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Mo-free 1.6-GPa bolt was developed for a Variable Compression Turbo (VC-Turbo) engine, which is environment friendly and improves fuel efficiency and output. Mo contributes to the improvement of delayed fracture resistance; therefore, the main objective is to achieve both high strength and delayed fracture resistance. Therefore, Si is added to the developed steel to achieve high strength and delayed fracture resistance. The delayed fracture tests were performed employing the Hc/He method. Hc is the limit of the diffusible hydrogen content without causing a delayed fracture under tightening, and He is the diffusible hydrogen content entering under a hydrogen-charging condition equivalent to the actual environment. The delayed fracture resistance is compared between the developed steel and the SCM440 utilized for 1.2-GPa class bolt as a representative of the current high-strength bolts.