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Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

A new method for measuring unregulated substances in the exhaust gas is being investigated to clarify the influence of the vehicles' exhaust emissions into the environment. This paper explains our work on developing an analysis method for detecting and quantifying trace substances in the exhaust gas. A new analysis method was examined that uses thermal desorption to analyze trace amounts of polycyclic aromatic hydrocarbons (PAHs) in vehicle exhaust gas. This technique is faster than conventional methods and does not require any preconditioning of the samples before analysis. While lead and chloromethane were detected in the exhaust gas samples, it was made clear that these substances did not originate in the engine system. Accordingly, the results of this study indicate that careful attention must be paid to the test environment and the presence of measurement interfering substances in exhaust samples when measuring trace constituents in the exhaust gas from low-emission vehicles.

Three-dimensional combustion simulation tools together with the Universal Coherent Flamelet Model (UCFM), a flame propagation model, have been applied to SI lean-burn combustion to study the influence of the equivalence ratio on the amount of unburned hydrocarbons (HCs). Unburned HCs from piston-cylinder crevices were taken into the consideration by using a calculation grid incorporating the actual crevice volume and shape and by applying an autoignition model to post-flame phenomena. The calculation results show the general tendencies for the total amount of unburned HCs and their distribution in the combustion chamber.

This paper presents a measurement technique to visualize the distribution of the in-cylinder mixture temperature and an experimental approach for analyzing the effect of the temperature distribution prior to ignition on homogeneous charge compression ignition (HCCI) combustion. First, a visualization technique for mixture temperature distribution based on the temperature dependence of laser induced fluorescence (LIF) was developed. As the next step, measurement of the temperature distribution was applied to an analysis of HCCI combustion. Controlled non-uniform temperature distributions in the mixture prior to ignition were generated by a special intake system with a completely divided intake port having separate electrical heaters.

A transient knock prediction technique has been developed by coupling a zero-dimensional knocking simulation with chemical kinetics and a one-dimensional gas exchange engine model to study the occurrence of transient knock in SI engines. A mixed chemical reaction mechanism of the primary reference fuels was implemented in the two-zone combustion chamber model as the auto-ignition model of the end-gas. An empirical correlation between end-gas auto-ignition and knock intensity obtained through intensive analysis of experimental data has been applied to the knocking simulation with the aim of obtaining better prediction accuracy. The results of calculations made under various engine operating parameters show good agreement with experimental data for trace knock sensitivity to spark advance.

This paper presents a study of mixture formation in the combustion chamber of a direct-injection SI engine. In-cylinder flow measurement was conducted using laser Doppler velocimetry (LDV) and particle image velocimetry (PIV), and visualization of fuel vapor behavior was done using laser-induced fluorescence (LIF). Further, fast response flame ionization detector (FID) was used to measure the hydrocarbon (HC) concentrations in the vicinity of the spark plug. Thereby mixture concentrations in the vicinity of the spark plug, within the mixture distribution observed using LIF, were quantified. Results revealed that an upward flow forms near the center of the cylinder in the latter half of the compression stroke and goes from the piston crown toward the cylinder head. This upward flow is caused by the synergistic effect of the swirl motion generated in the cylinder and the cylindrical bowl provided in the piston crown eccentrically to the central axis of the cylinder.

This paper describes simultaneous attainment in improving fuel consumption, output power and reducing HC emissions with a direct injection S.I. engine newly developed in Nissan. Straight intake port is adopted to increase discharge coefficient under WOT operation and horizontal swirl flow is generated by a swirl control valve to provide stable stratified charge combustion under part load conditions. As a result, fuel consumption is reduced by more than 20% and power output is improved by approximately 10%. Moreover, unburned HC is reduced by equivalently 30% in engine cold start condition. An application of diagnostic and numerical simulation tools to investigate and optimize various factors are also introduced.

Laser induced fluorescence (LIF) is a useful method for visualizing the distribution of the air-fuel ratio in the combustion chamber. The way this method is applied mainly depends on the fluorescent tracer used, such as biacetyl, toluene, various aldehydes, fluoranthene or diethylketone, among others. Gasoline strongly absorbs light in the UV region, for example, at the 248-nm wavelength of broadband KrF excimer laser radiation. Therefore, when using this type of laser, iso-octane is employed as the fuel because it is transparent to 248-nm UV light. However, since the distillation curves of iso-octane and gasoline are different, it can be expected that their vaporization characteristics in the intake port and cylinder would also be different. The aim of this study was to find a better fuel for use with LIF at a broadband wavelength of 248 nm. Three tasks were undertaken in this study.

The California Low-Emission Vehicle (LEV) standards mandate a reduction in non-methane organic gases (NMOG). With the aim of analyzing NMOG emissions, a comparison was made of the hydrocarbon species found in the exhaust gas when different types of catalyst systems and fuel specifications were used. NMOG emissions are usually measured by removing methane from the total hydrocarbon (THC) emissions and adding aldehyde and ketone emissions. The NMOG level found in this way is thus influenced by the rate of methane in THC emissions. Another important factor in the LEV standards is specific reactivity (SR), indicating the formation potential of ozone, which is one cause of photochemical smog. Specific reactivity is expressed by the amount of ozone generated per unit weight of NMOG emissions, and is affected by the respective proportion of hydrocarbon species in the total NMOG emissions.

Coherent anti-Stokes Raman spectroscopy (CARS) temperature measurements were performed in the unburned gas in a spark ignition engine. First, as the residual gas mass fraction is one of the factor that is known to cause to autoignition, the effect of the residual gas mass fraction on the unburned gas temperature is estimated. In order to control the residual gas mass fraction, a skip fired cycle method was used., and the single cylinder test engine used in this study was fueled with gasoline (89.9 RON). The residual gas causes the unburned gas temperature to rise by approximately 55 K and it also produces a large temperature variation on the order of ±20 K when expressed as a standard deviation. Second, the unburned gas temperature of the single cylinder test engine and the 4 valve production engine was measured under steady-state engine operation in order to compare the residual gas mass fraction of the test engine with that of the production engine.

A new numerical simulation system has been developed which predicts flow behavior of fuel film formed on intake port and combustion chamber walls of gasoline engines. The system consists of a film flow model employing film thickness as a dependent variable, an air flow model, and a fuel spray model. The system can analyze fuel film flow formed on any arbitrary three-dimensional configuration. Fuel film flow formed under a condition of continuous intermittent fuel injection and steady-state air flow was calculated, and comparison with experimental data showed the system possessing ability of qualitative prediction.

With the aim of improving the air quality in large cities, the California Air Resources Board (CARB) has stipulated that non-methane organic gas (NMOG) composed of carbon numbers from C1 to C12 must be reduced for vehicle categories designated as Transitional Low Emission Vehicles (TLEVs), Low Emission Vehicles (LEVs), Ultra low Emission Vehicles (ULEVs), and Zero Emission Vehicles (ZEVs). Although considerable research work has been done on this issue to date, the entire picture is still not clear. Studies done by the authors have been aimed at providing a better understanding of the potential for reducing automotive tailpipe emissions by using several clean fuel candidates. The major questions of concern are the extent to which emissions of certain species can actually be reduced and what fuel can provide the best performance under a reduced NMOG condition.

Since a 4-valve engine is less flexible in the design and location of the intake ports as compared with a conventional 2-valve engine, there are some difficulties in strengthening the air motion, including swirl and turbulence, in order to achieve stable combustion under lean mixture operation. This study examined air motion imporvements of 4-valve engine that result in a stable combustion with a lean mixture. These improvements are brought about by the installation of a swirl control valve in each intake port. The results of this study have clarified that the lean stable limit was extended from an air-fuel ratio of 21.5 to 26.3 under a partial load, by optimizing the location and diameter of aperture of the swirl control valve.