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A highly anti-corrosive organic-inorganic hybrid paint for automotive steel parts has been developed. The inorganic component included in the paint is silicon dioxide (SiO2), which has the capability to passivate zinc. By application of the paint on a trivalent chromatetreated zinc-plated steel sheet or a trivalent chromate-treated zinc-nickel-plated steel sheet, high anti-corrosion protection can be provided to steel materials. Particularly in the case of application over a zinc-nickel-plated steel sheet, 0 mm corrosion depth after a cyclic corrosion test (CCT) of 450 cycles was demonstrated.

The dissolution and exfoliation of chromium plating specific to Russia was studied. Investigation and analysis of organic compounds in Russian soil revealed contents of highly concentrated fulvic acid. Additionally, it was found that fulvic acid, together with CaCl2 (a deicing agent), causes chromium plating corrosion. The fulvic acid generates a compound that prevents reformation of a passivation film and deteriorates the sacrificial corrosion effectiveness of nickel.

Current and future engine technologies and fuels are mutually dependent. The increased use of alternative fuels has been linked to deterioration in performance of injectors, fuel filters and engines as a result of insoluble deposit formation. The present work aimed to study the impact of Diesel/biodiesel blends formulation (biodiesel feedstock and content) and temperature on the oxidation stability based on total acid number (TAN). The biofuels used in the fuel matrix were: rapeseed, soy and palm methyl esters (RME, SME and PME respectively). The Diesel/biodiesel blends were made with 0%v/v, 5%v/v, 10% v/v and 20%v/v of biodiesel blended with additive-free new Diesel. The oxidation stability of Diesel/biodiesel blends was to evaluate during 6 months fuels storage, under 20°C and 40°C, and fuels severe oxidation into a reactor vessel to better understand the parameters leading to fuel oxidation on-board.

The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.

To evaluate the influence of FAME, which has poor oxidation stability, on engine oil performance, an engine test was conducted under large volumes of fuel dilution by post-injection. The test showed that detergent consumption and polymerization of FAME were accelerated in engine oil, causing a severe deterioration in piston cleanliness and sludge protection performance of engine oil.

Transmission electron microscope (TEM) is a powerful tool for studying catalyst materials at nano-size and/or atomic level. Conventional TEM usually needs to be observed at room temperature in high vacuum conditions. A gaseous atmosphere and high temperature condition may change the properties of catalyst materials. Recently we developed an in situ observation system in TEM for observing the oxidation and reduction under a gas atmosphere at high temperature. Using the new in situ observation system in TEM, the morphological changes of the nano particle and support were observed in the heated gaseous atmosphere at atomic level in real time.

NO2 sources of roadside atmosphere at Matsubarabashi monitoring station in Tokyo were investigated analytically. The result showed that contribution of urban background is dominant from November to February and NO oxidation with O3 has large contribution from April to September. NO2 air quality standard will be achieved by reducing vehicle NOx emission to post-new long-term regulation level. The analytical method was verified by using our developed simulation system, which consists of micro traffic flow analyzer and CFD-based, unsteady-state diffusion with chemical reaction solver.

Since 2000, an Aluminum Cosmetic Corrosion task group within the SAE Automotive Corrosion and Protection (ACAP) Committee has existed. The task group has pursued the goal of establishing a standard test method for in-laboratory cosmetic corrosion evaluations of finished aluminum auto body panels. A cooperative program uniting OEM, supplier, and consultants has been created and has been supported in part by USAMP (AMD 309) and the U.S. Department of Energy. Prior to this committee's formation, numerous laboratory corrosion test environments have been used to evaluate the performance of painted aluminum closure panels. However, correlations between these laboratory test results and in-service performance have not been established. Thus, the primary objective of this task group's project was to identify an accelerated laboratory test method that correlates well with in-service performance.

There is an increasing global realization about the need for fuel efficient vehicles. An inexpensive way to accomplish this is through mass reduction, and one of the most effective ways that this can occur is through substituting current materials with magnesium, the lightest structural metal. This document describes the results of a U.S. Automotive Materials Partnership (USAMP) sponsored study [1] that examines why magnesium use has only grown 10% per year and identifies how to promote more widespread commercial applications beyond the 5-6 kg of component currently in vehicles. The issues and concerns which have limited magnesium use are discussed via a series of research and development themes. These address concerns associated with corrosion, fastening, and minimal metalworking/non-traditional casting processing. The automotive and magnesium supplier industries have only a limited ability to develop implementation-ready magnesium components.

Trivalent chromate coating is replacing the conventional hexavalent chromate coating applied on zinc plating. Zinc plating uses one of three types of plating baths (zincate, cyanide and chloride) according to the characteristics required of subject parts. It has been recognized that trivalent chromate coating provides different corrosion resistance depending on the type of zinc plating bath used. Zinc plating with chromate coating were analyzed to clarify the cause of the corrosion resistance variation with the type of zinc plating bath. It has been revealed that the chromate coating thickness and the condition of top SiO2 layer vary with the type of zinc plating bath, resulting in corrosion resistance variation.

Durability requirements for exhaust materials have resulted in the increased use of stainless steels throughout the exhaust system. The conversion of carbon steel exhaust flanges to stainless steel has occurred on many vehicles. Ferritic stainless steels are commonly used for exhaust flanges. Flange construction methods include stamped sheet steel, thick plate flanges and powder metal designs. Flange material selection criteria may include strength, oxidation resistance, weldability and cold temperature impact resistance. Flange geometry considerations include desired stiffness criteria, flange rotation, gasket/sealing technique and vehicle packaging. Both the material selection and flange geometry are considered in terms of meeting the desired durability and cost. The cyclic oxidation performance of the material is a key consideration when selecting flange materials.

A co-operative program initiated by the Automotive Aluminum Alliance and supported by USAMP continues to pursue the goal of establishing an in-laboratory cosmetic corrosion test for finished aluminum auto body panels that provides a good correlation with in-service performance. The program is organized as a task group within the SAE Automotive Corrosion and Protection (ACAP) Committee. Initially a large reservoir of test materials was established to provide a well-defined and consistent specimen supply for comparing test results. A series of laboratory procedures have been conducted on triplicate samples at separate labs in order to evaluate the reproducibility of the various lab tests. Exposures at OEM test tracks have also been conducted and results of the proving ground tests have been compared to the results in the laboratory tests. Outdoor tests and on-vehicle tests are also in progress. An optical imaging technique is being utilized for evaluation of the corrosion.

In recent years, alternative sources of fuel are receiving a lot of attention in the automotive industry. Fuels derived from an agricultural feedstock are an attractive option. Bio-fuels based on vegetable oils offer the advantage being a sustainable, annually renewable source of automobile fuel. One of key issues in using vegetable oil based fuels is its oxidation stability. Since diesel fuels from fossil oil have good oxidation stability, automobile companies have not considered fuel degradation when developing diesel engines and vehicles as compared with gasoline engines. This paper presents the results of oxidation stability testing on bio-fuels. Oxidation stability was determined using three test methods, ASTM D525, EN14112 and ASTM D2274. The effects of storage condition, bio-fuel composition and antioxidants on the degradation of bio-fuels were all investigated. ASTM D525 is an effective test method to determine the effects of storage condition on bio-fuels stability.

Toyota Motor Corporation has been developing technologies for reductions on the environmental load. This paper reports the following as a part of technological development for the painting process. Prior to the application of the E-coat, vehicle bodies are pretreated with zinc phosphates. This is applied to ensure good adhesion and corrosion resistance of the E-coat film. To obtain an excellent pretreatment film, surface conditioning with titanium colloid is generally applied before pretreatment. Since colloid flocculation control was difficult in the case of a conventional titanium colloid-type surface conditioner, the surface conditioner had to be renewed at approximately two-month intervals. The liquid life, however, increased remarkably as a result of adopting fine zinc-type surface conditioners and adding an organic protective surface layer. The water supply/discharge amount was decreased significantly compared with previous amounts.

Phosphating is a surface treatment process widely used for preparing metal surfaces before painting. The phosphate coating plays a very important role in enhancing after-painting corrosion resistance, which is one of the essential quality requirements of painted surfaces. Continued research and development is therefore under way in various parts of the world to increase the corrosion resistance enhancement effect of phosphating. Moreover, because the demand for environmental protection has been increasing in recent years, reducing the amount of waste (sludge) generated during the phosphating process is also strongly required. To meet these requirements, we have developed a novel phosphating technology called the “electrolytic phosphating process,” which drastically enhances corrosion resistance after painting and reduces sludge generation. The developed process has already been put to practical use for surface preparation before cation electrodeposition painting of automotive parts.

The Automotive Aluminum Alliance in conjunction with SAE ACAP founded a corrosion task group in 2000 with a goal to establish an in-laboratory cosmetic corrosion test for finished aluminum auto body panels, which provides a good correlation with in-service performance. Development of this test involves a number of key steps that include: (1) Establishing a reservoir of standard test materials to provide a well-defined and consistent frame of reference for comparing test results; (2) Defining a real-world performance for the reference materials through on-vehicle tests conducted in the U.S. and Canada; (3) Evaluating existing laboratory, proving ground, and outdoor tests; (4) Conducting statistically designed experiments to evaluate the effects of cyclic-test variables; (5) Comparing corrosion mechanisms of laboratory and on-vehicle tests; and (6) Conducting a round robin test program to determine the precision of the new test. Several of these key steps have been accomplished.

Two types of new conceptual lead free overlays are developed for automotive internal combustion(IC) engine bearings. The overlays are consisted of molybdenum disulfide(MoS2) and polyamideimide(PAI) resin for binding. One of the overlays is suitable for diesel engines with higher unit load and the other overlay is suitable for gasoline engines with higher sliding velocity. Both overlays indicate good corrosion resistance and wear resistance comparing with conventional lead base overlay. Moreover, higher fatigue resistance is obtained in combination with high performance lead free bearing alloy. These new bearings have the potential to become alternative materials to conventional copper lead bearings with lead base overlay.

As automobile power needs increase 42-volt electrical systems are being proposed for use in consumer vehicles. One concern when using these new systems is the corrosion resistance of these components, especially in underhood environments. Corrosion is an electrochemical phenomenon and as such can be altered (increased or decreased) by the application of an external current or voltage. Although unintentional, the use of a higher voltage electrical system has the ability to increase corrosion through its normal use. This program evaluated the impact of corrosion on electrical components powered by 14 and 42-volt DC systems. Accelerated corrosion test findings suggested that 42-volt systems may be more susceptible to corrosion, but without proper environmental shielding both supply system can have unacceptable degradation.

The Corrosion Task Force of the Automotive/Steel Partnership has developed the SAE J2334 cyclic laboratory test for evaluating the cosmetic corrosion resistance of auto body steel sheet. [Ref. 1] Since the publishing of this test in 1997, further work has improved the precision of J2334. In this paper, the results of this work along with the revisions to the J2334 test will be discussed.

Among aluminum heat exchangers used for automotive air conditioning, the evaporator is located in the instrument panel. We have developed a new evaporator by: 1) improving the heat transfer performance through use of thinner tubes and fins; 2) establishing technologies for improving corrosion resistance and enabling reduction in wall thickness (development of highly corrosion-resistant material and control of Zn diffusion by shortening brazing time); and 3) improving refrigerant distribution in the tanks. The new evaporator is equivalent to our conventional MS Evaporator (of Multi-Tank Super-Slim Structure)(1) in cooling performance and corrosion resistance, while being significantly thinner (35% reduction) and lighter in weight (40% reduction).