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Technical Paper

Elucidation of the Sulfide Corrosion Mechanism in Piston Pin Bushings

2020-04-14
2020-01-1079
Recent trends to downsize engines have resulted in lighter weight and greater compactness. At the same time, however, power density has increased due to the addition of turbocharger and other such means to supplement engine power and torque, and this has increased the thermal and mechanical load. In this kind of environment, corrosion of the copper alloy bushing (piston pin bushing) that is press-fitted in the small end of the connecting rod becomes an issue. The material used in automobile bearings, of which the bushing is a typical example, is known to undergo sulfidation corrosion through reaction with an extreme-pressure additive Zinc Dialkyldithiophosphate (ZnDTP) in the lubricating oil. However, that reaction path has not been clarified. The purpose of the present research, therefore, is to clarify the reaction path of ZnDTP and copper in an actual engine environment.
Technical Paper

Residual Stress Analysis for Additive Manufactured Large Automobile Parts by Using Neutron and Simulation

2020-04-14
2020-01-1071
Metal additive manufacturing has high potential to produce automobile parts, due to its shape flexibility and unique material properties. On the other hand, residual stress which is generated by rapid solidification causes deformation, cracks and failure under building process. To avoid these problems, understanding of internal residual stress distribution is necessary. However, from the view point of measureable area, conventional residual stress measurement methods such as strain gages and X-ray diffractometers, is limited to only the surface layer of the parts. Therefore, neutron which has a high penetration capability was chosen as a probe to measure internal residual stress in this research. By using time of flight neutron diffraction facility VULCAN at Oak Ridge National Laboratory, residual stress for mono-cylinder head, which were made of aluminum alloy, was measured non-distractively. From the result of precise measurement, interior stress distribution was visualized.
Technical Paper

Temperature Prediction of Actual Contact Portion of the Metal Belt CVT

2018-04-03
2018-01-0122
In a previous study by the authors, austenite (γ phase) formed on the topmost of pulleys after long term operation of continuously variable transmission (CVT) [1]. In general, martensite arising from heat treatment forms on the surface of pulleys and gears. Therefore, the sliding surface has a body-centered cubic (BCC) metal structure, and transformation into and existence of austenite (γ phase) is difficult unless there is a thermal history exceeding the eutectoid point. For the verification of that possibility, it was crucial to obtain temperature variation on the sliding surface. The major problem for such measurements was rotation of parts inside an operating CVT. In this study, uniquely developed measurement system enabled non-contact temperature measurement near the contact portion. Results were substituted to heat conduction equation to predict the temperature at the exact contact portion.
Technical Paper

Atomization in High-Pressure Die Casting - Step 2 Simulation of Atomized Flow of Molten Aluminum by LES-VOF Method

2018-04-03
2018-01-1393
The atomization of molten aluminum when injected during high-pressure die casting is analyzed to determine its effect in enhancing the strength of the product being cast. In the previously reported first step of this study, molten aluminum was injected into open space and its atomization was observed photographically. Now in the second step of the study, a simulation is conducted to determine how the molten aluminum becomes atomized at the injection nozzle (gate) and how this atomized material flows and fills the cavity. A new simulation method is developed based on large-eddy simulation coupled with the volume-of-fluid method. The simulation system is verified by comparing its output with photographs taken in the first step of the study. Simulations are then conducted using an approximation of a real cavity to visualize how it is filled by the atomized molten aluminum.
Journal Article

Application of Rapid Heat and Cool Molding to High Strength Outer Parts without Painting Treatment

2016-11-08
2016-32-0024
Glass fiber reinforced plastic of polyamide is applied as one of the materials used for the high strength exterior parts of a motorcycle, such as a rear grab rail or a carrier, to which both strength and good exterior appearance are required. However, Glass Fiber reinforced Polypropylene (PPGF), which is relatively inexpensive material, has a property that the contained glass fibers are prone to be exposed at the surface and, therefore, the requirements for good appearance are hardly met by using PPGF. In this study, Heat and Cool molding method (H&C molding) was employed to realize a cost reduction by using PPGF yet without applying painting process, and the established method was applied to mass production while fulfilling the requirements for a good exterior appearance. In H&C molding, the metal molds are heated up by steam and cooled down by water after molding.
Journal Article

Development of Heat Resistant Titanium Alloy for Exhaust Valves Applicable for Motorcycles

2016-11-08
2016-32-0023
Amidst of the recent concerns on depletion of natural resources, a new heat resistant titanium alloy has been developed using the minimum amount of rare metals. Using Ti-811 as a basis and modifying the alloy composition to Ti-7Al-2Mo-0.2Si-0.15C-0.2Nb, the mechanical property, the creep resistance and the oxidation resistance at high temperatures are improved. At the same time, with the β transformation point shifted to a higher temperature, the hot formability is also improved. The newly developed alloy has made it possible to expand the application of titanium material to exhaust valves in reciprocating engines.
Technical Paper

Development of Aluminium Hollow Subframe Using High-Pressure Die Casting

2016-04-05
2016-01-0406
High-tensile steel plates and lightweight aluminum are being employed as materials in order to achieve weight savings in automotive subframe. Closed-section structures are also in general use today in order to efficiently increase parts stiffness in comparison to open sections. Aluminum hollow-cast subframe have also been brought into practical use. Hollow-cast subframe are manufactured using sand cores in gravity die casting (GDC) or low-pressure die casting (LPDC) processes. Using these manufacturing methods, it is difficult to reduce product thickness, and the limitations of the methods therefore make the achievement of weight reductions a challenge. The research discussed in this paper developed a lightweight, hollow subframe technology employing high-pressure die casting (HPDC), a method well-suited to reducing wall thickness, as the manufacturing method. Hollow-casting using HPDC was developed as a method of forming water jackets for water-cooled automotive engines.
Journal Article

Development of γ′-Fe4N Phase Control Technology and Low-Carbon Alloy Steel for High-Strength Nitrided Gear

2015-04-14
2015-01-0519
A new nitriding technology and material technology have been developed to increase the strength of microalloyed gears. The developed nitriding technology makes it possible to freely select the phase composition of the nitride compound layer by controlling the treatment atmosphere. The treatment environment is controlled to exclude sources of supply of [C], and H2 is applied as the carrier gas. This has made it possible to control the forward reaction that decomposes NH3, helping to enable the stable precipitation of γ′-phase, which offers excellent peeling resistance. A material optimized for the new nitriding technology was also developed. The new material is a low-carbon alloy steel that makes it possible to minimize the difference in hardness between the compound layer and the substrate directly below it, and is resistant to decline in internal hardness due to aging precipitation in the temperature range used in the nitriding treatment.
Journal Article

Effect of Surface Heat Treatment on Corrosion-Related Failure of the Suspension Spring

2015-04-14
2015-01-0518
In this research, a new wire material made using surface-reforming heat treatment was developed in order to enhance the corrosion fatigue resistance of suspension springs. The aim of surface reforming is to improve hydrogen embrittlement characteristics through grain refinement and to improve crack propagation resistance by partial softening of hardness. The grain refinement method used an α'→γ reversed transformation by rapid short-term heating in repeated induction heating and quenching (R-IHQ) to refine the crystal grain size of SAE 9254 steel spring wire to 4 μm or less. In order to simultaneously improve the fatigue crack propagation characteristics, the possibility of reducing the hardness immediately below the spring surface layer was also examined. By applying contour hardening in the second IHQ cycle, a heat affected zone (HAZ) is obtained immediately below the surface.
Technical Paper

The Structure of an Advanced Independent Rear Toe-Control System

2015-04-14
2015-01-1499
Honda announced an independent right and left rear toe control system (first generation) in 2013 and presented it as the world's first. As stated in a previous paper, “Independent Left and Right Rear Toe Control System,” with this system Honda has achieved a balance between an enjoyable driving experience in which handling is performed at the driver's will (“INOMAMA” handling) and stable driving performance.(1) This first generation is optimally designed to the vehicle specifications such as suspension axial force and steering gear ratio of the vehicle to which the system is applied. For more widespread application of independent rear toe control technology, a next generation system (second generation) has been developed, which achieves both cost reduction and flexible system performance which can be adapted to a variety of vehicles. The system development began by setting the required target performance with consideration for adaptation to various car models.
Technical Paper

Development of Pd-Only Catalyst for LEV III and SULEV30

2015-04-14
2015-01-1003
This research is aimed at development of the catalyst for gasoline automobiles which uses only palladium (Pd) among platinum group metals (PGMs). And the conformity emission category aimed at LEV III-SULEV30. For evaluation, the improvement effect was verified for 2013 model year (MY) ACCORD (LEV II-SULEV) as the reference. As compared with Pd-rhodium (Rh) catalyst, a Pd-only catalyst had the low purification performance of nitrogen oxides (NOx), and there was a problem in the drop in dispersion of Pd by sintering, and phosphorus (P) poisoning.
Journal Article

Manufacturing Technology for Hollow Structure Large Aluminum Parts Production by High Pressure Die Casting (HPDC)

2015-04-14
2015-01-1319
When using aluminum for vehicle body parts to reduce weight, the high pressure die casting (HPDC) is widely applied due to its adaptability to thin-wall products, near-net-shape castability, and short casting cycle time. Since a hollow construction is advantageous to increase stiffness of body parts, there has been a need of development of techniques for casting of hollow parts by HPDC. So far, hollow casting by HPDC has been realized for small parts using sand cores. When applying that method to large parts, however, it is necessary to increase filling speed. When the filling speed is increased, the core tends to break. In this project, we have developed a method to estimate changes of pressure distribution when filling molten metal by the casting simulation in order to analyze damages to the core. Through the analysis, we discovered occurrence of impulsive pressure waves.
Technical Paper

Development of Aluminum Powder Metal Composite Material Suitable for Extrusion Process used for Cylinder Sleeves of Internal Combustion Engines

2014-04-01
2014-01-1002
There are a couple of ways to manufacture aluminum cylinder blocks that have a good balance between productivity and abrasion resistance. One of them is the insert-molding of a sleeve made of PMC (Powder Metal Composite) by the HPDC (High Pressure Die Casting) method. However, in this method, cracks are apt to occur on the surface when the PMC sleeve is extruded and that has been a restriction factor against higher extrusion speed. The authors attempted to raise this extrusion temperature by eliminating the Cu additive process from the aluminum alloy powder in order to raise its melting point by approximately 50 °C. This enabled the wall of the extruded sleeve to be thinner and the extrusion speed to be higher compared to those of a conventional production method while avoiding the occurrence of surface cracks.
Technical Paper

Development of Torque Sensor with Nickel-Iron Alloy Plating for Pedal-Equipped Electric Vehicles

2013-10-15
2013-32-9045
This paper describes the development of non-contacting detection type torque sensor that realizes a small lost motion with light weight and low cost. Pedal-equipped electric vehicles are becoming popular in recent years. In those vehicles, torque sensors are usually necessary for measuring the pedaling force to determine the motor torque. We applied an integrated sensing structure and a non-contacting scheme utilizing inverse-magnetostrictive material to minimize the lost motions. As for the sensing material, nickel-iron alloy plating was used to obtain a wide dynamic range. In the tests using the actual structure, the output linearity deterioration occurred because of the strain distribution dispersion produced by the ratchet drive structure. Therefore, the effect of this strain distribution was examined. The inverse-magnetostrictive sensing material of nickel-iron alloy plating has an extremum on its output curve.
Technical Paper

Development of HPDC Alloy for Motorcycle Wheel Using Recycle Aluminum

2013-10-15
2013-32-9111
The new die cast (HPDC) wheel alloy has been developed using recycled aluminum to attain considerable reduction of energy at the time of material production to make large contribution to the reduction of CO2 emissions. The material for motorcycle body parts, especially for wheels, requires a sufficient elongation property. However, when recycled aluminum, which contains large amount of impurities, is used as main raw material, the intermetallic compounds crystalize out and the elongation property is deteriorated. Accordingly, we firstly made the investigations on the elements contained in a recycled aluminum and it was clarified that the elongation property was correlated to the shape of crystallized iron-based intermetallic compounds.
Journal Article

Development of Rare Earth-saving Magnet Using Localized Diffusion Method

2013-04-08
2013-01-1757
Nd₂Fe₁₄B sintered magnets are used in the drive motors of hybrid, electric and other vehicles. A magnet in which rare earth content is reduced by means of a localized diffusion method has been developed in order to reduce the volume of dysprosium. The distribution of the demagnetization fields in a motor is not uniform, so the necessary coercivity distribution for the magnets was quantified using Computer-Aided Engineering (CAE). Then material specifications of the localized dysprosium diffusion satisfied with this coercivity distribution was determined, and optimal manufacturing conditions including the position of dysprosium diffusion were set. The coercivity distribution in every position of the magnet using localized diffusion method was inspected. As a result, the magnet was satisfied with coercivity distribution demanded by CAE.
Technical Paper

Structure to Assist in the Prevention of Bimetallic Corrosion of Hybrid Doors

2013-04-08
2013-01-0386
The use of low-density materials in body panels is increasing as a measure to reduce the weight of the vehicle body. Honda has developed an aluminum/steel sheet hybrid door that is more effective in reducing weight than an all-aluminum door. Because aluminum was used in the door skin, bimetallic corrosion at the connection between the aluminum and the steel sheets represented an issue. It was possible that the difference in the electrical potential of the two metals might promote corrosion at the connection between the aluminum door skin and the steel sheet door panel, in particular at the lower edge of the door, where rainwater and other moisture tend to accumulate, with the result that the appeal of the exterior of the door might decline.
Video

A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-06-18
Currently, two consolidated aftertreatment technologies are available for the reduction of NOx emissions from diesel engines: Urea SCR (Selective Catalytic Reduction) systems and LNT (Lean NOx Trap) systems. Urea SCR technology, which has been widely used for many years at stationary sources, is becoming nowadays an attractive alternative also for light-duty diesel applications. However, SCR systems are much more effective in NOx reduction efficiency at high load operating conditions than light load condition, characterized by lower exhaust gas temperatures.
Technical Paper

A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-04-16
2012-01-0365
Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO₃ (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn⁴+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/γ-Al₂O₃ (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO₂).
Technical Paper

Next Generation Formed-In-Place Gasket (FIPG) Liquid Sealant for Automotive Intake Manifold Application

2009-04-20
2009-01-0996
Intake manifold is a part of an engine that supplies fuel/air mixture to the cylinder heads. Recently, silicone FIPG has been used for the two part design of the intake manifold. It is known that a small, but significant, amount of gasoline fuel can penetrate through silicone FIPG layer due to the flexible nature of the siloxane backbone. Since gasoline permeation is becoming more important because of more severe regulations, it is found that a new polyacrylate based FIPG dramatically reduces the gasoline fuel permeation. This study compares this new technology, polyacrylate FIPG sealant with silicone FIPG sealant used today for vehicle powertrain gasketing applications. Adhesion investigation on both aluminum and magnesium alloys, and oil resistance are also discussed in this study.
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