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Selective Catalytic Reduction (SCR) is a process where one injects an aqueous solution of urea into a diesel exhaust system in order to reduce NOx emissions. The urea solution known as AdBlue® or Diesel Exhaust Fluid (DEF) is stored in a DEF Tank that can under cold weather conditions freeze over. Since AdBlue® is unusable while frozen, we use heaters installed in the tanks to melt AdBlue® with government regulations mandating time required to melt AdBlue® in the tank. In this article, we investigate whether a CFD (Computational Fluid Dynamics) based methodology can accurately evaluate time required in melting AdBlue® for a given DEF Tank and heater coil design for a production vehicle as per standard testing procedure. Simulations used a coupled methodology with PowerFLOW® as the flow solver and PowerTHERM® as the thermal solver. The flow simulation did require an accurate modelling of phase change from solid to liquid for AdBlue®.