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Lignocellulosic biomass consists of (hemi-) cellulose and lignin. Accordingly, an integrated biorefinery will seek to valorize both streams into higher value fuels and chemicals. To this end, this study evaluated the overall combustion performance of both cellulose- and lignin derivatives, namely the high cetane number (CN) di-n-butyl ether (DnBE) and low CN anisole, respectively. Said compounds were blended both separately and together with EN590 diesel. Experiments were conducted in a single cylinder compression ignition engine, which has been optimized for improved combustion characteristics with respect to low emission levels and at the same time high fuel efficiency. The selected operating conditions have been adopted from previous “Tailor-Made Fuels from Biomass (TMFB)” work.

The current direction for Diesel combustion system development is towards homogenization, in order to reduce particulate and NOx emissions. However, a strong increase of carbon monoxide emissions (CO) is frequently noted in combination with enhanced homogenization. Therefore, the current investigation focuses on a detailed analysis of the particulate - CO trade-off using a laser-optical and multidimensional CFD investigation of the combustion process of a swirl HSDI system. The CFD methodology involves reduced kinetics for soot formation and oxidation and a three-step CO model. These models are validated by a detailed comparison to optical measurements of flow, spray penetration and the spatial distribution of soot, temperature and oxygen concentration. The results obtained show that high concentrations of CO occur as an intermediate combustion reaction product. Subsequently, CO and soot are oxidized in large areas of the combustion chamber.

Dielectric barrier discharge (DBD) offers the advantage to excite and dissociate molecules in the exhaust gas stream. Those dissociated and excited species are oxidizing or reducing harmful exhaust gas components. The advantage of a plasma chemical system in comparison to a catalytic measure for exhaust gas treatment is the instantaneous activity at ambient temperature from the starting of the engine. The investigations reviewed in this paper are dealing with the plasma chemical oxidation of hydrocarbons in the exhaust gas stream during cold start conditions. The article concerns the design and development of a plasma-system in order to decrease the hydrocarbon emissions from engine start till catalyst light off. Vehicle results in the New European Driving Cycle show a hydrocarbon conversion of more than 42% in the first 11 seconds from engine start. In this period nearly all types of hydrocarbon were reduced.