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Technical Paper

Fuel Property Effects of a Broad Range of Potential Biofuels on Mixing Control Compression Ignition Engine Performance and Emissions

2021-04-06
2021-01-0505
Conventional diesel engines will continue to hold a vital role in the heavy- and medium-duty markets for the transportation of goods along with many other uses. The ability to offset traditional diesel fuels with low-net-carbon biofuels could have a significant impact on reducing the carbon footprint of these vehicles. A prior study screened several hundred candidate biofuel blendstocks based on required diesel blendstock properties and identified 12 as the most promising. Eight representative biofuel blendstocks were blended at a 30% volumetric concentration with EPA certification ultra-low-sulfur diesel (ULSD) and were investigated for emissions and fuel efficiency performance. This study used a single cylinder engine (based on the Ford 6.7L engine) using Conventional Diesel Combustion (CDC), also known as Mixing Control Compression Ignition (MCCI). The density, cetane number, distillation curve and sooting tendency (using the yield sooting index method) of the fuels were measured.
Technical Paper

Micro-Channel Heat Exchanger: An Exhaust Waste Heat Recovery Device

2018-04-03
2018-01-0052
Almost one-third of the fuel energy is wasted through the exhaust of a vehicle. An efficient waste heat recovery (WHR) process will undoubtedly lead to improved fuel efficiency and reduced greenhouse gases (GHG) emission. Currently, there are multiple WHR technologies that are being investigated by various entities in the auto industry. One relatively simple device to extract heat energy from the exhaust is a heat exchanger. Heat exchangers are used in some automotive applications to transfer heat from the hot exhaust gas to the colder coolant fluid to raise the coolant temperature. The warmer coolant fluid can be used for several purposes such as; faster heating of the engine’s lubrication oil and transmission fluids during cold starts, and faster cabin heating, which in turn, can potentially improve the overall engine efficiency and reduce exhaust emissions.
Technical Paper

Sustained Low Temperature NOx Reduction

2018-04-03
2018-01-0341
Sustained NOx reduction at low temperatures, especially in the 150-200 °C range, shares some similarities with the more commonly discussed cold-start challenge, however, poses a number of additional and distinct technical problems. In this project, we set a bold target of achieving and maintaining 90% NOx conversion at the SCR catalyst inlet temperature of 150 °C. This project is intended to push the boundaries of the existing technologies, while staying within the realm of realistic future practical implementation. In order to meet the resulting challenges at the levels of catalyst fundamentals, system components, and system integration, Cummins has partnered with the DOE, Johnson Matthey, and Pacific Northwest National Lab and initiated the Sustained Low-Temperature NOx Reduction program at the beginning of 2015 and completed in 2017.
Journal Article

Real-time Sensing of Particulate Matter in a Vehicle Exhaust System

2017-03-28
2017-01-1639
Onboard diagnostic regulations require performance monitoring of diesel particulate filters used in vehicle aftertreatment systems. Delphi has developed a particulate matter (PM) sensor to perform this function. The objective of this sensor is to monitor the soot (PM) concentration in the exhaust downstream of the diesel particulate filter which provides a means to calculate filter efficiency. The particulate matter sensor monitors the deposition of soot on its internal sensing element by measuring the resistance of the deposit. Correlations are established between the soot resistance and soot mass deposited on the sensing element. Currently, the sensor provides the time interval between sensor regeneration cycles, which, with the knowledge of the exhaust gas flow parameters, is correlated to the average soot concentration.
Journal Article

Selection Criteria and Screening of Potential Biomass-Derived Streams as Fuel Blendstocks for Advanced Spark-Ignition Engines

2017-03-28
2017-01-0868
We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.
Technical Paper

The Role of Second Phase Hard Particles on Hole Stretchability of Two AA6xxx Alloys

2017-03-28
2017-01-0307
The hole stretchability of two Aluminum Alloys (AA6111 and AA6022) are studied by using a two stages integrated finite element framework where the edge geometry and edge damages from the hole piercing processes were considered in the subsequent hole expansion processes. Experimentally it has been found that AA6022 has higher hole expansion ratios than those of AA6111. This observation has been nicely captured by finite element simulations. The main cause of differences have been identified to the volume fractions of the random distributed second phase hard particles which play a critical role in determining the fracture strains of the materials.
Technical Paper

Development of Electrical-Electronic Controls for a Gasoline Direct Injection Compression Ignition Engine

2016-04-05
2016-01-0614
Delphi is developing a new combustion technology called Gasoline Direct-injection Compression Ignition (GDCI), which has shown promise for substantially improving fuel economy. This new technology is able to reuse some of the controls common to traditional spark ignition (SI) engines; however, it also requires several new sensors and actuators, some of which are not common to traditional SI engines. Since this is new technology development, the required hardware set has continued to evolve over the course of the project. In order to support this development work, a highly capable and flexible electronic control system is necessary. Integrating all of the necessary functions into a single controller, or two, would require significant up-front controller hardware development, and would limit the adaptability of the electronic controls to the evolving requirements for GDCI.
Technical Paper

Optimal SCR Control Using Data-Driven Models

2013-04-08
2013-01-1573
In this paper, we develop a method for optimizing urea dosing to minimize the downstream readings from a production NOx sensor that has cross-sensitivity to ammonia. This approach favors high NOx conversion and reduced ammonia slip. The motivation for this work is to define a process to identify the maximum selective catalytic reduction SCR performance bounds for a given drive cycle. The approach uses a model structure that has a closed-form optimal solution for the urea injection. Every aftertreatment system has its own, unique model, which must be identified and validated. To demonstrate the approach, a model is identified and validated using experimental SCR input/output NOx sensor data from a 2010 Cummins 6.7L ISB production engine. The optimal control law is then simulated and its performance compared against the simulated performance of the SCR using experimental data for its inlet conditions.
Technical Paper

1D Model of a Copper Exchanged Small Pore Zeolite Catalyst Based on Transient SCR Protocol

2013-04-08
2013-01-1578
Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.
Technical Paper

Energy Harvesting as Strategy for Reducing Vehicles Emissions

2012-10-02
2012-36-0114
In vehicular mobility context, it is extremely important for the environmental sustainability that the available energy will be used as efficiently as possible, both in the use of internal combustion engines (ICE) as powertrain, as well in the application of Hybrid and Electric Vehicle Motors (HEV/EV). In this comparison, ICE has a lower efficiency when compared to electric motors, wasting much of the potential energy of the fuel in form of heat and noise. On the other hand, the electric vehicles face limitation in autonomy and recharge time, demanding for a more efficient use of energy stored in batteries. This study aims to present emerging technologies for reuse of energy within the automotive context, originally known as “Energy Harvesting” and “Renewable Energies”.
Journal Article

Modeling Species Inhibition and Competitive Adsorption in Urea-SCR Catalysts

2012-04-16
2012-01-1295
Although the urea-SCR technology exhibits high NO reduction efficiency over a wide range of temperatures among the lean NO reduction technologies, further improvement in low-temperature performance is required to meet the future emission standards and to lower the system cost. In order to improve the catalyst technologies and optimize the system performance, it is critical to understand the reaction mechanisms and catalyst behaviors with respect to operating conditions. Urea-SCR catalysts exhibit poor NO reduction performance at low-temperature operating conditions (T ≺ 150°C). We postulate that the poor performance is either due to NH₃ storage inhibition by species like hydrocarbons or due to competitive adsorption between NH₃ and other adsorbates such as H₂O and hydrocarbons in the exhaust stream. In this paper we attempt to develop one-dimensional models to characterize inhibition and competitive adsorption in Fe-zeolite-based urea-SCR catalysts based on bench reactor experiments.
Journal Article

Particulate Matter Sampling and Volatile Organic Compound Removal for Characterization of Spark Ignited Direct Injection Engine Emissions

2011-08-30
2011-01-2100
More stringent emissions regulations are continually being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular particulate matter (PM) emissions should be regulated based on particle number in addition to particle mass. One aspect of this project is to study different sample handling methods for number-based aerosol measurements, specifically, two different methods for removing volatile organic compounds (VOCs). One method is a thermodenuder (TD) and the other is an evaporative chamber/diluter (EvCh). These sample-handling methods have been implemented in an engine test cell with a spark-ignited direct injection (SIDI) engine. The engine was designed for stoichiometric, homogeneous combustion.
Technical Paper

Particulate Characteristics for Varying Engine Operation in a Gasoline Spark Ignited, Direct Injection Engine

2011-04-12
2011-01-1220
The objective of this research is a detailed investigation of particulate sizing and number count from a spark-ignited, direct-injection (SIDI) engine at different operating conditions. The engine is a 549 [cc] single-cylinder, four-valve engine with a flat-top piston, fueled by Tier II EEE. A baseline engine operating condition, with a low number of particulates, was established and repeatability at this condition was ascertained. This baseline condition is specified as 2000 rpm, 320 kPa IMEP, 280 [°bTDC] end of injection (EOI), and 25 [°bTDC] ignition timing. The particle size distributions were recorded for particle sizes between 7 and 289 [nm]. The baseline particle size distribution was relatively flat, around 1E6 [dN/dlogDp], for particle diameters between 7 and 100 [nm], before dropping off to decreasing numbers at larger diameters. Distributions resulting from a matrix of different engine conditions were recorded.
Technical Paper

Diesel Particulate Oxidation Model: Combined Effects of Volatiles and Fixed Carbon Combustion

2010-10-25
2010-01-2127
Diesel particulate samples were collected from a light duty engine operated at a single speed-load point with a range of biodiesel and conventional fuel blends. The oxidation reactivity of the samples was characterized in a laboratory reactor, and BET surface area measurements were made at several points during oxidation of the fixed carbon component of both types of particulate. The fixed carbon component of biodiesel particulate has a significantly higher surface area for the initial stages of oxidation, but the surface areas for the two particulates become similar as fixed carbon oxidation proceeds beyond 40%. When fixed carbon oxidation rates are normalized to total surface area, it is possible to describe the oxidation rates of the fixed carbon portion of both types of particulates with a single set of Arrhenius parameters. The measured surface area evolution during particle oxidation was found to be inconsistent with shrinking sphere oxidation.
Technical Paper

Hydrocarbon Effect on a Fe-zeolite Urea-SCR Catalyst: An Experimental and Modeling Study

2010-04-12
2010-01-1171
Synergies between various catalytic converters such as SCR and DPF are vital to the success of an integrated aftertreatment system for simultaneous NO and particulate matter control in diesel engines. Several issues such as hydrocarbon poisoning, thermal aging and other coupled aftertreatment dynamics need to be addressed to develop an effective emission control system. This work is significant especially in an integrated DPF-SCR aftertreatment scenario where the SCR catalyst on the filter substrate is exposed to un-burnt diesel hydrocarbons during active regeneration of the particulate filter. This paper reports an experimental and modeling study to understand the effect of hydrocarbons on a Fe-zeolite urea-SCR catalyst. Several bench-reactor tests to understand the inhibition of NO oxidation, to characterize hydrocarbon storage and to investigate the impact of hydrocarbons on SCR reactions were conducted.
Technical Paper

Visualization Techniques for Single Channel DPF Systems

2007-04-16
2007-01-1126
New techniques have been developed to visualize soot deposition in both traditional and new diesel particulate filter (DPF) substrate materials using a modified cyanoacrylate fuming technique. Loading experiments have been conducted on a variety of single channel DPF substrates to develop a deeper understanding of soot penetration, soot deposition characteristics, and to confirm modeling results. Early results indicate that stabilizing the soot layer using a vaporized adhesive (Cynoacrylate) may allow analysis of the layer with new methods.
Technical Paper

Optimizing the Advanced Ceramic Material for Diesel Particulate Filter Applications

2007-04-16
2007-01-1124
This paper describes the application of pore-scale filtration simulations to the advanced ceramic material (ACM) developed for use in advanced diesel particulate filters. The application required the generation of a three-dimensional substrate geometry to provide the boundary conditions for the flow model. An innovative stochastic modeling technique was applied matching chord length distribution and the porosity profile of the material. Additional experimental validation was provided by the single-channel experimental apparatus. Results show that the stochastic reconstruction techniques provide flexibility and appropriate accuracy for the modeling efforts. Early investigation efforts imply that needle length may provide a mechanism for adjusting performance of the ACM for diesel particulate filter (DPF) applications. New techniques have been developed to visualize soot deposition in both traditional and new DPF substrate materials.
Technical Paper

Palladium/Rhodium Dual-Catalyst LEV 2 and Bin 4 Close-Coupled Emission Solutions

2007-04-16
2007-01-1263
Dual-monolith catalyst systems containing Pd/Rh three-way catalysts (TWCs) provide effective emission solutions for LEV2/Bin 5 and Bin 4 close-coupled applications at low PGM loadings. These systems combine washcoat technology and PGM distribution for front and rear catalysts resulting in optimal hydrocarbon and NOx light-off and transient NOx control. The dual-catalyst [Pd/Rh + Pd/Rh] systems are characterized as a function of Pd-Rh content, PGM location, and catalyst technology for 4-cyl [close-coupled + underfloor] systems and 6-cyl close-coupled applications. The current Pd/Rh dual-catalyst converters significantly reduce NOx emissions compared to earlier [Pd + Pt/Rh] or [Pd + Pd/Rh] LEV/ULEV systems by utilizing uniform Rh distribution and new OSC materials. These new design strategies particularly impact NOx performance, especially during transient A/F excursions.
Technical Paper

Modeling of Friction Stir Welding (FSW) Process with Smooth Particle Hydrodynamics (SPH)

2006-04-03
2006-01-1394
Since its invention fifteen years ago, Friction Stir Welding (FSW) has found commercial applications in marine, aerospace, rail, and now automotive industries. Development of the FSW process for each new application, however, has remained largely empirical. Few detailed numerical modeling techniques have been developed that can explain and predict important features of the process physics. This is particularly true in the areas of material flow, mixing mechanisms, and void prediction. In this paper we present a novel modeling approach to simulate FSW processes that may have significant advantages over current traditional finite element or finite difference based methods. The proposed model is based on the Smoothed Particle Hydrodynamics (SPH) method.
Technical Paper

The New Wireless Frontier: Home and Vehicle Connectivity

2004-10-18
2004-21-0068
Our customers expect in their vehicles the same constant connectivity that they experience in their homes through high speed internet portals. New services based on these advances will be transparent and ubiquitous - completely integrated into our lives, just as electricity comes to the wall socket or water from the faucet. The Wi-Fi Radio implements this vision using Wireless Fidelity (Wi-Fi) based on the suite of IEEE 802.11 standards. Drivers have constant wireless connectivity and personalized digital content made available to them through the Wi-Fi Radio. Ford and our partner Delphi developed the Wi-Fi Radio to overcome the inherent functional and packaging limitations of our vehicles, to quickly introduce new technology at affordable prices and to seamlessly integrate new services into the vehicle. We chose the radio as the integration site because the radio is accessible to every customer and affordable on every vehicle.
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