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Technical Paper

Assessment of Condensation Particle Counter-Based Portable Solid Particle Number System for Applications with High Water Content in Exhaust

2024-04-22
2024-01-5048
The Particle Number–Portable Emission Measurement System (PN-PEMS) came into force with Euro VI Phase E regulations starting January 1, 2022. However, positive ignition (PI) engines must comply from January 1, 2024. The delay was due to the unavailability of the PN-PEMS system that could withstand high concentrations of water typically present in the tailpipe (TP) of CNG vehicles, which was detrimental to the PN-PEMS systems. Thus, this study was designed to evaluate the condensation particle counter (CPC)-based PN-PEMS measurement capabilities that was upgraded to endure high concentration of water. The PN-PEMS measurement of solid particle number (SPN23) greater than 23 nm was compared against the laboratory-grade PN systems in four phases. Each phase differs based upon the PN-PEMS and PN system location and measurements were made from three different CNG engines. In the first phase, systems measured the diluted exhaust through constant volume sampler (CVS) tunnel.
Technical Paper

Sulfur Impact on Methane Steam Reforming over the Stoichiometric Natural Gas Three-Way Catalyst

2024-04-09
2024-01-2633
The steam reforming of CH4 plays a crucial role in the high-temperature activity of natural gas three-way catalysts. Despite existing reports on sulfur inhibition in CH4 steam reforming, there is a limited understanding of sulfur storage and removal dynamics under various lambda conditions. In this study, we utilize a 4-Mode sulfur testing approach to elucidate the dynamics of sulfur storage and removal and their impact on three-way catalyst performance. We also investigate the influence of sulfur on CH4 steam reforming by analyzing CH4 conversions under dithering, rich, and lean reactor conditions. In the 4-Mode sulfur test, saturating the TWC with sulfur at low temperatures emerges as the primary cause of significant three-way catalyst performance degradation. After undergoing a deSOx treatment at 600 °C, NOx conversions were fully restored, while CH4 conversions did not fully recover.
Technical Paper

An Approach for Incorporating Learning into System Design: System Level Assessment Methodology

2023-09-05
2023-01-1517
Shafaat and Kenley in 2015 identified the opportunity to improve System Engineering Standards by incorporating the design principle of learning. The System Level Assessment (SLA) Methodology is an approach that fulfills this need by efficiently capturing the learnings of a team of subject matter experts in the early stages of product system design. By gathering expertise, design considerations are identified that when used with market and business requirements improve the overall quality of the product system. To evaluate the effectiveness of this approach, the methodology has been successfully applied over 400 times within each realm of the New Product Introduction process, including most recently to a Technology Development program (in the earliest stages of the design process) to assess the viability of various electrification technologies under consideration by an automotive Tier 1 supplier.
Journal Article

An Evaluation of an Unhealthy Part Identification Using a 0D-1D Diesel Engine Simulation Based Digital Twin

2022-03-29
2022-01-0382
Commercial automotive diesel engine service and repair, post a diagnostic trouble code trigger, relies on standard troubleshooting steps laid down to identify or narrow down to a faulty engine component. This manual process is cumbersome, time-taking, costly, often leading to incorrect part replacement and most importantly usually associated with significant downtime of the vehicle. Current study aims to address these issues using a novel in-house simulation-based approach developed using a Digital Twin of the engine which is capable of conducting in-mission troubleshooting with real world vehicle/engine data. This cost-effective and computationally efficient solution quickly provides the cause of the trouble code without having to wait for the vehicle to reach the service bay. The simulation is performed with a one-dimensional fluid dynamics, detailed thermodynamics and heat transfer-based diesel engine model utilizing the GT-POWER engine performance tool.
Technical Paper

Impact of Using Low Thermal Mass Turbine Housing on Exhaust Temperature with Implication on Aftertreatment Warm-Up Benefit for Emissions Reduction

2020-09-02
2020-01-5083
The present study examines the impact of using low thermal mass (LTM) turbine housing designs on the transient characteristics of the turbine outlet temperature for a light-duty diesel standard certification cycle (FTP75). For a controlled exhaust flow, the turbine outlet temperature will directly determine the impact on an aftertreatment system warm-up from a cold state, typical of engine-off and engine idling conditions. The performance of the aftertreatment system such as a Selective Catalytic Reduction (SCR) system is highly dependent on how quickly it warms up to its desirable temperature to be able to convert the harmful oxides of Nitrogen (NOx) to gaseous Nitrogen. Previous works have focused on mostly insulating the exhaust manifold and turbine housing to conserve the heat going into the aftertreatment system. The use of LTM turbine housing has not been previously considered as a means for addressing this requirement.
Technical Paper

Flux Residue and Migration in Charge Air-Cooled Engines

2020-03-27
2019-01-5083
Traditionally, most charge air coolers (CACs) have been constructed using the Nocolok aluminum brazing process. The Nocolok process uses flux, some of which remains after the manufacturing process, and migrates through the intake tract to the engine during normal use. This migration and deposition on engine components can cause a variety of issues with engine operation. Currently the only alternative to Nocolok brazed CACs for engines sensitive to flux migration is vacuum brazing, which comes at a significant price increase. In the effort to reduce cost and increase efficiency, there is interest in whether a Nocolok brazed CAC with a reduced amount of flux residue can be successfully applied to flux-sensitive engines.
Technical Paper

Reactor System with Diesel Injection Capability for DOC Evaluations

2018-04-03
2018-01-0647
Plug flow reactors, simulating engine exhaust gas, are widely used in emissions control research to gain insight into the reaction mechanisms and engineering aspects that controls activity, selectivity, and durability of catalyst components. The choice of relevant hydrocarbon (HC) species is one of the most challenging factor in such laboratory studies, given the variety of compositions that can be encountered in different application scenarios. Furthermore, this challenge is amplified by the experimental difficulties related to introducing heavier and multi-component HCs and analyzing the reaction products.
Technical Paper

Experimental and Kinetic Modeling of Degreened and Aged Three-way Catalysts: Aging Impact on Oxygen Storage Capacity and Catalyst Performance

2018-04-03
2018-01-0950
The aging impact on oxygen storage capacity (OSC) and catalyst performance was investigated on one degreened and one aged (hydrothermally aged at 955 °C for 50 h) commercial three-way catalyst (TWC) by experiments and modeling. The difference of OSC between the degreened and aged TWCs was dependent on catalyst temperature. The largest difference was found at 600 °C, at which the amount of OSC decreased by 45.5%. Catalyst performance was evaluated through lightoff tests at two simulated engine exhaust conditions (lean and rich) on a micro-reactor. The aging impact on the catalyst performance was different under lean and rich environments and investigated separately. At the lean condition, oxidation of CO and C3H6 was significantly suppressed while oxidation of C3H8 was relatively less degraded. At the rich condition, the inhibition effect was more pronounced on the aged TWC and inhibiting hydrocarbon species from C3H6 partial oxidation can survive at temperatures up to 450 °C.
Technical Paper

FEM Simulation Methodology for Accurately Capturing the Experimental Vibration Response of ECM Assembly on a Commercial Vehicle

2018-04-03
2018-01-0467
This paper presents an experimental setup and an equivalent FEM simulation methodology to accurately predict the response of Engine Control Module (ECM) assembly mounted on a commercial vehicle subjected to road vibrations. Comprehensive vibration study is carried out. It involved Modal characteristics determination followed by random vibration characterization of the ECM assembly. A hammer impact experiment is first performed in lab to estimate the natural frequencies and mode shapes of ECM assembly. Mounting conditions in test specimen are kept similar to the actual mounting settings on vehicle. Natural frequencies and mode shapes predicted from free vibration experiment are compared with finite element (FE) based modal analysis. The importance of capturing the assembly stiffness more accurately by incorporating pre-stress effects like bolt-pretension and gravity, is emphasized.
Technical Paper

Gear Interference-Fit Joint Considerations and Design for the Resultant Tooth Distortion

2018-04-03
2018-01-1293
Automotive timing gear trains, transmission gearboxes, and wind turbine gearboxes are some of the application examples known to use interference-fit to attach the gear to the rotating shaft. This paper discusses the interference-fit joint design and the finite element analysis to demonstrate the distortion. The mechanism of tooth profile distortion due to the interference-fit assembly in gear trains is discussed by demonstrating the before and after assembly gear profile measurements. An algorithm to calculate the profile slope deviation change is presented. The effectiveness of the computational algorithm to predict the distortion is demonstrated by comparing with measurements. Finally, steps to mitigate the interference assembly effects are discussed.
Technical Paper

Diesel Engines Gear Whine: Production Plant Perspective

2017-06-05
2017-01-1809
Engine noise is one of the significant aspects of product quality for light and medium duty diesel engine market applications. Gear whine is one of those noise issues, which is considered objectionable and impacts the customer’s perception of the product quality. Gear whine could result due to defects in the gear manufacturing process and/or due to inaccurate design of the gear macro and micro geometry. The focus of this technical paper is to discuss gear whine considerations from the production plant perspective. This includes quick overview of the measurement process, test cell environment, noise acceptance criteria considerations. A gear whine case study is presented based on the data collected in the test cell at the engine plant. Gear whine data acquired on current product and next generation of prototype engines is analyzed and presented. This paper concludes by highlighting the lessons learned from the case study.
Journal Article

Effect of Transition Metal Ion Properties on the Catalytic Functions and Sulfation Behavior of Zeolite-Based SCR Catalysts

2017-03-28
2017-01-0939
Copper- and Iron- based metal-zeolite SCR catalysts are widely used in US and European diesel aftertreatment systems to achieve drastic reduction in NOx emission. These catalysts are highly selective to N2 under wide range of operating conditions. Nevertheless, the type of transition metal has a significant impact on the key performance and durability parameters such as NOx conversion, selectivity towards N2O, hydrothermal stability, and sensitivity to fuel sulfur content. In this study, we explained the differences in the performance characteristics of these catalysts based on their relative acidic-basic nature of transition metal present in these catalysts using practically relevant gas species present in diesel exhaust such as NO2, SOx, and NH3. These experiments show that Fe-zeolite has relatively acidic nature as compared to Cu-zeolite that causes NH3 inhibition and hence explains low NOx conversion on Fe-zeolite at low temperature under standard SCR conditions.
Technical Paper

Lean Breakthrough Phenomena Analysis for TWC OBD on a Natural Gas Engine using a Dual-Site Dynamic Oxygen Storage Capacity Model

2017-03-28
2017-01-0962
Oxygen storage capacity (OSC) is one of the most critical characteristics of a three-way catalyst (TWC) and is closely related to the catalyst aging and performance. In this study, a dynamic OSC model involving two oxygen storage sites with distinct kinetics was developed. The dual-site OSC model was validated on a bench reactor and a natural gas engine. The model was capable of predicting temperature dependence on OSC with H2, CO and CH4 as reductants. Also, the effects of oxygen concentration and space velocity on the amount of OSC were captured by the model. The validated OSC model was applied to simulate lean breakthrough phenomena with varied space velocities and oxygen concentrations. It is found that OSC during lean breakthrough is not a constant for a particular TWC catalyst and is dependent on space velocity and oxygen concentration. Specifically, breakthrough time exhibits a non-linear, inverse correlation to oxygen flux.
Technical Paper

Development of a Kinetic Model to Evaluate Water Storage on Commercial Cu-Zeolite SCR Catalysts during Cold Start

2017-03-28
2017-01-0968
Commercial Cu-Zeolite SCR catalyst can store and subsequently release significant amount of H2O. The process is accompanied by large heat effects. It is critical to model this phenomenon to design aftertreatment systems and to provide robust tuning strategies to meet cold start emissions and low temperature operation. The complex reaction mechanism of water adsorption and desorption over a Cu-exchanged SAPO-34 catalyst at low temperature was studied through steady state and transient experiments. Steady state isotherms were generated using a gravimetric method and then utilized to predict water storage interactions with respect to feed concentration and catalyst temperature. Transient temperature programmed desorption (TPD) experiments provided the kinetic information required to develop a global kinetic model from the experimental data. The model captures fundamental characteristics of water adsorption and desorption accompanied by the heat effects.
Technical Paper

Automotive Selective Catalytic Reduction System Model-Based Estimators for On-ECU Implementation: A Brief Overview

2016-04-05
2016-01-0972
The amount of ammonia stored on the walls of the catalyst (or ammonia storage) is a parameter with significant impact on NOx reduction efficiency and undesired ammonia slip of Selective Catalytic Reduction catalysts. This makes the ammonia storage interesting for utilization in urea injection control. However, ammonia storage is not directly measurable onboard vehicles, it can only be estimated. Model-based online estimation requires models that are capable of capturing the main phenomena of the SCR and at the same time can be computed onboard vehicle. While the modeling of SCR and model-based control is well present in the literature, it is apparent that few attempts of implementing the models on production ECUs were published. This paper reviews literature on ammonia storage, outlet NH3 and NOx concentration estimation in SCR and SCR/DPF systems-including the estimation of NOx sensor cross-sensitive to NH3-in order to present the state of the art.
Technical Paper

New Insights into the Unique Operation of Small Pore Cu-Zeolite SCR Catalyst: Overlapping NH3 Desorption and Oxidation Characteristics for Minimizing Undesired Products

2014-04-01
2014-01-1542
An operational challenge associated with SCR catalysts is the NH3 slip control, particularly for commercial small pore Cu-zeolite formulations as a consequence of their significant ammonia storage capacity. The desorption of NH3 during increasing temperature transients is one example of this challenge. Ammonia slipping from SCR catalyst typically passes through a platinum based ammonia oxidation catalyst (AMOx), leading to the formation of the undesired byproducts NOx and N2O. We have discovered a distinctive characteristic, an overlapping NH3 desorption and oxidation, in a state-of-the-art Cu-zeolite SCR catalyst that can minimize NH3 slip during temperature transients encountered in real-world operation of a vehicle.
Technical Paper

Development and Demonstration of a Soot Generator Integrated Bench Reactor

2014-04-01
2014-01-1589
Experimental evaluation of soot trapping and oxidation behaviors of various diesel particulate filters (DPF) has been traditionally hampered by several experimental difficulties, such as the deposition of soot particles with well-characterized and consistent properties, and the tracking of the soot oxidation rate in real time. In the present study, an integrated bench flow-reactor system with a soot generator has been developed and its capabilities were demonstrated with regards to: Consistently and controllably loading soot on DPF samples; Monitoring the exhaust gas composition by FTIR, including quantification of the soot oxidation rate using CO and CO2; Measuring soot oxidation characteristics of various DPF samples. Soot particles were produced from a laminar propane co-flow diffusion flame.
Journal Article

Internal Diesel Injector Deposits: Theory and Investigations into Organic and Inorganic Based Deposits

2013-10-14
2013-01-2670
Over the last two decades, global emission regulations have become more stringent and have required the use of more advanced fuel injection systems. This includes the use of tighter tolerances, more rapid injections and internal components actuated by weaker injection forces. Unfortunately, these design features make the entire system more susceptible to fuel contaminants. Over the last six years, the composition of these contaminants has evolved from hard insoluble debris, such as dust and rocks, to soluble chemical contaminants. Recent research by the diesel engine manufacturers, fuel injection equipment suppliers and the fuel and fuel additive industry has discovered a major source of the soluble chemical contaminant that leads to injector deposits to be derived from cost effective and commonly used additives used to protect against pipeline corrosion.
Technical Paper

The Effects of Thermal Degradation on the Performance of a NOX Storage/Reduction Catalyst

2009-04-20
2009-01-0631
The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.
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