposits with implications on back pressure losses. The main objective of this technical contribution is to study the above-mentioned challenges while applying Indian driving conditions and typical Indian climate and other ambient conditions. The substrate technology selected for this study is a high porosity GPF designed to enable the integration of a three-way functionality into the GPF, commonly described as catalyzed GPF (cGPF).
Journal Article

Next Generation Gasoline Particulate Filters for Uncatalyzed Applications and Lowest Particulate Emissions

2021-04-06
2021-01-0584
With the introduction of EU6d and CN6 all vehicles with gasoline direct injection and many with port fuel injection engine will be equipped with a gasoline particulate filter (GPF). A range of first generation filter technologies has been introduced successfully, helping to significantly reduce the tailpipe particulate number emissions. The continued focus on particulate emissions and the increasing understanding of their impact on human health, combined with the advanced emission regulations under RDE conditions results in the desire for filters with even higher filtration efficiency, especially in the totally fresh state. At the same time, to balance with the requirements on power and CO2, limitations exist with respect to the tolerable pressure drop of filters. In this paper we will report on a new generation of gasoline particulate filters for uncatalyzed applications.
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