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Hydrogen crossover and membrane hydration are significant issues for polymer electrolyte fuel cells (PEFC). Hydrogen crossover amounts to a quantity of unspent fuel, thereby reducing the fuel efficiency of the cell, but more significantly it also gives rise to the formation of hydrogen peroxide in the cathode catalyst layer which acts to irreversibly degenerate the polymer electrolyte. Membrane hydration not only strongly governs the performance of the cell, most noticeable through its effect on the ionic conductivity of the membrane, it also influences the onset and propagation of internal degradation and failure mechanisms that curtail the reliability and safety of PEFCs. This paper focuses on how hydrogen crossover and membrane hydration are affected by; (a) characteristic cell geometries, and (b) operating conditions relevant to automotive fuel cells.

A qualitative FMEA study of Polymer Electrolyte Fuel Cell (PEFC) technology is established and presented in the current work through a literature survey of mechanisms that govern performance degradation and failure. The literature findings are translated into Fault Tree (FT) diagrams that depict how basic events can develop into performance degradation or failure in the context of the following top events; (1) activation losses; (2) mass transportation losses; (3) Ohmic losses; (4) efficiency losses and (5) catastrophic cell failure. Twenty-two identified faults and forty-seven frequent causes are translated into fifty-two basic events and a system of FTs with twenty-one reoccurring dominant mechanisms. The four most dominant mechanisms discussed that currently curtail sustained fuel cell performance relate to membrane durability, liquid water formation, flow-field design, and manufacturing practices.