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Technical Paper

A systematic review on smart coatings for automotive applications

2024-01-08
2023-36-0126
Corrosion affects all industrial sectors where metals or metal alloys are used in their structures. In the automotive industry, the continuous search for lightweight parts has increased the demand for effective corrosion protection, in order to improve vehicle performance without compromising durability and safety. In this scenario, coatings are essential elements to preserve and protect vehicle parts from various environmental aggressions. Automotive coatings can be classified into primers, topcoats, clearcoats, and specialty coatings. Primers provide corrosion resistance and promote adhesion between the substrate and topcoat. Topcoats provide color, gloss, and durability to the coating system, while clearcoats enhance the appearance and durability of the finish. Specialty coatings provide additional properties, such as scratch resistance, chemical resistance, and UV protection.
Technical Paper

Potential Application of Rubber-Graphene Compounds in the Automotive Parts

2024-01-08
2023-36-0028
Rubber is one of the most used materials currently selected to produce automotive parts, but, for specific applications, some improvement is required in its properties through the addition of some components to the rubber compound formulation. Because of that, mechanical, thermal, and chemical properties are enhanced in order to meet strict requirements of the vast range of application of the rubber compounds. In addition to improving material properties, the combination of different substances, also aims to improve processability and reduce the costs of the final product. Recently, the use of nanofillers has been very explored because of their distinctive properties and characteristics. Among the nanofillers under study, graphene is known for its high-barrier property, thermal and electrical conductivities, and good mechanical properties.
Journal Article

Graphene Coating as a Corrosion Protection Barrier for Metallic Terminals in Automotive Environments

2021-04-06
2021-01-0354
Inside an automobile, hundreds of connectors and electrical terminals in various locations experience different corrosive environments. These connectors and electrical terminals need to be corrosion-proof and provide a good electrical contact for a vehicle’s lifetime. Saltwater and sulfuric acid are some of the main corrosion concerns for these electrical terminals. Currently, various thin metallic layers such as gold (Au), silver (Ag), or tin (Sn) are plated with a nickel (Ni) layer on copper alloy (Cu) terminals to ensure reliable electrical conduction during service. Graphene due to its excellent chemical stability can serve as a corrosion protective layer and prevent electrochemical oxidation of metallic terminals. In this work, effects of thin graphene layers grown by plasma-enhanced chemical vapor deposition (PECVD) on Au and Ag terminals and thin-film devices were investigated. Various mechanical, thermal/humidity, and electrical tests were performed.
Technical Paper

Detection of Presence and Posture of Vehicle Occupants Using a Capacitance Sensing Mat

2019-04-02
2019-01-1232
Capacitance sensing is the technology that detects the presence of nearby objects by measuring the change in capacitance. A change in capacitance is triggered either by a change in dielectric constant, area of overlap or distance of separation between the electrodes of the capacitor. It is a technology that finds wide use in applications such as touch screens, proximity sensing etc. Drawing motivation from such applications, this paper investigates how capacitive sensing can be employed to detect the presence and posture of occupants inside vehicles. Compared to existing solutions, the proposed approach is low-cost, easy to deploy and highly efficient. The sensing system consists of a capacitance-sensing mat that is embedded with copper foils and an associated sensing circuitry. Inside the mat the foils are arranged in rows and columns to form several touch-nodes across the surface of the mat.
Technical Paper

Coating on striker: Robust corrosion protection with low cost

2018-09-03
2018-36-0044
Corrosion is a known phenomenon that the automotive industry needs to pay attention, once that several issues faced in the field had it as root cause. Indisputably is important spend resources in usage of proper materials and process based on chemical properties, minimum thickness, adhesion conditions, wear resistance, finish applicators, etc. to cover the parts in order to ensure robust protection against this phenomena; however, the key point is to optimize these resources once that the customer will buy/use the vehicle (not the part singly); so if develop a proper design in system level providing proper protection of the parts, despite of the part does not have the most efficient protection level, the customers will have a satisfactory experience during vehicle usage.
Technical Paper

Copper Effect on the Ultrasonic Fatigue Life of A356 Aluminum Alloy Under Variable Humidity Levels

2018-04-03
2018-01-1411
Ultrasonic fatigue tests (testing frequency around 20kHz) have been conducted on A356 aluminum alloys with different copper contents and AS7GU aluminum alloy. Tests were performed in dry air and submerged in water conditions. The effect of copper content was investigated and it was concluded that copper content plays an important role influencing the humidity effect on A356 aluminum alloy ultrasonic fatigue lives. Also, for the same copper content, copper in solute solution or in precipitate have different humidity sensitivities.
Technical Paper

Development of a Computationally Efficient Progress Variable Approach for a Direct Injection Stochastic Reactor Model

2017-03-28
2017-01-0512
A novel 0-D Probability Density Function (PDF) based approach for the modelling of Diesel combustion using tabulated chemistry is presented. The Direct Injection Stochastic Reactor Model (DI-SRM) by Pasternak et al. has been extended with a progress variable based framework allowing the use of a pre-calculated auto-ignition table. Auto-ignition is tabulated through adiabatic constant pressure reactor calculations. The tabulated chemistry based implementation has been assessed against the previously presented DI-SRM version by Pasternak et al. where chemical reactions are solved online. The chemical mechanism used in this work for both, online chemistry run and table generation, is an extended version of the scheme presented by Nawdial et al. The main fuel species are n-decane, α-methylnaphthalene and methyl-decanoate giving a size of 463 species and 7600 reactions.
Technical Paper

Improving Multi-Voltage Electrical System Performance with Smart Step-Down Converters

2017-03-28
2017-01-1668
The demand for more features in a vehicle is growing at an extraordinary rate. This trend especially with emerging autonomous functions shows no sign of slowing. The energy requires to supply this ever growing system goes through multiple conversion, protection and other elements before it actually powers the loads. Considering the loss of each of these elements for a vehicle and multiplying the value by the total numbers of cars, underlines the need for an optimized electrical distribution system to power all loads efficiently. In this paper, Smart Step-Down Convertor is introduced as a power supply to power devices which operate at voltages below the power net voltage while protecting the power net and the devices against faults.
Journal Article

Ultra-Trace Real Time VOC Measurements by SIFT-MS for VIAQ

2017-03-28
2017-01-0989
Vehicle interior air quality (VIAQ) measurements are currently conducted using the offline techniques GC/MS and HPLC. To improve throughput, speed of analysis, and enable online measurement, specialized instruments are being developed. These instruments promise to reduce testing cost and provide shortened analysis times at comparable accuracy to the current state of the art offline instruments and methods. This work compares GCMS/HPLC to the Voice200ultra, a specialized real-time instrument utilizing the technique selected ion flow tube mass spectrometry (SIFT-MS). The Voice200ultra is a real-time mass spectrometer that measures volatile organic compounds (VOCs) in air down to the parts-per-trillion level by volume (pptv). It provides instantaneous, quantifiable results with high selectivity and sensitivity using soft chemical ionization.
Technical Paper

Numerical Analysis of Thermal Growth of Cast Aluminum Engine Components

2008-04-14
2008-01-1419
As-cast or as-solution treated cast aluminum A319 has copper solutions within its aluminum dendrite. These copper solutions precipitate out to form Al2Cu through a sequence of phase changes and bring with them volume changes at elevated temperatures. These volume changes, referred to as thermal growth are irreversible. The magnitude of thermal growth at a material point is decided by the temperature history of the material point. When an under aged or non heat treated cast aluminum is exposed to non-uniform temperature such as that during engine operation, thermal growth leads to non-uniform volume change and thus additional self balanced stresses. These stresses remain inside material as residual stresses even when the temperature of the material is uniform again. In the present paper, numerical analysis method for thermal growth is developed and integrated into engine operation analysis.
Technical Paper

Method Development for Evaluating Microbiological Growth on and Attachment to Aluminum Air Conditioner Evaporator Core Surfaces

2006-04-03
2006-01-1645
Corrosion failures of aluminum air conditioner evaporator cores have been reported in regions where the climate is relatively warm and humid. Microbiologically-influenced corrosion [MIC] has been implicated in these failures. Application of surface-treatment chemicals may inhibit microbiological (bacterial) growth and/or attachment, thereby reducing the potential for MIC. In this study, two laboratory methods were developed to evaluate selected surface-treatment chemicals for their ability to inhibit bacterial growth and reduce bacterial attachment to treated surfaces. Using the developed methods, two controlled-atmosphere brazed aluminum core materials and three surface-treatment chemicals were evaluated. Neither of the untreated core materials was found to inhibit the growth of the bacteria tested.
Technical Paper

Oxidation and Antiwear Retention Capability of Low-Phosphorus Engine oils

2005-10-24
2005-01-3822
Future vehicle emission regulations both in the US and Europe will require maintaining catalyst efficiency for longer mileage intervals. In order to achieve this requirement, chemical restrictions are being placed on elements in engine oil that can poison catalysts. Most of phosphorus and a significant amount of sulfur in current engine oils come from zinc dialkyldithiophosphates, ZDDPs, which are a class of cost-effective multifunctional additives providing wear, oxidation and corrosion protection. Reducing ZDDP concentrations raises oxidation and wear concerns. The overall purpose of this research is to look at the antioxidation and antiwear capability of low phosphorus engine oils containing 0.05 wt% phosphorus and the potential of engine oils formulated without phosphorus. In addition to fresh oils, used oils drained from fleet vehicles were also analyzed and evaluated.
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