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To comply with increasingly strict emission regulations, diesel vehicles are equipped with Diesel Particulate Filters (DPF) to capture fine particulate matter (PM) from exhaust gas. However, due to the limited capacity of DPF to capture soot, periodic regeneration processing is required to burn it off. The ash created by metal-based additives in engine oil accumulates in DPF, leading to issues such as increased regeneration frequency and decreased fuel efficiency. To solve this problem, researchers have developed diesel engine oil with reduced ash content. However, the authors are taking it a step further and developing a diesel engine oil without metal-based detergents and anti-wear additives, for even more significant environmental impact reduction. This paper describes the development of an ashless engine oil with DH-2 performance, the effects of the developed engine oil on DPF, and the results of engine and actual field tests.

The SAE J300 classification was expanded to 0W-12 and 0W-8 viscosity grades in 2015, and lower viscosity engine oils have been studied in the industry. ILSAC GF-6B that will be introduced in 2020 will specify a 0W-16 requirement, but 0W-12 and 0W-8 grades are not considered. Because engine oil equal to or higher than the 0W-20 grade is recommended for almost all engines globally, suitable engine tests for 0W-12 and 0W-8 do not exist. Therefore, the Japan Automobile Manufacturers Association, Petroleum Association of Japan and Society of Automotive Engineers of Japan decided to establish new 0W-12 and 0W-8 low viscosity engine oil specifications. It is referred to as JASO GLV-1, and together with a new fuel economy engine test procedure, these engine oils for better fuel economy will be put on the Japanese market in 2019. Motoring friction torque tests are widely used to ascertain the friction reduction effect of fuel-economy engine oils.

The deposition of ash derived from engine oil on the surface of diesel particle filters (DPF) has recently been reported to degrade the performance of the DPF. It is generally known that phosphorus in engine oil is adsorbed on the surface of an automotive exhaust catalyst, reducing the performance of the catalyst. Thus, the amounts of ash and phosphorus in engine oil have been decreased. We have developed a non-phosphorus, non-ash engine oil (NPNA) that does not contain metal-based detergents or zinc dialkyldithiophosphate (ZnDTP). Various engine tests were performed, and we confirmed that under normal running conditions, the NPNA oil had a sufficiently high piston detergency and wear resistance-two important requirements for engine oil-to meet current American and Japanese standards. However, the piston detergency of NPNA required further improvement when engine running conditions were more severe.

To meet the strict emission regulations for diesel engines, an advanced processing device such as a Urea-SCR (selective catalytic reduction) system is used to reduce NOx emissions. The Real Driving Emissions (RDE) test, which is implemented in the European Union, will expand the range of conditions under which the engine has to operate [1], which will lead to the construction of a Urea-SCR system capable of reducing NOx emissions at lower and higher temperature conditions, and at higher space velocity conditions than existing systems. Simulations are useful in improving the performance of the urea-SCR system. However, it is necessary to construct a reliable NOx reduction model to use for system design, which covers the expanded engine operation conditions. In the urea-SCR system, the mechanism of ammonia (NH3) formation from injected aqueous urea solution is not clear. Thus, it is important to clarify this mechanism to improve the NOx reduction model.

In the urea SCR system, urea solution is injected by injector installed in the front stage of the SCR catalyst, and NOx can be purified on the SCR catalyst by using NH3 generated by the chemical reaction of urea. NH3 is produced by thermolysis of urea and hydrolysis of isocyanic acid after evaporation of water in the urea solution. But, biuret and cyanuric acid which may cause deposit are sometimes generated by the chemical reactions without generating NH3. Spray behavior and chemical reaction of urea solution injected into the tail-pipe are complicated. The purpose of this study is to reveal the spray behavior and NH3 generation process in the tail-pipe, and to construct the model capable of predicting those accurately. In this report, the impingement spray behavior is clarified by scattered light method in high temperature flow field. Liquid film adhering to the wall and deposit generated after evaporation of water from the liquid film are photographed by the digital camera.

Recently, deposition of ash derived from engine oil on the surface of a diesel particle filter (DPF) has been reported to worsen the performance of the DPF. It is generally known that phosphorus in engine oil is adsorbed on the surface of an automotive exhaust catalyst and reduces the performance of the catalyst. Thus, the amounts of ash and phosphorus in engine oil have been decreased. We have developed a non-phosphorus and non-ash engine oil (NPNA) that does not contain metal-based detergents and zinc dialkyldithiophosphate (ZnDTP). We performed a performance test for NPNA using an actual engine and reported that the piston detergency and anti-wear performance of NPNA were sufficiently high. However, the piston detergency of NPNA required further improvement when engine running conditions were more severe.

To explore the measures that can be used to improve the fuel economy of internal combustion engines, we investigated how friction at the piston ring-cylinder liner interface is influenced by the boundary lubrication performance of engine oils. We formulated several engine oils with varying boundary lubrication performance and tested them for ring-liner friction by using a floating liner friction tester. We used friction modifiers (FMs) to modify the boundary lubrication performance of engine oils. We found that ring-liner friction is well correlated with the friction coefficients in boundary lubrication regimes when measured by a laboratory friction tester. We also found that the impact of the boundary lubrication performance of engine oils was emphasized in low viscosity engine oils. It makes it possible for improved boundary lubrication performance to inhibit or overcome the viscosity reduction-induced increase of friction energy.

Gasoline engine downsizing combined with a turbocharger is one of the more effective approaches to improve fuel efficiency without sacrificing power performance. The benefit comes from lower pumping loss, lower mechanical friction due to ‘downsizing’ of the engine displacement and ‘down-speeding’ of the engine by using higher transmission gear ratios which is allowed by the higher engine torque at lower engine speeds. However abnormal combustion referred to as Low-Speed Pre-ignition (LSPI) is known to be able to occur in low-speed and high-torque conditions. It is a potential restriction to maximize the engine performance and its benefit, therefore prevention of LSPI is strongly desired for long-term durability of engine performance. According to recent technical reports, auto-ignition of an engine oil droplet in a combustion chamber is believed to be one of major contributing factors of LSPI and its formulations have a significant effect on LSPI frequency.

1 Fuel savings by engine oil have been requested for two-wheeled vehicles from the viewpoint of environmental issues. In four-wheeled vehicles, reduction of oil viscosity and addition of friction modifiers have been effective in improving fuel efficiency. However, direct application of engine oil for four-wheeled vehicles to two-wheeled vehicles is difficult. In a four-cycle two-wheeled vehicle, the transmission, gears, and a wet clutch system are imbedded within the engine1). Engine oil must display a remarkable performance as it is required to function as transmission oil and to improve anti-metal fatigue life and clutch performance2), 3). If fuel efficiency is improved by reducing the viscosity of engine oil used in two-wheeled vehicles, the fatigue life tends to worsen. Therefore, reduction in oil viscosity is difficult to achieve.

The demands of application of dual-axis chassis dynamometers (4WD-CHDY) have increased recently due to the improvement of performance of 4WD-CHDY and an increase in the number of 4WD vehicles which are difficult to convert to 2WD. However, there are few evaluations of any differences between fuel economy and exhaust emission levels in the case of 2WD-CHDY with conversion from 4WD to 2WD (2WD-mode) and 4WD-CHDY without conversion to 2WD (4WD-mode). Fuel economy and exhaust emission tests of 4WD vehicle equipped with a typical 4WD mechanism were performed to investigate any differences between the case of the 2WD-mode and the 4WD-mode. In these tests, we measured ‘work at wheel’ (wheel-work) using wheel torque meters. A comparison of the 2WD-mode and the 4WD-mode reveals a difference of fuel economy (2WD-mode is 1.5% better than that of 4WD-mode) and wheel-work (2WD-mode is 3.9% less than that of 4WD-mode). However, there are almost no differences of exhaust emission levels.

Engine oils normally contain calcium detergents and ZnDTPs to have detergency and antiwear performance. However, it has been recently understood that these additives could deteriorate filter performance in catalyst and DPF. In this background this paper explains the study and the development about new type of engine oil excluding metal detergents and phosphorus compounds. The developed engine oil shows good durability in several JASO engine tests and a fleet test by formulating newly developed additives as substitute for calcium detergents and ZnDTPs.

It is becoming more and more necessary to achieve a sustainable low-carbon society by mobility not depending on oil. Electric vehicles are appropriate for such a society, but expensive battery cost and long charging time prohibit the promotion of EVs. One of the solutions is minimizing battery usage by ultra-low fuel efficiency, so we developed an ultrahigh-efficient electric commuter concept car “C-ta”, which requires as small a battery as possible. We assumed that drivers would use the car as a second car for short-distance daily use, such as commuting, shopping, transportation of family, etc. In order to improve fuel efficiency, we mainly considered an ultra-light weight body and chassis, to which CFRP (carbon fiber reinforced plastic) greatly contributes, ultra-low rolling resistance tires, and highly accurate vehicle control technology with four in-wheel motors.

As well as a four-wheeled vehicle, in the field of motorcycle, development of the CO2 reduction technology and practical use are required for global environment. Zinc dialkyldithiophosphate (Zn-DTP) type additives are widely used for engine oil formulations. However, phosphorus compounds are environmental load materials. The reduction of the quantity of phosphorus compounds in engine oils is required to reduce poisoning of three-way catalysts used to purify exhaust gases from internal combustion engines. Ito1) reported that they developed a sulfur-based additive as a substitute for Zn-DTP. Their non-phosphorus engine oil formulation for four-wheeled vehicles with a sulfur-based additive was examined to evaluate its anti-wear performance using the following test methods: JASO M328 for gasoline engines (KA24E) and JASO M354 for Diesel engine (4D34T4).

Just as CO2 reduction is required of four wheeled vehicles for environmental protection, similar environmental concerns drive the development of motorcycle oil technology. Zinc dialkyldithiophosphate (Zn-DTP) type additives are widely used for engine oil formulations. However, phosphorus compounds are environmental load materials. The reduction of the quantity of phosphorus compounds in engine oils is required to reduce poisoning of three-way catalysts used to purify exhaust gases from internal combustion engines. Mr. Ito and his co-authors1) reported that they developed a sulfur-based additive as a substitute for Zn-DTP. Their non-phosphorus engine oil formulation for four-wheeled vehicles with a sulfur-based additive was examined to evaluate its anti-wear performance using the following test methods:JASO M328 for gasoline engines (KA24E) and JASO M354 for Diesel engine (4D34T4).

Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.

JCAPII gasoline workgroup reported vehicle emission study to comprehend the impact of ETBE blending. In previous study, we focused on the compatibility of ETBE blended gasoline with Japanese current gasoline vehicles in-use. Based on recent discussion with ETBE 8% blended gasoline into the market, more information becomes necessary. In this second report, we studied to comprehend the actual emission impact using realistic model fuels using several base stocks. Fuel properties of T50, T90 and aromatic compound content were selected through discussions. Specifications were changed within the range of the market. Both ETBE 0% and 8% were combined for these fuel matrixes. In total, eight fuels and two reference fuels were tested. Two J-ULEV vehicles (one MPI, and a stoichiometric-SIDI) were procured as representatives. We discussed quantitative and qualitative impact toward emissions. Data regarding CO2 and fuel economy change were also reported.

The engine in the research is a single cylinder DI diesel using the emission reduction techniques such as high boost, high injection pressure and broad range and high quantity of exhaust gas recirculation (EGR). The study especially focuses on the reduction of particulate matter (PM) under the engine operating conditions. In the experiment the authors measured engine performance, exhaust gases and mass of PM by low sulfur fuel such as 3 ppm and low sulfur lubricant oil such as 0.26%. Then the PM components were divided into soluble organic fraction (SOF) and insoluble organic fraction (ISOF) and they were measured at each engine condition. The mass of SOF was measured from the fuel fraction and lubricant oil fraction by gas chromatography. Also each mass of soot fraction and sulfate fraction was measured as components of ISOF. The experiment was conducted at BMEP = 2.0 MPa as full load condition of the engine and changing EGR rate from 0% to 40 %.

Energy conserving performance by engine oils is required even for motorcycles from the viewpoint of environmental issues. The fuel efficiency of passenger car engine oils has been improved through lower viscosity and usage of friction modifiers. However, engine oils containing friction modifiers such as Mo compounds may not be applied to four-stroke motorcycles, because motorcycles normally have a wet clutch system inside the crankcase and such engine oils can decrease the clutch capacity. Therefore, it is important to investigate the effects of oil formulation in order to develop motorcycle engine oils, which can improve fuel efficiency and preserve clutch capacity1)∼2). In this study, fuel efficiency of prototype oils was evaluated with a motorcycle engine motoring tester. In addition, friction coefficients of engine oils formulated with different additives such as dispersants and detergents in clutch system were evaluated with an SAE No. 2 clutch friction tester.

In the Japan Clean Air Program II (JCAP II) Diesel WG, effects of fuel properties on the performance of two types of diesel NOx emission aftertreatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined. For a Urea-SCR system, the NOx emission reduction performance with and without an oxidation catalyst installed in front of the SCR catalyst at low exhaust gas temperature operation was compared. For an NSR catalyst system, the effect of fuel sulfur on both emissions and fuel economy during 50,000 km driving was examined. Furthermore, effects of other fuel properties such as distillation on exhaust emissions were investigated. The results show that sulfur is the influential factor for both devices. Namely, high NOx emission reduction performance of the Urea-SCR system with the oxidation catalyst at low exhaust gas temperature operation is influenced by sulfur.

Emission regulations for diesel-powered vehicles have been gradually tightening. Installation of after-treatment devices such as diesel particulate filters (DPF), NOx storage reduction (NSR) catalysts, and so on is indispensable to satisfy rigorous limits of particulate matter (PM) and nitrogen oxides (NOx). Japan Clean Air Program II Oil Working Group (JCAPII Oil WG) has been investigating the effect of engine oil on advanced diesel after-treatment devices. First of all, we researched the impact of oil-derived ash on continuous regeneration-type diesel particulate filter (CR-DPF), and already reported that the less sulfated ash in oil gave rise to lower pressure drop across CR-DPF [1]. In this paper, impact of oil-derived sulfur and phosphorus on NSR catalyst was investigated using a 4L direct injection common-rail diesel engine with turbo-intercooler. This engine equipped with NSR catalyst meets the Japanese new short-term emission regulations.