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Natural gas (NG) is attractive for heavy-duty (HD) engines for reasons of cost stability, emissions, and fuel security. NG cannot be reliably compression-ignited, but conventional gasoline ignition systems are not optimized for NG and are challenged to ignite mixtures that are lean or diluted with exhaust-gas recirculation (EGR). NG ignition is particularly challenging in large-bore engines, where completing combustion in the available time is more difficult. Using two high-speed infrared (IR) cameras with borescopic access to one cylinder of an HD NG engine, the effect of ignition system on the early flame-kernel development and cycle-to-cycle variability (CCV) was investigated. Imaging in the IR yielded strong signals from water emission lines, which located the flame front and burned-gas regions and obviated image intensifiers. A 9.7-liter, six-cylinder engine was modified to enable exhaust-gas recirculation and to provide optical access.

Greenhouse gas (GHG) emission targets are becoming more stringent for both automakers and electricity generators. With the introduction of plug-in hybrid and electric vehicles, transportation and electricity generation sectors become connected. This provides an opportunity for both sectors to work together to achieve the cost efficient reduction of CO2 emission. In addition, the abundant natural gas (NG) in USA is drawing increased attention from both policy makers and various industries due to its low cost and low carbon content. NG has the potential to ease the pressure from CO2 emission constraints for both the light duty vehicle (LDV) and the electricity generation sectors while simultaneously reducing their fuel costs. To quantify the benefit of this collaboration, an analytical model is developed to evaluate the total societal cost and CO2 emission for both sectors.

In this study, the performance and emissions of a 4 cylinder 2.5L light-duty diesel engine with methane fumigation in the intake air manifold is studied to simulate a dual fuel conversion kit. Because the engine control unit is optimized to work with only the diesel injection into the cylinder, the addition of methane to the intake disrupts this optimization. The energy from the diesel fuel is replaced with that from the methane by holding the engine load and speed constant as methane is added to the intake air. The pilot injection is fixed and the main injection is varied in increments over 12 crank angle degrees at these conditions to determine the timing that reduces each of the emissions while maintaining combustion performance as measured by the brake thermal efficiency. It is shown that with higher substitution the unburned hydrocarbon (UHC) emissions can increase by up to twenty times. The NOx emissions decrease for all engine conditions, up to 53%.

A study was conducted to investigate combustion variability and exhaust emissions from high-speed, natural gas fueled engines. Two types of fuel systems were used in the investigation: a mixer and a port fuel injection. The overall engine performances were not much different at stoichiometric fuel-air ratio. But as the equivalence ratio was reduced the engine with the mixer produced higher levels of hydrocarbons and larger coefficient of variations in imep. The same engine exhibited longer flame development angle and rapid burn duration in comparison to the fuel injected engine. The differences in burn durations increased as the equivalence ratio decreased and the mixer system produced larger variations in their values at these operating points. The investigation showed the performance of the engine was better with natural gas injection system than with the mixer, particularly at lean equivalence ratios.

Natural gas quality, in terms of the volume fraction of higher hydrocarbons, strongly affects the auto-ignition characteristics of the air-fuel mixture, the engine performance and its controllability. The influence of natural gas composition on engine operation has been investigated both experimentally and through chemical kinetic based cycle simulation. A range of two component gas mixtures has been tested with methane as the base fuel. The equivalence ratio (0.3), the compression ratio (19.8), and the engine speed (1000 rpm) were held constant in order to isolate the impact of fuel autoignition chemistry. For each fuel mixture, the start of combustion was phased near top dead center (TDC) and then the inlet mixture temperature was reduced. These experimental results have been utilized as a source of data for the validation of a chemical kinetic based full-cycle simulation.

A detailed chemical kinetic mechanism, consisting of 22 species and 104 elementary reactions, has been used in conjunction with the multi-dimensional reactive flow code KIVA-3 to study autoignition of natural gas injected under compression ignition conditions. Calculations for three different blends of natural gas are performed on a three-dimensional computational grid by modeling both the injection and ignition processes. Ignition delay predictions at pressures and temperatures typical of top-dead-center conditions in compression ignition engines compare well with the measurements of Naber et al. [1] in a combustion bomb. Two different criteria, based on pressure rise and mass of fuel burned, are used to detect the onset of ignition. Parametric studies are conducted to show the effect of additives like ethane and hydrogen peroxide in increasing the fuel consumption rate.

The effect of natural gas composition on ignition delay has been investigated numerically by using detailed and reduced chemical kinetic mechanisms. Three different blends of natural gas have been analyzed at pressures and temperatures that are typical of top dead center conditions in compression ignition engines. The predicted ignition delay shows a decrease with temperature in an Arrhenius manner and has a first order dependence on pressure. Similar trends have been observed by Naber et al. [1] in their experimental study of natural gas autoignition in a bomb. It is shown that two kinetic mechanisms (GRI-Mech 1.2 and reduced set DRM22) are best capable of predicting the ignition delay of natural gas under compression ignition conditions. The DRM22 mechanism has been chosen for further studies as t involves lower computational costs compared to the full GRI-Mech 1.2 mechanism.

An experimental study was undertaken to study exhaust emission from a lean-burn natural gas spark ignition engine. The possibility that such an engine may help to reduce exhaust emissions substantially by taking advantage of natural gas fuel properties, such as its antiknock properties and extended lean flammability limit compared to gasoline, was the main motivation behind the investigation. A four cylinder, automotive type spark ignition engine was used in the investigation. The engine was converted to operate on natural gas by replacing its fuel system with a gaseous carburetion system. A 3-way metal metrix catalytic converter was used in the engine exhaust system to reduce emission levels. The engine operated satisfactorily at an equivalence ratio as lean as 0.6, at all speeds and loads. As a result NOx emissions were significantly reduced. However, hydrocarbon emissions were high, particularly at very lean conditions and light loads.

An experimental study was undertaken to investigate emissions of hydrocarbons, oxides of nitrogen, carbon monoxide, and methane hydrocarbons emitted by natural gas fueled engines and the extent of their conversion in catalysts. Two engines were used in the study: a four cylinder, 1.6 liter, spark ignition engine and a modified version of the same engine with only one of the cylinders operating at 0.4 liter capacity. Two-way and three-way catalysts were used to treat exhaust gases leaving the engine. Natural gas was supplied through gas carburetors operated at regulated pressures and supplying air-fuel ratios in the desired range. The results of the investigation showed that oxides of nitrogen could not be reduced in a three-way catalyst to the levels found in gasoline fueled engines when the operating air-fuel ratio was stoichiometric.