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The transport of fuel-borne additives into the engine oil is a critical factor for the efficacy with which the additive functionality can be imparted on the engine. This paper describes the combination of Laser Induced Fluorescence (LIF) and Liquid Chromatography (LC) to determine the real-time additive concentrations and transfer ratios in a spark-ignition, 2-liter GM LHU engine. The current research used a continuous sample circuit from the engine sump which passed through an integrating cavity flow cell to enhance the LIF signal. In the absence of a fluorescence signature of any of the native additive species, a suitable fluorescing dye was selected to simulate the additive. After establishing rigorous calibration curves, LC was employed as a referee method to do a direct comparison with the LIF determined dye concentrations.

In the early years of antifreeze/coolants (1920s & 30s) glycerin saw some usage, but because of higher cost and weaker freeze point depression, it was not competitive with ethylene glycol. Glycerin is a by-product of the manufacture of biodiesel (fatty acid methyl esters) made by reacting natural vegetable or animal fats with methanol. Biodiesel fuel is becoming increasingly important and is expected to gain a large market share in the next several years. Regular diesel fuels blended with 2%, 5%, and 20% biodiesel are now commercially available. The large amount of glycerin generated from high volume usage of biodiesel fuel has resulted in this chemical becoming cost competitive with the glycols currently used in engine coolants. For this reason, and lower toxicity comparable to that of propylene glycol, glycerin deserves to be reconsidered as a base for antifreeze/coolant.

A new multi-layer co-extruded in-color Ionomer film is developed to provide an alternative decoration process to replace paint on Dodge Neon Fascias. The Ionomer film provides a high-gloss “class-A” surface in both non-metallic and metallic colors that match the car body paint finish. Using the Ionomer film to decorate fascias reduces cost; eliminates VOCs; increases manufacturing flexibility and improves performance (weatherability and durability). The molding process consists of thermoforming a film blank and injection molding Polypropylene or TPO behind the film. The paper will include the background, the benefits, the technology development objectives, the film materials development, tooling optimization, film fascia processing (co-extrusion; thermoforming and injection molding) and validation testing of the film.

This oil category was driven by two new cooled exhaust gas recirculation (EGR) engine tests operating with 15% EGR, with used oil soot levels at the end of the test ranging from 6 to 9%. These tests are the Mack T-10 and Cummins M11 EGR, which address ring, cylinder liner, bearing, and valve train wear; filter plugging, and sludge. In addition to these two new EGR tests, there is a Caterpillar single-cylinder test without EGR which measures piston deposits and oil consumption control using an articulated piston. This test is called the Caterpillar 1R and is included in the existing Global DHD-1 specification. In total, the API CI-4 category includes eight fired-engine tests and seven bench tests covering all the engine oil parameters. The new bench tests include a seal compatibility test for fresh oils and a low temperature pumpability test for used oils containing 5% soot. This paper provides a review of the all the tests, matrix results, and limits for this new oil category.

This paper presents the findings of some fundamental characterisation of the deposits that form on the injectors of an air-assisted DISI automotive engine, including the effect of these deposits on engine performance when operated in different combustion modes, with varying fuel composition and additive content. A root cause analysis was undertaken, including an assessment of injector temperature and deposit chemistry. Fuels from a matrix designed around the European year 2000 gasoline specifications for T90, olefin and aromatic levels were used to study the effect of fuel composition on deposit formation. Two commercial gasoline detergent additives, of different chemistries, were used to investigate the impact on deposit formation. The results of the fuels study and deposit analysis are consistent with published theories concerning fuel composition impact on combustion chamber deposit (CCD).