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Stringent emission regulations and the anticipated climate change call for a paradigm shift in the design of the conventional internal combustion engines. One way to combat this problem is oxy-fuel combustion in which the combustion products are mainly water vapor and carbon dioxide. Water vapor can be easily separated by condensation and carbon dioxide is then easily captured and stored. However, many technical challenges are associated with this mode of combustion. There are many challenges facing oxy-fuel combustion before it find its way to commercial production especially for internal combustion engines. One such challenge is the relatively high temperature of the oxy-fuel combustion. A solution to this problem is the recirculation of the generated CO2 to moderate the in-cylinder temperature. Therefore, careful study of the effect of recirculating the CO2 back to combustion chamber is needed before the implementation of such a concept.

The improvement of the indicated thermal efficiency of an argon power cycle (replacing nitrogen with argon in the combustion reaction) is investigated in a CFR engine at high compression ratios in homogeneous charge compression ignition (HCCI) mode. The study combines the two effects that can increase the thermodynamic efficiency as predicted by the ideal Otto cycle: high specific heat ratio (provided by argon), and high compression ratios. However, since argon has relatively low heat capacity (at constant volume), it results in high in-cylinder temperatures, which in turn, leads to the occurrence of knock. Knock limits the feasible range of compression ratios and further increasing the compression ratio can cause serious damage to the engine due to the high pressure rise rate caused by advancing the combustion phasing.