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Technical Paper

Kinetic Measurements of HNCO Hydrolysis over SCR Catalyst

2018-09-10
2018-01-1764
To meet the strict emission regulations for diesel engines, an advanced processing device such as a Urea-SCR (selective catalytic reduction) system is used to reduce NOx emissions. The Real Driving Emissions (RDE) test, which is implemented in the European Union, will expand the range of conditions under which the engine has to operate [1], which will lead to the construction of a Urea-SCR system capable of reducing NOx emissions at lower and higher temperature conditions, and at higher space velocity conditions than existing systems. Simulations are useful in improving the performance of the urea-SCR system. However, it is necessary to construct a reliable NOx reduction model to use for system design, which covers the expanded engine operation conditions. In the urea-SCR system, the mechanism of ammonia (NH3) formation from injected aqueous urea solution is not clear. Thus, it is important to clarify this mechanism to improve the NOx reduction model.
Technical Paper

ISO 26262 C Class Evaluation Method for Motorcycles by Expert Riders Incorporating Technical Knowledge Obtained from Actual Riding Tests

2017-11-05
2017-32-0057
In applying the ISO 26262 controllability classification for motorcycles in actual riding tests, a subjective evaluation by expert riders is considered to be the appropriate approach from the viewpoint of safety. We studied the construction of an expert-rider-based C class evaluation method for motorcycles and developed some evaluation test cases reproducing various hazardous events. We determined that it was necessary to accumulate more evaluation cases for further representative scenarios and that, to avoid variations in such evaluations, a method in which different expert riders can carry out testing following a common understanding had to be devised. Considering these problems for practical application, this study aimed at establishing an actual riding test method for C class evaluation by expert riders and to develop a deeper understanding of test procedures and management.
Technical Paper

Detailed Study of Hazard Analysis and Risk Assessment of ISO 26262 for Motorcycles

2017-11-05
2017-32-0083
ISO 26262, an international functional safety standard of electrical and/or electronic systems (E/E systems) for motor vehicles, was published in November 2011 and it is expected that the scope will be extended to motorcycles in a second edition of ISO 26262 going to be published in 2018. ISO/DIS 26262 second edition published in 2016 has Part 12 as a new part in order to apply ISO 26262 to motorcycle. Proper estimation of Exposure, Controllability, and Severity in accordance with ISO/DIS 26262 Part 12, are key factors to determine Motorcycle Safety Integrity Level. To estimate precise these factors, there would be a case that it might not be appropriate to apply studies done for passenger car to motorcycle, and it would be necessary to apply motorcycle specific knowledge and estimation methods. In our previous studies we clarified these motorcycle specific issues and studied the method for the adaptation.
Journal Article

Prediction of Spray Behavior in Injected by Urea SCR Injector and the Reaction Products

2017-10-08
2017-01-2375
In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.
Journal Article

Examination of Hazard Analysis and Risk Assessment and Exposure Research in the Real Traffic Situation of ISO 26262 for Motorcycles

2016-11-08
2016-32-0058
ISO 26262, an international functional safety standard of electrical and/or electronic systems (E/E systems) for motor vehicles, was published in November 2011 and it is expected that the scope will be extended to motorcycles in a second edition of ISO 26262 going to be published in 2018. In order to apply ISO 26262 to motorcycle, proper estimation of Exposure, Controllability, and Severity are key factors to determine Motorcycle Safety Integrity Level (MSIL). Exposure is a factor to indicate the probability of the state of an operational situation that can be hazardous with the E/E system malfunction. And it is not easy to estimate the motorcycle Exposure due to less availability of back ground data in actual operational situation compared to motor vehicle. Therefore real traffic situation should be investigated in order to provide rationales for MSIL determination.
Journal Article

Comparison of Fires in Lithium-Ion Battery Vehicles and Gasoline Vehicles

2014-04-01
2014-01-0428
Electric vehicles have become more popular and may be involved in fires due to accidents. However, characteristics of fires in electric vehicles are not yet fully understood. The electrolytic solution of lithium-battery vehicles is inflammable, so combustion characteristics and gases generated may differ from those of gasoline cars. Therefore, we conducted fire tests on lithium-ion battery vehicles and gasoline vehicles and investigated the differences in combustion characteristics and gases generated. The fire tests revealed some differences in combustion characteristics. For example, in lithium-ion battery vehicles, the battery temperature remained high after combustion of the body. However, there was almost no difference in the maximum CO concentration measured 0.5 to 1 m above the roof and 1 m from the side of the body. Furthermore, HF was not detected in either type of vehicle when measured at the same positions as for CO.
Journal Article

Development and Characteristics of a Burner for Localized Fire Tests and an Evaluation of Those Fire Tests

2012-04-16
2012-01-0987
We have developed a new propane burner that satisfies the requirements of localized fire test which was presented in SAE technical paper 2011-01-0251. This paper introduces the specifications of this burner and reports its characteristics as determined from various fire exposure tests that we conducted in order to gather data. These tests included temperature and heat flux distribution on cylinder surfaces, which would be useful for the design of automotive compressed fuel cylinders. Our fire exposure tests included localized and engulfing fire tests to compare TPRD activation time, cylinder burst pressure and other parameters between different flame configurations and tests to identify the effects of an automotive compressed fuel cylinder on localized fire test results.
Journal Article

Study of the Impact of High Biodiesel Blends on Engine Oil Performance

2011-08-30
2011-01-1930
In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.
Technical Paper

Establishing Localized Fire Test Methods and Progressing Safety Standards for FCVs and Hydrogen Vehicles

2011-04-12
2011-01-0251
The SAE Fuel Cell Vehicle (FCV) Safety Working Group has been addressing FCV safety for over 11 years. In the past couple of years, significant attention has been directed toward a revision to the standard for vehicular hydrogen systems, SAE J2579(1). In addition to streamlining test methodologies for verification of Compressed Hydrogen Storage Systems (CHSSs) as discussed last year,(2) the working group has been considering the effect of vehicle fires, with the major focus on a small or localized fire that could damage the container in the CHSS and allow a burst before the Pressure Relief Device (PRD) can activate and safely vent the compressed hydrogen stored from the container.
Journal Article

Mixing-Controlled, Low Temperature Diesel Combustion with Pressure Modulated Multiple-Injection for HSDI Diesel Engine

2010-04-12
2010-01-0609
This paper proposes a new mixing-controlled, low temperature combustion (LTC) approach for high-speed direct injection (HSDI) diesel engines. The purpose of this approach is to avoid the excessively high pressure-rise rate (PRR) of premixed, kinetics-controlled LTC and to enable the low nitrogen oxides (NOx) combustion to operate over the wide speed and load range of the engine. To address the soot/noise trade-off at high load LTC operating conditions, the pressure modulated multiple-injection coupled with swirl control was applied. This injection strategy enables the injection of high pressure (HP) main spray into the local high temperature region of the already burning low pressure (LP) pilot spray injected from the neighboring injection hole. By employing this injection strategy, the equivalence ratio (φ) distribution of mixture is drastically varied during main combustion processes.
Technical Paper

SOF Component of Lubricant Oil on Diesel PM in a High Boosted and Cooled EGR Engine

2007-04-16
2007-01-0123
The engine in the research is a single cylinder DI diesel using the emission reduction techniques such as high boost, high injection pressure and broad range and high quantity of exhaust gas recirculation (EGR). The study especially focuses on the reduction of particulate matter (PM) under the engine operating conditions. In the experiment the authors measured engine performance, exhaust gases and mass of PM by low sulfur fuel such as 3 ppm and low sulfur lubricant oil such as 0.26%. Then the PM components were divided into soluble organic fraction (SOF) and insoluble organic fraction (ISOF) and they were measured at each engine condition. The mass of SOF was measured from the fuel fraction and lubricant oil fraction by gas chromatography. Also each mass of soot fraction and sulfate fraction was measured as components of ISOF. The experiment was conducted at BMEP = 2.0 MPa as full load condition of the engine and changing EGR rate from 0% to 40 %.
Technical Paper

Effects of Fuel Properties on the Performance of Advanced Diesel NOx Aftertreatment Devices

2006-10-16
2006-01-3443
In the Japan Clean Air Program II (JCAP II) Diesel WG, effects of fuel properties on the performance of two types of diesel NOx emission aftertreatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined. For a Urea-SCR system, the NOx emission reduction performance with and without an oxidation catalyst installed in front of the SCR catalyst at low exhaust gas temperature operation was compared. For an NSR catalyst system, the effect of fuel sulfur on both emissions and fuel economy during 50,000 km driving was examined. Furthermore, effects of other fuel properties such as distillation on exhaust emissions were investigated. The results show that sulfur is the influential factor for both devices. Namely, high NOx emission reduction performance of the Urea-SCR system with the oxidation catalyst at low exhaust gas temperature operation is influenced by sulfur.
Technical Paper

Impact of Oil-derived Sulfur and Phosphorus on Diesel NOx Storage Reduction Catalyst - JCAP II Oil WG Report

2006-10-16
2006-01-3312
Emission regulations for diesel-powered vehicles have been gradually tightening. Installation of after-treatment devices such as diesel particulate filters (DPF), NOx storage reduction (NSR) catalysts, and so on is indispensable to satisfy rigorous limits of particulate matter (PM) and nitrogen oxides (NOx). Japan Clean Air Program II Oil Working Group (JCAPII Oil WG) has been investigating the effect of engine oil on advanced diesel after-treatment devices. First of all, we researched the impact of oil-derived ash on continuous regeneration-type diesel particulate filter (CR-DPF), and already reported that the less sulfated ash in oil gave rise to lower pressure drop across CR-DPF [1]. In this paper, impact of oil-derived sulfur and phosphorus on NSR catalyst was investigated using a 4L direct injection common-rail diesel engine with turbo-intercooler. This engine equipped with NSR catalyst meets the Japanese new short-term emission regulations.
Technical Paper

Improvement of Flame Exposure Test for High Pressure Hydrogen Cylinders to Achieve High Reliability and Accuracy

2006-04-03
2006-01-0128
To achieve a method for flame exposure testing of high-pressure cylinders in automobiles that allows fair evaluations to be made at each testing institute and also provides high testing accuracy, we investigated the effects of the flame scale of the fire source, the fuel type, the shape of the pressure relief device shield, and the ambient temperature through experiments and numerical simulation. We found that, while all of these are factors that influence evaluation results, the effects of some factors can be reduced by increasing the flame size. Therefore, a measurement technique to quantitatively determine the flame size during the test is required. Measuring temperatures at the top of each cylinder is a candidate technique. Furthermore, flame exposure tests to be conducted on cylinders as single units must ensure safety during a vehicle fire.
Technical Paper

Effect of Alcohol Fuels on Fuel-Line Materials of Gasoline Vehicles

2005-10-24
2005-01-3708
In 1999, some Japanese fuel suppliers sold highly concentrated alcohol fuels, which are mixtures of gasoline and oxygenates, such as alcohol or ether, in amounts of 50% or more. In August 2001, it was reported that some vehicle models using the highly concentrated alcohol fuels encountered fuel leakage and vehicle fires due to corrosion of the aluminum used for the fuel-system parts. The Ministry of Economy, Trade and Industry (METI) and the Ministry of Land, Infrastructure and Transport Government of Japan (MLIT) jointly established the committee on safety for highly concentrated alcohol fuels in September 2001. The committee consisted of automotive technology and metal corrosion experts knowledgeable about preventing such accidents and ensuring user safety. Immersion tests were conducted on metals and other materials used for the fuel-supply system parts to determine the corrosion resistance to each alcohol component contained in the highly concentrated alcohol fuels.
Technical Paper

Lubricity of Liquefied Gas Assessment of Multi-Pressure/Temperature High-Frequency Reciprocating Rig (MPT-HFRR) -DME Fuel for Diesel

2004-06-08
2004-01-1865
In this study, a MPT-HFRR (Multi-Pressure/Temperature High-Frequency Reciprocating Rig) was manufactured based on a diesel fuel lubricity test apparatus. The MPT-HFRR was designed to be used for conventional test methods as well as for liquefied gas fuel tests. Lubricity tests performed on a calibration standard sample under both atmospheric pressure and high pressure produced essentially constant values, so it was determined that this apparatus could be used for assessing the lubricity of fuel. Using this apparatus, the improvement of lubricity due to the addition of a DME (Dimethyl Ether) fuel additive was investigated. It was found that when 50ppm or more of a fatty acid lubricity improver was added, the wear scar diameter converged to 400μm or less, and a value close to the measured result for Diesel fuel was obtained. The lubricity obtained was considered to be generally satisfactory.
Technical Paper

Feasibility Study of Urea SCR Systems on Heavy Duty Commercial Vehicles

2004-06-08
2004-01-1944
Four urea SCR systems were developed and evaluated on a C/D and on the road to investigate their potential for Japanese emission regulations in 2005 and beyond. Test results showed that NOx conversion ratios were 50 to 70% during the Japanese D13 mode cycle, and the ratios under the transient driving cycle were lower than those tested during a steady state. Unregulated emissions, such as benzene, aldehyde and benzo[a]pyrene, existed either at a trace level using the oxidation catalyst, or lower than a base diesel engine, when no oxidation catalyst was used. The health effects of particulate matter emitted from the SCR system were almost the same as those from conventional diesel engines, as evaluated by the Ames test and in vitro micronucleus test. Thermal degradation products, such as cyanuric acid and melamine, were two to four figures lower compared with the toxicological information of Safety Information Resources Inc. (SIRI).
Technical Paper

Lubricity of Liquefied Gas - Assessment of the Various Pressure and Temperature High-Frequency Reciprocating Rig (VPT-HFRR) - LPG Blended Fuel for Diesel Engine

2003-10-27
2003-01-3092
In this research, a test apparatus (VPT-HFRR) for evaluating lubricity was manufactured at an arbitrary pressure according to the lubricity test method (HFRR) for diesel fuel. The lubricity of LPG blended fuel (LBF) for diesel engines was examined using VPT-HFRR., This was a value close to that of diesel fuel, and when a suitable lubricity had been maintained, it was checked. Prototype trucks were manufactured and their durability was examined. After a run of 70,000km or more, no serious trouble had occurred, and when LBF was maintained at a suitable lubricity, it was checked.
Technical Paper

77 Basic Investigation of Particulate Matters (O-PM)) and Polycyclic Aromatic Hydrocarbons Emitted by Two-stroke Motorcycles

2002-10-29
2002-32-1846
Characteristics of mass emission of unburned Oil-Particulate Matter and polycyclic aromatic hydrocarbons from two-stroke scooter were investigated. The tests were carried out under with and without oxidation catalyst and various air-fuel ratio ranging from 12 to 16 at 50:1 of fuel-oil mixing ratio for easy sampling. Unburned Oil-Particulate Matter and 4- to 7-rings polycyclic aromatic hydrocarbons were trapped on filter. These compounds were analyzed by high performance liquid chromatography with fluorescence detector. Mass emission of polycyclic aromatic hydrocarbons and unburned Oil-Particulate Matter tends to decrease as air-fuel ratio which increased up to stoichiometric ratio. The highest conversion ratio of unburned Oil-Particulate Matter on the oxidation catalyst was 64%. Conversion ratio of polycyclic aromatic hydrocarbons increased as rings are smaller.
Technical Paper

Reduction in Exhaust Emissions from Methanol Fueled Vehicle by Intermittent Dual-Fluid Exhaust Burner (IDEB)

1997-02-24
970742
Intermittent Dual-fluid Exhaust Burner (IDEB) has been developed to reduce emissions from methanol fueled vehicles during the warm-up period after a cold start. The IDEB does not need any special fuel injector or blower, and has been built mainly through software modification of an ECU. An FTP mode test while operating an IDEB confirmed that the catalyst temperature was rapidly increased to significantly reduce the emissions to meet a level of ULEV standards.
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