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Technical Paper

Improved Coated Gasoline Particulate Filters for China 7 and US Tier 4 Legislations

2024-04-09
2024-01-2387
The impending emission regulations in both China (CN7) and the United States (Tier 4) are set to impose more stringent emission limits on hydrocarbons (HC), carbon monoxide (CO), nitrogen oxides (NOx), and particulate matter (PM). CN7 places particular emphasis on reducing particulate number (PN) thresholds, while the forthcoming United States Tier 4 legislation is primarily concerned with reducing the allowable particulate matter (PM) to an assumed limit of 0.5 mg/mile. Given the more stringent constraints on both PN and PM emissions, the development of enhanced aftertreatment solutions becomes imperative to comply with these new regulatory demands. Coated Gasoline Particulate Filters (cGPFs) play a pivotal role as essential components for effective PN and PM abatement.
Technical Paper

Advanced Aftertreatment System Meeting Future HD CNVII Legislation

2024-04-09
2024-01-2379
Options for CNVII emission legislation are being widely investigated in a national program organized by China Vehicle Emission Control Center (VECC) since early 2020. It is foreseen that this possibly last legislation in China will have more stringent emission requirements compared to CNVI, including among other changes especially a further reduction of nitrogen oxide (NOx), inclusion of nitrous oxide (N2O) and sub-23 nm particle number (PN). This study investigates the technical feasibility to fulfill a CNVII emission legislation scenario, based on a modified CNVI 8 L engine operating under both cold and hot World Harmonized Transient Cycle (WHTC) and Low Load Cycle (LLC).
Technical Paper

Performance Evaluation Study to Optimize the NOx Conversion Efficiency of SDPF Catalyst for BS6 RDE/OBD2 Engine Application

2024-01-16
2024-26-0161
To meet future emission levels, the automotive industry is trying to reduce tailpipe emissions through both possible pathways, i.e. emission from engines as well as and the development of novel catalytic emission control concepts. The present study will focus on the close coupled SCR on Filter commonly known as SDPF which is a main pathway to reduce NOx along with particulate mass and number for light duty passenger cars and sport utility vehicles for BS 6 RDE/OBD 2 and future legislation like BS-7. The SDPF is a challenging technology as it is critical component in exhaust after treatment system involving in NOx and PM/PN reductions hence careful optimization of this technology is necessary in terms of space velocity requirements, temperature, feed NOx emission levels, particulate mass and ash holding capacities, NH3 storage on the SDPF, and back pressure.
Technical Paper

Effect of Engine-Out Soot Emissions and the Frequency of Regeneration on Gasoline Particulate Filter Efficiency

2020-04-14
2020-01-1431
Gasoline particulate filters (GPFs) are an important aftertreatment system that enables gasoline direct injection (GDI) engines to meet current emission standardsn note of GPFs may need to improonont accumulates on the GPF during engine operation. GPFs are often ‘pa during vehicle operation when the exhaust is sufficiently hot and it contains sufficient oxygen. This paper explores the effect that engine-out soot emissions and the frequency of GPF regeneration have on GPF filtration efficiency. Two GPF technologies were tested on two engine dynamometers as well as two production vehicles on a chassis dynamometer. The engines span a wide range of engine-out particle emissions (a range of almost one order of magnitude). The filtration efficiency of the GPFs were measured with a regulation-compliant particle number system (non-volatile particles > 23 nm), as well as with a particle counter with a lower cutoff of 2.5 nm, and with a differential mobility spectrometer.
Journal Article

Catalysts for Post Euro 6 Plug-In Hybrid Electric Vehicles

2020-04-14
2020-01-0354
Due to benefits from the use of electric power, Hybrid Electric Vehicles (HEVs) and Plug-in Hybrid Electric Vehicles (PHEVs) are regarded to be superior over conventional Internal Combustion Engine (ICE) only vehicles in fuel economy and emissions. However, recent studies find out that this is not always true. On certain conditions, hybrid vehicles can be even more polluted. In order to identify these challenges and develop catalysts to meet more stringent emission requirement in the future, e.g. Euro 7, for hybrid application, as a part of our xHEV project, this study includes exclusively extensive investigation on a latest Euro 6d temp Parallel PHEV.
Technical Paper

Impact of European Real-Driving-Emissions Legislation on Exhaust Gas Aftertreatment Systems of Turbocharged Direct Injected Gasoline Vehicles

2017-03-28
2017-01-0924
Recently, the European Union has adopted a new regulation on Real-Driving-Emissions (RDE) and also China is considering RDE implementation into new China 6 legislation. The new RDE regulation is focused on measuring nitrogen oxides (NOx) and particulate number (PN) emissions of both light-duty gasoline and diesel vehicles under real world conditions. A supplemental RDE test procedure was developed for European type approval, which includes on-road testing with cars equipped with portable emission measurement systems (PEMS). This new regulation will significantly affect the engine calibrations and the exhaust gas aftertreatment. In this study the impact of the new RDE regulation on two recent EU 6b certified turbocharged direct injected gasoline vehicles has been investigated. A comparison of several chassis dyno drive cycles with two new defined on-road RDE cycles was performed.
Technical Paper

Synthetic Gas Bench (SGB) Tests Simulating Real and Dynamic Driving Conditions: A New and Cost Attractive Method for TWC Evaluation

2015-04-14
2015-01-1066
The introduction of vehicle emission and fuel economy standards (CO2) accelerates the introduction of new platform and powertrain combinations into the market place. All of these combinations will require unique exhaust gas aftertreatment systems that comply with the current emission legislation. The optimization of each unique aftertreatment solution requires the proper application of catalyst technologies at the lowest PGM concentrations. The optimization process needs to be fast, reliable, realistic and cost attractive. It is arguable that performing the aftertreatment optimization on a chassis dynamometer is variable, time consuming and expensive. This work demonstrates how a synthetic gas bench (SGB) can be used to simulate stoichiometric engine emissions and aftertreatment performance. The SGB procedure duplicates the vehicle NEDC engine-out emissions and catalyst heat-up profiles.
Technical Paper

Advanced TWC Technology to Cover Future Emission Legislations

2015-04-14
2015-01-0999
The new emission regulations in Europe, EU 6 will promulgate more realistic driving conditions with more stringent HC, CO, NOx and particulate emissions. This legislation will also include the WLTP (Worldwide harmonized Light vehicles Test Procedure) cycle for CO2 measurements and a new requirement called “Real-Driving-Emissions” (RDE) as well. The RDE requirement is to ensure modern vehicles comply with the legislation under all conditions of normal driving. More robust aftertreatment solutions are needed to meet these new requirements. This work introduces an improved three-way catalyst (TWC) for gasoline engines for these new regulations. It is tested under static and dynamic conditions and on several engines and vehicles with various drive cycles. It offers better thermal stability combined with lower backpressure than former TWC generations.
Journal Article

Applicable Diesel Oxidation Catalyst for Multi-Diesel Exhaust System

2014-04-01
2014-01-1511
The diesel oxidation catalysts (DOC) having high purification performance to the exhaust gas at low temperatures were investigated. In this paper two main technological improvements from conventional DOC are shown. First is forming Pt/Pd composite particles in order to suppress sintering of precious metal under high thermal aging condition. This generating Pt/Pd composite and the effect were exemplified by TEM-EDS and XRD analysis. Second is adjusting electric charge of Pt/Pd surface to reduce interaction between Pt/Pd and carbon monoxide (CO) by modifying the support material components. Adjusting electric charge of Pt/Pd surface by applying new support material could cancel CO poisoning at Pt/Pd surface. Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) studies suggested that improved support material is more suitable for CO oxidation at a low temperature based on the concept.
Technical Paper

Comprehensive Gasoline Exhaust Gas Aftertreatment, an Effective Measure to Minimize the Contribution of Modern Direct Injection Engines to Fine Dust and Soot Emissions?

2014-04-01
2014-01-1513
With the growing awareness about the presence of fine/ultra fine particulates in the ambient air and their negative impact on climate and health, some regions of the world have started to look closer at the contribution of road traffic. Since Gasoline engines, in particular when injecting fuel directly into the combustion chamber, proved to emit relevant numbers of particulates, even hardly visible, the growing share of Gasoline DI engines and their small size of particulate emissions is a concern. To address the same, the EU has already set limits for the particulate number with EU6 from 2015 onwards. The US considers setting challenging limits by particulate mass. Since mass of ultra fine particulates is very low and difficult to measure, experts investigate if a measurement by number might better address the particular concern. The implementation of a coated Particulate Filter enables meeting not only basic demands during traditional emission test cycles.
Technical Paper

Different Properties of Biodiesel in Comparison with Standard Diesel Fuel and their Impact on EURO VI Exhaust Aftertreatment Systems

2012-09-10
2012-01-1733
The use of fatty acid methyl esters (FAME), often referred to as biodiesel, instead of fossil diesel fuel is under consideration in order to increase the share of fuels from renewable sources and to reduce greenhouse gas emissions. In Europe, commercial diesel fuels already contain up to 7% biodiesel. Higher biodiesel blends or the use of pure biodiesel are probable measures to further increase the share of fuels from renewable sources. Due to its different feedstock and refining process, the specification of biodiesel reveals some important distinctions in comparison with standard diesel fuel. The current work aims to discuss the possible implications of biodiesel utilization on the aftertreatment systems of recent heavy-duty diesel (HDD) vehicles compliant with EURO VI legislation. In particular, the effect of biodiesel on heat-up operation, i.e., the increase of the exhaust gas temperature by catalytic combustion of fuel within a diesel oxidation catalyst (DOC), is investigated.
Technical Paper

Catalyst Technologies for Gasoline Engines with Respect to CO2 Reduction

2011-01-19
2011-26-0027
Besides the further reduction of the harmful gaseous emissions (HC, CO and NOx) to reach upcoming emission limits, the discussion on lowering the CO₂ emissions is omnipresent. From engine development point of view further optimization of the stoichiometric-operated gasoline engine as well as the introduction of lean-operated engines are the main development trend. The emission control system can support the engine development by dedicated catalyst technologies as presented in this paper. A new family of TWC technologies offers to tune the catalyst system to the engine performance and the back pressure requirement - which helps to reduce CO₂ emissions. In addition these technologies show improved performance in HC, CO, NOx light-off, and in CO and NOx conversions under dynamic conditions - this again can positively impact the CO₂ emissions as less harsh heating strategies for cold start is required.
Journal Article

Comparison of Diesel Spray Combustion in Different High-Temperature, High-Pressure Facilities

2010-10-25
2010-01-2106
Diesel spray experimentation at controlled high-temperature and high-pressure conditions is intended to provide a more fundamental understanding of diesel combustion than can be achieved in engine experiments. This level of understanding is needed to develop the high-fidelity multi-scale CFD models that will be used to optimize future engine designs. Several spray chamber facilities capable of high-temperature, high-pressure conditions typical of engine combustion have been developed, but because of the uniqueness of each facility, there are uncertainties about their operation. For this paper, we describe results from comparative studies using constant-volume vessels at Sandia National Laboratories and IFP.
Journal Article

Effects of Methane/Hydrogen Blends On Engine Operation: Experimental And Numerical Investigation of Different Combustion Modes

2010-10-25
2010-01-2165
The introduction of alternative fuels is crucial to limit greenhouse gases. CNG is regarded as one of the most promising clean fuels given its worldwide availability, its low price and its intrinsic properties (high knocking resistance, low carbon content...). One way to optimize dedicated natural gas engines is to improve the CNG slow burning velocity compared to gasoline fuel and allow lean burn combustion mode. Besides optimization of the combustion chamber design, hydrogen addition to CNG is a promising solution to boost the combustion thanks to its fast burning rate, its wide flammability limits and its low quenching gap. This paper presents an investigation of different methane/hydrogen blends between 0% and 40 vol. % hydrogen ratio for three different combustion modes: stoichiometric, lean-burn and stoichiometric with EGR.
Technical Paper

Improving Emissions, Noise and Fuel Economy Trade-Off by using Multiple Injection Strategies in Diesel Low Temperature Combustion (LTC) Mode

2010-10-25
2010-01-2162
Latest emissions standards impose very low NOx and particle emissions that have led to new Diesel combustion operating conditions, such as low temperature combustion (LTC). The principle of LTC is based on enhancing air fuel mixing and reducing combustion temperature, reducing raw nitrogen oxides (NOx) and particle emissions. However, new difficulties have arisen. LTC is typically achieved through high dilution rates and low CR, resulting in increased auto-ignition delay that produces significant noise and deteriorates the combustion phasing. At the same time, lower combustion temperature and reduced oxygen concentration increases hydrocarbon (HC) and carbon oxide (CO) emissions, which can be problematic at low load. Therefore, if LTC is a promising solution to meet future emission regulations, it imposes a new emissions, fuel consumption and noise trade-off. For this, the injection strategy is the most direct mean of controlling the heat release profile and fuel air mixture.
Journal Article

Increasing Power Density in HSDI Engines as an Approach for Engine Downsizing

2010-05-05
2010-01-1472
In the context of CO₂ emission regulations and increase of energy prices, the downsizing of engine displacement is a widely discussed solution that allows a reduction of fuel consumption. However, high power density is required in order to maintain the power output and a good driveability. This study demonstrates the potential to strongly increase the specific power of High Speed Diesel Injection (HSDI) diesel engines. It includes the technological requirements to achieve high specific power and the optimal combination of engine settings to maximize specific power. The results are based on experimental work performed with a prototype single-cylinder engine (compression ratio of 14). Tests were conducted at full load, 4000 rpm. Part load requirements are also taken into account in the engine definition to be compatible with the targets of new emission standards.
Journal Article

Cold Start on Diesel Engines: Effect of Fuel Characteristics

2010-05-05
2010-01-1506
Faced with the need to reduce greenhouse gas emissions, diesel engines present the advantage of having low CO₂ emission levels compared to spark-ignited engines. Nevertheless, diesel engines still suffer from the fact that they emit pollutants and, particularly nitrogen oxides (NOx) and particulates (PM). One of the most promising ways to meet this challenge is to reduce the compression ratio (CR). However a current limitation in reducing the diesel CR is cold start requirements. In this context, the fuel characteristics such as the cetane number, which represents ignition, and volatility could impact cold start. That is why a matrix of 8 fuels was tested. The cetane number ranges from 47.3 to 70.9 and the volatility, represented by the temperature necessary to distillate 5% of the product (T5%), ranges from 173 to 198°C. The engine tests were carried out at -25°C, on a common rail 4-cylinder diesel engine.
Journal Article

Optimization of a Euro 5 Vehicle Powered by an Ethanol Based Diesel Fuel

2010-05-05
2010-01-1520
Diversifying energy resources and reducing greenhouse gas emissions are key priorities in the forthcoming years for the automotive industry. Currently, among the different solutions, sustainable biofuels are considered as one of the most attractive answer to these issues. This paper deals with the vehicle application of an innovative diesel fuel formulation using Ethanol to tackle these future challenges. The main goal is to better understand the impact of using biofuel blends on engine behavior, reliability and pollutants emissions. This alternative oxygenated fuel reduces dramatically particulate matter (PM) emissions; this paves the way to improve the NOx/PM/CO₂ trade-off. Another major interest is to avoid adding a particulate filter in the exhaust line and to avoid modifying powertrain and vehicle hardware and therefore to minimize the overall cost to fulfill upcoming emission regulations.
Journal Article

Study of Air Entrainment of Multi-hole Diesel Injection by Particle Image Velocimetry - Effect of Neighboring Jets Interaction and Transient Behavior After End of Injection.

2010-04-12
2010-01-0342
The air entrainment of multi-hole diesel injection is investigated by high speed Particle Image Velocimetry (PIV) using a multi-hole common rail injector with an injection pressure of 100 MPa. The sprays are observed in a high pressure, high temperature cell that reproduces the thermodynamic conditions which exist in the combustion chamber of a diesel engine during injection. Typical ambient temperature of 800K and ambient density of 25 kg/m3 are chosen. The air entrainment is studied with the PIV technique, giving access to the velocity fields in the surrounding air and/or in the interior of two neighboring jets. High acquisition rate of 5000 Hz, corresponding to 200 μs between two consecutive image pairs is obtained by a high-speed camera coupled with a high-speed Nd:YLF laser. The effect of neighboring jets interaction is studied by comparing four injectors with different numbers of holes (4, 6, 8 and 12) with similar static mass flow rate per hole.
Journal Article

Analysis of Combustion Process in Cold Operation with a Low Compression Ratio Diesel Engine

2010-04-12
2010-01-1267
Future emissions standards for passenger cars require a reduction of NOx (nitrogen oxide) and CO₂ (carbon dioxide) emissions of diesel engines. One of the ways to reach this challenge while keeping other emissions under control (CO: carbon monoxide, HC: unburned hydrocarbons and particulates) is to reduce the volumetric compression ratio (CR). Nevertheless complications appear with this CR reduction, notably during very cold operation: start and idle. These complications justify intensifying the work in this area. Investigations were led on a real 4-cylinder diesel 13.7:1 CR engine, using complementary tools: experimental tests, in-cylinder visualizations and CFD (Computational Fluid Dynamics) calculations. In previous papers, the way the Main combustion takes place according to Pilot combustion behavior was highlighted. This paper, presents an in-depth study of mixture preparation and the subsequent combustion process.
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