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Technical Paper

Development of Low Pressure and High Performance GPF Catalyst

2018-04-03
2018-01-1261
Awareness of environmental protection with respect to the particulate number (PN) in the exhaust emissions of gasoline direct injection (GDI) engine vehicles has increased. In order to decrease the emission of particulate matter (PM), suppressing emissions by improving engine combustion, and/or filtering PM with a gasoline particulate filter (GPF) is effective. This paper describes the improvement of the coated GPF to reduce pressure drop while securing three-way performance and PN filtration efficiency. It was necessary to load a certain amount of washcoat on the GPF to add the three-way function, but this led to an increase in pressure drop that affected engine power. The pressure drop was influenced by the gas permeation properties of the filter wall.
Journal Article

Development of Prediction Method for Engine Compartment Water Level by Using Coupled Multibody and Fluid Dynamics

2017-03-28
2017-01-1328
When vehicles run on the flooded road, water enters to the engine compartment and sometimes reaches the position of the air intake duct and electrical parts and causes the reliability problems. Numerical simulation is an effective tool for this phenomenon because it can not only evaluate the water level before experiment but also identify the intrusion route. Recently, the gap around the engine cooling modules tends to become smaller and the undercover tends to become bigger than before in order to enhance the vehicle performance (e.g., aerodynamics, exterior noise). Leakage tightness around the engine compartment becomes higher and causes an increase of the buoyancy force from the water. Therefore the vehicle attitude change is causing a greater impact on the water level. This paper describes the development of a water level prediction method in engine compartment while running on the flooded road by using the coupled multibody and fluid dynamics.
Technical Paper

Development of CFD Method for Spray Shape Estimation

2016-10-17
2016-01-2198
Computational fluid dynamic (CFD) is widely used to develop engine combustion. Especially the in-cylinder spray calculation is important in order to resolve the issues of direct injection gasoline engines (e.g., particulate matter (PM) and oil dilution caused by fuel wetting on the cylinder walls). Conventional spray calculation methods require fitting based on measurements of spray characteristics such as penetration and droplet diameter (i.e., the Sauter mean diameter (SMD)). Particularly in the case of slit nozzle shapes that widen from the inlet to the outlet to form a fan-shaped spray, fitting the shape of spray is a complex procedure because the flow inside the nozzle is not uniform. In response, a new calculation method has been developed that eliminates the need for spray shape fitting by combining calculations of the Eulerian multiphase and the Lagrangian multiphase.
Journal Article

Typical Velocity Fields and Vortical Structures around a Formula One Car, based on Experimental Investigations using Particle Image Velocimetry

2016-04-05
2016-01-1611
This paper presents typical flow structures around a 60%-scale wind-tunnel model of a Formula One (F1) car, using planar particle image velocimetry (PIV). The customized PIV system is permanently installed in a wind tunnel to help aerodynamicists in the development loop. The PIV results enhance the understanding of the mean velocity field in the two-dimensional plane in some important areas of the car, such as the front-wheel wake and the underfloor flow. These real phenomena obtained in the wind tunnel also help maintain the accuracy of simulations using computational fluid dynamics (CFD) by allowing regular checking of the correlation with the real-world counterpart. This paper first surveys recent literature on unique flow structures around the rotating exposed wheel, mostly that on the isolated wheel, and then gives the background to F1 aerodynamics in the late 2000s.
Journal Article

Development of a Highly Anti-Corrosive Organic-Inorganic Hybrid Paint

2016-04-05
2016-01-0540
A highly anti-corrosive organic-inorganic hybrid paint for automotive steel parts has been developed. The inorganic component included in the paint is silicon dioxide (SiO2), which has the capability to passivate zinc. By application of the paint on a trivalent chromatetreated zinc-plated steel sheet or a trivalent chromate-treated zinc-nickel-plated steel sheet, high anti-corrosion protection can be provided to steel materials. Particularly in the case of application over a zinc-nickel-plated steel sheet, 0 mm corrosion depth after a cyclic corrosion test (CCT) of 450 cycles was demonstrated.
Journal Article

Analysis of Influence of Snow Melting Agents and Soil Components on Corrosion of Decorative Chrome Plating

2016-04-05
2016-01-0539
The dissolution and exfoliation of chromium plating specific to Russia was studied. Investigation and analysis of organic compounds in Russian soil revealed contents of highly concentrated fulvic acid. Additionally, it was found that fulvic acid, together with CaCl2 (a deicing agent), causes chromium plating corrosion. The fulvic acid generates a compound that prevents reformation of a passivation film and deteriorates the sacrificial corrosion effectiveness of nickel.
Technical Paper

Oxidation Stability of Diesel/Biodiesel Blends: Impact of Fuels Physical-Chemical Properties over Ageing During Storage and Accelerated Oxidation

2015-09-01
2015-01-1930
Current and future engine technologies and fuels are mutually dependent. The increased use of alternative fuels has been linked to deterioration in performance of injectors, fuel filters and engines as a result of insoluble deposit formation. The present work aimed to study the impact of Diesel/biodiesel blends formulation (biodiesel feedstock and content) and temperature on the oxidation stability based on total acid number (TAN). The biofuels used in the fuel matrix were: rapeseed, soy and palm methyl esters (RME, SME and PME respectively). The Diesel/biodiesel blends were made with 0%v/v, 5%v/v, 10% v/v and 20%v/v of biodiesel blended with additive-free new Diesel. The oxidation stability of Diesel/biodiesel blends was to evaluate during 6 months fuels storage, under 20°C and 40°C, and fuels severe oxidation into a reactor vessel to better understand the parameters leading to fuel oxidation on-board.
Journal Article

Reaction Mechanism Analysis of Di-Air-Contributions of Hydrocarbons and Intermediates

2012-09-10
2012-01-1744
The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.
Journal Article

Cooling Loss Reduction of Highly Dispersed Spray Combustion with Restricted In-Cylinder Swirl and Squish Flow in Diesel Engine

2012-04-16
2012-01-0689
In diesel engines with a straight intake port and a lipless cavity to restrict in-cylinder flow, an injector with numerous small-diameter orifices with a narrow angle can be used to create a highly homogeneous air-fuel mixture that, during PCCI combustion, dramatically reduces the NOX and soot without the addition of expensive new devices. To further improve this new combustion concept, this research focused on cooling losses, which are generally thought to account for 16 to 35% of the total energy of the fuel, and approaches to reducing fuel consumption were explored. First, to clarify the proportions of convective heat transfer and radiation in the cooling losses, a Rapid Compression Machine (RCM) was used to measure the local heat flux and radiation to the combustion chamber wall. The results showed that though larger amounts of injected fuel increased the proportion of heat losses from radiation, the primary factor in cooling losses is convective heat transfer.
Journal Article

Low Emissions and High-Efficiency Diesel Combustion Using Highly Dispersed Spray with Restricted In-Cylinder Swirl and Squish Flows

2011-04-12
2011-01-1393
A new clean diesel combustion concept has been proposed and its excellent performance with respect to gas emissions and fuel economy were demonstrated using a single cylinder diesel engine. It features the following three items: (1) low-penetrating and highly dispersed spray using a specially designed injector with very small and numerous orifices, (2) a lower compression ratio, and (3) drastically restricted in-cylinder flow by means of very low swirl ports and a lip-less shallow dish type piston cavity. Item (1) creates a more homogeneous air-fuel mixture with early fuel injection timings, while preventing wall wetting, i.e., impingement of the spray onto the wall. In other words, this spray is suitable for premixed charge compression ignition (PCCI) operation, and can decrease both nitrogen oxides (NOx) and soot considerably when the utilization range of PCCI is maximized.
Journal Article

Combustion Improvement of Diesel Engine by Alcohol Addition - Investigation of Port Injection Method and Blended Fuel Method

2011-04-12
2011-01-0336
Alcohol fuels that can be produced from cellulose continue to become more widely used in gasoline engines. This research investigated the application of alcohol to diesel engines with the aims of improving the combustion of diesel engines and of utilizing alternative fuels. Two methods were compared, a method in which alcohol is injected into the air intake system and a method in which alcohol is blended in advance into the diesel fuel. Alcohol is an oxygenated fuel and so the amount of soot that is emitted is small. Furthermore, blended fuels have characteristics that help promote mixture formation, which can be expected to reduce the amount of soot even more, such as a low cetane number, low viscosity, low surface tension, and a low boiling point. Ethanol has a strong moisture-absorption attribute and separates easily when mixed with diesel fuel. Therefore, 1-butanol was used since it possesses a strong hydrophobic attribute and does not separate easily.
Technical Paper

Three-Dimension Deposited Soot Distribution Measurement in Silicon Carbide Diesel Particulate Filters by Dynamic Neutron Radiography

2011-04-12
2011-01-0599
Exhaust emissions are well known to have adverse impacts on human health. Studies have demonstrated that there is an association between ambient particulate matter (PM) levels and various harmful cardiopulmonary conditions. Soot exhaust from diesel engines can be a significant contributor to airborne pollutants. A key component in PM level control for a diesel engine is a diesel particulate filter (DPF). This device traps soot while allowing other exhaust gases to pass unhindered. However, the performance of diesel particulate filters can change with increasing soot loadings and thus may require regeneration or replacement. Improved understanding of diesel particulate filters is dependent upon the knowledge of the actual soot loading and the soot distribution within the DPF. Neutron radiography (NR) has been identified as an effective means of non-destructively identifying hydrogen or carbon adsorbed in PM.
Journal Article

Influence of Bio Diesel Fuel on Engine Oil Performance

2010-05-05
2010-01-1543
To evaluate the influence of FAME, which has poor oxidation stability, on engine oil performance, an engine test was conducted under large volumes of fuel dilution by post-injection. The test showed that detergent consumption and polymerization of FAME were accelerated in engine oil, causing a severe deterioration in piston cleanliness and sludge protection performance of engine oil.
Technical Paper

Two-Dimensional Temperature Measurements in Diesel Piston Bowl Using Phosphor Thermometry

2009-09-13
2009-24-0033
Phosphor thermometry was used during fuel injection in an optical engine with the glass piston of reentrant type. SiO2 coated phosphor particle was used for the gas-phase temperature measurements, which gave much less background signal. The measurements were performed in motored mode, in combustion mode with injection of n-heptane and in non-combustion mode with injection of iso-octane. In the beginning of injection period, the mean temperature of each injection cases was lower than that of the motored case, and temperature of iso-octane injection cases was even lower than that of n-heptane injection cases. This indicates, even if vaporization effect seemed to be the same at both injection cases, the effect of temperature decrease changed due to the chemical reaction effect for the n-heptane cases. Chemical reaction seems to be initiated outside of the fuel liquid spray and the position was moving towards the fuel rich area as the time proceeds.
Technical Paper

Improvement of DI Diesel Engine System by Utilizing GTL Fuels Characteristics

2009-06-15
2009-01-1933
Gas To Liquid (GTL) fuels synthesized from natural gas are known as clean fuels. Therefore, GTL fuels have been expected to be a promising option that can reduce the NOx and PM emissions from diesel engines and contribute to the energy security. In this study, in order to clarify the emission reduction potentials, the improvement of DI diesel engine and aftertreatment systems were investigated by utilizing GTL fuels characteristics. To achieve a further reduction of both NOx and PM emissions, the combustion chamber, injection pattern and EGR calibration were modified. From the results of tests, the engine out NOx emissions were reduced to the Euro 6 regulation level and in parallel the expected deteriorations of HC emission and fuel consumption were suppressed because of the characteristics of high cetane number and zero poly-aromatics hydrocarbons. Additionally, an aftertreatment system was optimized to GTL fuel in order to improve NOx conversion efficiency.
Technical Paper

Analysis of Sophisticated DPNR Catalyst, Focused on PM Particle Number Emissions

2009-04-20
2009-01-0290
Diesel particulate and NOx reduction system (DPNR) is an effective technology for the diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. Further improvement of the DPNR is expected for cleaner air in the future. The catalyst for the DPNR (called DPNR catalyst) consists of a NOx Storage Reduction (NSR) catalyst coated onto a Diesel Particulate Filter (DPF). The development of the DPNR catalyst for the decrease of exhaust weight has been considered before now with respect to the PM combustion. But it will be necessary to focus on PM particle number emissions in the future. In this study, the relationship between the pore structure of the DPNR catalyst and the trapping of PM to lower particle number was clarified by evaluating a high-porosity, large-pore cordierite DPF with an average pore size of 20 μm or greater. Furthermore, the optimal pore structure to trap PM particles in a highly effective manner was discussed.
Technical Paper

In Situ Observation of Catalysis Reactions Using Transmission Electron Microscope

2008-04-14
2008-01-1266
Transmission electron microscope (TEM) is a powerful tool for studying catalyst materials at nano-size and/or atomic level. Conventional TEM usually needs to be observed at room temperature in high vacuum conditions. A gaseous atmosphere and high temperature condition may change the properties of catalyst materials. Recently we developed an in situ observation system in TEM for observing the oxidation and reduction under a gas atmosphere at high temperature. Using the new in situ observation system in TEM, the morphological changes of the nano particle and support were observed in the heated gaseous atmosphere at atomic level in real time.
Technical Paper

Development of Next-Generation NOx Reduction System for Diesel Exhaust Emission

2008-04-14
2008-01-0065
Diesel particulate and NOx reduction system (DPNR) is an effective technology for the diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. The DPNR has been developed under the Toyota D-CAT (Diesel Clean Advanced Technology) concept. Further improvement of the DPNR is hoped for cleaner air in the future. This paper reviews the results of our study to improve the NOx purification performance on the DPNR. The NOx reduction performance of the catalysts deteriorates due to thermal deterioration and sulfur poisoning. In order to improve the thermal resistance of the catalysts, the suppression of precious metal sintering in the catalyst has been studied. As a result, higher catalytic activity after aging especially under lower temperature conditions was obtained. On the other hands, improvement of desulfurization performance is one of the key technologies in order to keep the high NOx reduction capability of the catalyst.
Technical Paper

Analysis for Relationship between Vehicle NOx Emission and Roadside NO2 Concentration

2008-04-14
2008-01-0755
NO2 sources of roadside atmosphere at Matsubarabashi monitoring station in Tokyo were investigated analytically. The result showed that contribution of urban background is dominant from November to February and NO oxidation with O3 has large contribution from April to September. NO2 air quality standard will be achieved by reducing vehicle NOx emission to post-new long-term regulation level. The analytical method was verified by using our developed simulation system, which consists of micro traffic flow analyzer and CFD-based, unsteady-state diffusion with chemical reaction solver.
Technical Paper

Exhaust Gas Pressure Sensor

2008-04-14
2008-01-0907
As the whole world has been getting more concerned about the environmental protection, the emission regulations are getting stricter. The requirement to diesel engine is to develop the high-level engine management system to reduce both PM(Particulate Matter)and NOx. For PM reduction, post-treatment technology using a pressure sensor and a diesel particulate filter (hereinafter referred to as DPF) is necessary. This system burns out the clogged PM at the filter that the pressure sensor detects. The pressure sensor used in the DPF system has to be at an affordable price and to be reliable against corrosion, freezing, moisture and clogged soot in the harsh environment of exhaust gas with high humidity where highly-acid condensation water and the produced soot can intrude. This paper describes our newly developed pressure sensor that is suitable for the DPF system. The main features are as follows: a. Semiconductor type sensor with a simple structure and being less costly. b.
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