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The main benefit of HCCI engines compared to SI engines is improved fuel economy. The drawback is the diluted combustion with a substantially smaller operating range if not some kind of supercharging is used. The reasons for the higher brake efficiency in HCCI engines can be summarized in lower pumping losses and higher thermodynamic efficiency, due to higher compression ratio and higher ratio of specific heats if air is used as dilution. In the low load operating range, where HCCI today is mainly used, other parameters as friction losses, and cooling losses have a large impact on the achieved brake efficiency. To initiate the auto ignition of the in-cylinder charge a certain temperature and pressure have to be reached for a specific fuel. In an engine with high in-cylinder cooling losses the initial charge temperature before compression has to be higher than on an engine with less heat transfer.

A naturally aspirated in-line six-cylinder 2.9-litre Volvo engine is operated in Homogeneous Charge Compression Ignition (HCCI) mode, using camshafts with low lift and short duration generating negative valve overlap. This implementation requires only minor modifications of the standard SI engine and allows SI operation outside the operating range of HCCI. Standard port fuel injection is used and pistons and cylinder head are unchanged from the automotive application. A heat exchanger is utilized to heat or cool the intake air, not as a means of combustion control but in order to simulate realistic variations in ambient temperature. The combustion is monitored in real time using cylinder pressure sensors. HCCI through negative valve overlap is recognized as one of the possible implementation strategies of HCCI closest to production. However, for a practical application the intake temperature will vary both geographically and from time to time.

In this work, constant volume combustion is studied using a zero-dimensional FORTRAN code, which is a wide-ranging chemical kinetic simulation that allows a closed system of gases to be described on the basis of a set of initial conditions. The model provides an engine- or reactor-like environment in which the engine simulations allow for a variable system volume and heat transfer both to and from the system. The combustion chamber is divided into two zones as burned and unburned ones, which are separated by an assumed thin flame front in the combustion model used for this work. Equilibrium assumptions have been adopted for the modeling of the thermal ionization, where Saha's equation was derived for singly ionized molecules. The investigation is focused on the thermal ionization of NO as well as for other species. The outputs generated by the model are temperature profiles, species concentration profiles, ionization degree and an electron density for each zone.

In this paper an online method for automatically reducing complex chemical mechanisms for simulations of combustion phenomena has been developed. The method is based on the Quasi Steady State Assumption (QSSA). In contrast to previous reduction schemes where chemical species are selected only when they are in steady state throughout the whole process, the present method allows for species to be selected at each operating point separately generating an adaptive chemical kinetics. The method is used for calculations of a natural gas fueled engine operating under Homogenous Charge Compression Ignition (HCCI) conditions. We discuss criteria for selecting steady state species and the influence of these criteria on the results such as concentration profiles and temperature.

It is generally accepted that knocking combustion influences the heat transfer in SI engines. However, the effects of heat transfer on the onset of knock is still not clear due to lack of experimental data of the thermal boundary layer close to the combustion chamber wall. This paper presents measurements of the temperature in the thermal boundary layer under knocking and non-knocking conditions. The temperature was measured using dual-broadband rotational Coherent anti-Stokes Raman Spectroscopy (CARS). Simultaneous time-resolved measurements of the cylinder pressure, at three different locations, and the heat flux to the wall were carried out. Optical access to the region near the combustion chamber wall was achieved by using a horseshoe-shaped combustion chamber with windows installed in the rectangular part of the chamber. This arrangement made CARS temperature measurements close to the wall possible and results are presented in the range 0.1-5 mm from the wall.

An experimental and theoretical study of the effect of thermal barriers and catalytic coatings in a Homogeneous Charge Compression Ignition (HCCI) engine has been conducted. The main intent of the study was to investigate if a thermal barrier or catalytic coating of the wall would support the oxidation of the near-wall unburned hydrocarbons. In addition, the effect of these coatings on thermal efficiency due to changed heat transfer characteristics was investigated. The experimental setup was based on a partially coated combustion chamber. The upper part of the cylinder liner, the piston top including the top land, the valves and the cylinder head were all coated. As a thermal barrier, a coating based on plasma-sprayed Al2O3 was used. The catalytic coating was based on plasma-sprayed ZrO2 doped with Platinum. The two coatings tested were of varying thickness' of 0.15, 0.25 and 0.6 mm. The compression ratio was set to 16.75:1.

A method for automatic reduction of detailed reaction mechanisms using simultaneous sensitivity, reaction flow and lifetime analysis has been developed and applied to a two-zone model of an SI engine fuelled with Primary Reference Fuel (PRF). Species which are less relevant for the occurrence of autoignition in the end gas are declared redundant. They are identified and eliminated for different pre-set minimum levels of reaction flow and sensitivity. The resulting skeletal mechanism is valid in the ranges of initial and boundary values for which the analyses have been performed. A measure of species lifetime is calculated from the chemical source terms, and the species with the lifetime shorter than and mass-fraction less than specified limits are selected for removal.

A theoretical investigation is presented concerning how the heat transfer process from the gas in the combustion chamber, burned as well as the unburned gas regions, to the walls is affected by the autoignition phenomenon in SI engines. The zonal model in ref. [1] is adapted for the calculations. The radiative heat flux during the heat release period and the heat transfer in the thermal boundary layer by convection are predicted for situations when autoignition has occurred. The cylinder wall temperature is also used as a parameter in this study. The effects of engine operating parameters such as engine speed, timing of ignition, duration time of flame propagation and the fuel parameter Research Octane Number, i.e., RON, on the heat flux to the walls have been studied. The heat release is calculated for a detailed chemical kinetic model, refs. [1, 2 and 3].

This paper reports an one–dimensional modeling procedure of the hot spot autoignition with a detailed chemistry and multi–species transport in the end gas in an SI engine. The governing equations for continuity of mass, momentum, energy and species for an one–dimensional, unsteady, compressible, laminar, reacting flow and thermal fields are discretized and solved by a fully implicit method. A chemical kinetic mechanism is used for the primary reference fuels n–heptane and iso–octane. This mechanism contains 510 chemical reactions and 75 species. The change of the cylinder pressure is calculated from both flame propagation and piston movement. The turbulent velocity of the propagating flame is modeled by the Wiebe function. Adiabatic conditions, calculated by minimizing Gibb's free energy at each time step, are assumed behind the flame front in the burned gas.

The use of a spark plug as an ionization sensor in an engine, and its physical and chemical explanation has been investigated. By applying a small constant DC voltage across the electrodes of the spark plug and measuring the current through the electrode gap, the state of the gas can be probed. An analytical expression for the current as a function of temperature is derived, and an inverse relation, where the pressure is a function of the current, is also presented. It is also found that a relatively minor species, NO, seems to be the major agent responsible for the conductivity of the hot gas in the spark gap.