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Recognition of Dimethyl Ether (DME) as an alternative fuel has been growing recently due to its fast evaporation and ignition in application of compression-ignition engine. Most importantly, combustion of DME produces almost no particulate matter (PM). The current study provides a further understanding of the combustion process in DME reacting spray via experiment done in a constant volume combustion chamber. Formaldehyde (CH2O), an important intermediate species in hydrocarbon combustion, has received much attention in research due to its unique contribution in chemical pathway that leads to the combustion and emission of fuels. Studies in other literature considered CH2O as a marker for UHC species since it is formed prior to diffusion flame. In this study, the formation of CH2O was highlighted both temporally and spatially through planar laser induced fluorescence (PLIF) imaging at wavelength of 355-nm of an Nd:YAG laser at various time after start of injection (ASOI).

Dimethyl ether (DME) appears to be an attractive alternative to common fossil fuels in compression ignition engines due to its smokeless combustion and fast mixture formation. However, in order to fully understand the complex combustion process of DME, there is still a remaining need to develop a comprehensive chemical kinetic mechanism that includes both soot and NOx chemistry. In this study, a detailed DME mechanism with 305 species is developed from the basic DME mechanism of Curran et al. (2000) with addition of soot and NOx chemistry from Howard's mechanism et al. (1999), and GRI 3.0 mechanism, respectively. Soot chemistry in Howard mechanism consisting hydrogen abstraction acetylene addition (HACA) and growth of small polycyclic aromatic hydrocarbons (PAH), assesses over a wide range of temperature and is able to predict good to fair the formation of PAH up to coronene.

High hydrocarbon (HC) emission during a cold start still remains one of the major emission control challenges for spark ignition (SI) engines in spite of about three decades of research in this area. This paper proposes a cold start HC emission control strategy based on a reduced order modeling technique. A novel singular perturbation approximation (SPA) technique, based on the balanced realization principle, is developed for a nonlinear experimentally validated cold start emission model. The SPA reduced model is then utilized in the design of a model-based sliding mode controller (SMC). The controller targets to reduce cumulative tailpipe HC emission using a combination of fuel injection, spark timing, and air throttle / idle speed controls. The results from the designed multi-input multi-output (MIMO) reduced order SMC are compared with those from a full order SMC. The results show the reduced SMC outperforms the full order SMC by reducing both engine-out and tailpipe HC emission.

Numerical modeling of aftertreatment systems has been proven to reduce development time as well as to facilitate understanding of the internal physical and chemical processes occurring during different operating conditions. Such a numerical model for a catalyzed diesel particulate filter (CPF) was developed in this research work which has been improved from an existing numerical model briefly described in reference. The focus of this CPF model was to predict the effect of the catalyst on the gaseous species concentrations and to develop particulate matter (PM) filtration and oxidation models for the PM cake layer and substrate wall so as to develop an overall model that accurately predicts the pressure drop and PM oxidized during passive oxidation and active regeneration. Descriptions of the governing equations and corresponding numerical methods used with relevant boundary conditions are presented.

The objective of this paper is to analyse the performance and the combustion of a large-bore single-cylinder medium speed engine running with hydrotreated vegetable oil. This fuel has a paraffinic chemical structure and high Cetane number. These features enable achievement of complete and clean combustion with different engine setups. The main benefits are thus lower soot and nitrogen oxides emissions compared to diesel fuel. The facility used in this study is a research engine, where the conditions upstream the machine, the valve timing and the injection parameters are fully adjustable. In fact, the boundary conditions upstream and downstream the engine are freely controlled by a separated supply air plant and by a throttle valve, located at the end of the exhaust pipe. The injection system is common-rail: rail pressure, injection timing and duration are completely adjustable.

Active regeneration experiments were performed on a production diesel aftertreatment system containing a diesel oxidation catalyst and catalyzed particulate filter (CPF) using blends of soy-based biodiesel. The effects of biodiesel on particulate matter oxidation rates in the filter were explored. These experiments are a continuation of the work performed by Chilumukuru et al., in SAE Technical Paper No. 2009-01-1474, which studied the active regeneration characteristics of the same aftertreatment system using ultra-low sulfur diesel fuel. Experiments were conducted using a 10.8 L 2002 Cummins ISM heavy-duty diesel engine. Particulate matter loading of the filter was performed at the rated engine speed of 2100 rpm and 20% of the full engine load of 1120 Nm. At this engine speed and load the passive oxidation rate is low. The 17 L CPF was loaded to a particulate matter level of 2.2 g/L.

Exhaust gas recirculation (EGR) has been employed in a diesel engine to reduce NOx emissions by diluting the fresh air charge with gases composed of primarily N2, CO2, H2O, and O2 from the engines exhaust stream. The addition of EGR reduces the production of NOx by lowering the peak cylinder gas temperature and reducing the concentration of O2 molecules, both of which contribute to the NOx formation mechanism. The amount of EGR has been typically controlled using an open loop control strategy where the flow of EGR was calibrated to the engine speed and load and controlled by the combination of an EGR valve and the ratio of the boost and exhaust back pressures. When oxygenated biofuels with lower specific energy are used, the engine control unit (ECU) will demand a higher fuel rate to maintain power output, which can alter the volumetric flow rate of EGR. In addition, oxygenated biofuels affect the oxygen concentration in the intake manifold gas stream.

Hydrotreating of vegetable oils or animal fats is an alternative process to esterification for producing biobased diesel fuels. Hydrotreated products are also called renewable diesel fuels. Hydrotreated vegetable oils (HVO) do not have the detrimental effects of ester-type biodiesel fuels, like increased NOx emission, deposit formation, storage stability problems, more rapid aging of engine oil or poor cold properties. HVOs are straight chain paraffinic hydrocarbons that are free of aromatics, oxygen and sulfur and have high cetane numbers. In this paper, NOx - particulate emission trade-off and NOx - fuel consumption trade-off are studied using different fuel injection timings in a turbocharged charge air cooled common rail heavy duty diesel engine. Tested fuels were sulfur free diesel fuel, neat HVO, and a 30% HVO + 70% diesel fuel blend. The study shows that there is potential for optimizing engine settings together with enhanced fuel composition.

The current study was focused on flow field measurements of diesel sprays. The global fuel spray characteristics, such as spray penetration, have also been measured. Particle Image Velocimetry (PIV) was utilized for flow field measurements and the global spray characteristics were recorded with high-speed back light photographing. The flow field was scanned to get an idea of the compatibility of PIV technique applied to dense and high velocity sprays. It is well proven that the PIV technique can be utilized at areas of low number density of droplets, but the center of the spray is way beyond the ideal PIV measurement conditions. The depth at which accurate flow field information can be gathered was paid attention to.

Soot modeling has become increasingly important as diesel engine manufacturers are faced with constantly tightening soot emission limits. As such the accuracy of the soot models used is more and more important but at the same time 3-D CFD engine studies require models that are computationally not too demanding. In this study, soot Phi-T maps created with detailed chemistry code have been used to develop a soot model for engineering purposes. The proposed soot model was first validated against detailed chemistry results in premixed laminar environment. As turbulence in engines is of major importance, it was taken into account in the soot oxidation part of the model with the laminar and turbulent characteristic time- type of approach. Finally, the model was tested in a large bore Diesel engine with varying loads. Within the steps described above, the proposed model was also compared with the well-known Hiroyasu-Magnussen soot model.

A novel two-stroke engine concept is introduced. The cylinder scavenging takes place during the upward motion of the piston. The gas exchange valves are similar to typical four-stroke valves, but the intake valves are smaller and lighter. The scavenging air pressure is remarkably higher than in present-day engines. The high scavenging air pressure is produced by an external compressor. The two-stroke operation is achieved without the drawbacks of port scavenged engines. Moreover, the combustion circumstances, charge pressure and temperature and internal exhaust gas re-circulation (EGR) can be controlled by using valve timings. There is good potential for a substantial reduction in NOx emissions through the use of adjustable compression pressure and temperature and by using the adjustable amount of exhaust gas re-circulation.

Three-dimensional diesel engine combustion simulations with single-step chemistry have been compared with two-step and three-step chemistry by means of the Laminar and Turbulent Characteristic Time Combustion model using the Star-CD program. The second reaction describes the oxidation of CO and the third reaction describes the combustion of H2. The comparisons have been performed for two heavy-duty diesel engines. The two-step chemistry was investigated for a purely kinetically controlled, for a mixing limited and for a combination of kinetically and mixing limited oxidation. For the latter case, two different descriptions of the laminar reaction rates were also tested. The best agreement with the experimental cylinder pressure has been achieved with the three-step mechanism but the differences with respect to the two-step and single-step reactions were small.

Non-evaporating diesel sprays have been simulated utilizing the ETAB and the WAVE atomization and breakup models and have been compared with experimental data. The experimental penetrations and widths were determined from back-lit spray images and the droplet sizes have been measured by means of a Malvern particle sizer. The model evaluation criteria include the spray penetration, the spray width and the local droplet size. The comparisons have been performed for variations of the injection pressure, the gas density and the fuel viscosity. The fuel nozzle exit velocities used in the simulations have been computed with a special code that considers the effect of in-nozzle cavitation. The simulations showed good overall agreement with experimental data. However, the capabilities of the models to predict the droplet size for different fuels could be improved.

The successful implementation of a clean, quiet, four-stroke engine into an existing snowmobile chassis has been achieved. The snowmobile is easy to start, easy to drive and environmentally friendly. The following paper describes the conversion process in detail with actual engine test data. The hydrocarbon emissions of the new, four-stroke snowmobile are 98% lower than current, production, two-stroke models. The noise production of the four-stroke snowmobile was 68 dBA during an independent wide open throttle acceleration test. If the four-stroke snowmobile were to replace all current, two-stroke snowmobiles in Yellowstone National Park (YNP), the vehicles would only produce 16% of the combined automobile and snowmobile hydrocarbon emissions compared to the current 93% produced by two-stroke snowmobiles.

The effects of a catalyzed particulate filter (CPF) and Exhaust Gas Recirculation (EGR) on heavy-duty diesel engine emissions were studied in this research. EGR is used to reduce the NOx emissions but at the same time it can increase total particulate matter (TPM) emissions. CPF is technology available for retrofitting existing vehicles in the field to reduce the TPM emissions. A conventional low sulfur fuel (371 ppm S) was used in all the engine runs. Steady-state loading and regeneration experiments were performed with CPF I to determine its performance with respect to pressure drop and particulate mass characteristics at different engine operating conditions. From the dilution tunnel emission characterization results for CPF II, at Mode 11 condition (25% load - 311 Nm, 1800 rpm), the TPM, HC and vapor phase emissions (XOC) were decreased by 70%, 62% and 62% respectively downstream of the CPF II.

Diesel particulate trap regeneration is a complex process involving the interaction of phenomena at several scales. A hierarchy of models for the relevant physicochemical processes at the different scales of the problem (porous wall, filter channel, entire trap) is employed to obtain a rigorous description of the process in a multidimensional context. The final model structure is validated against experiments, resulting in a powerful tool for the computer-aided study of the regeneration behavior. In the present work we employ this tool to address the effect of various spatial non-uniformities on the regeneration characteristics of diesel particulate traps. Non-uniformities may include radial variations of flow, temperature and particulate concentration at the filter inlet, as well as variations of particulate loading. In addition, we study the influence of the distribution of catalytic activity along the filter wall.

A study of particle size distributions was conducted on a Cummins M11 1995 engine using the Scanning Mobility Particle Sizer (SMPS) instrument in the baseline and downstream of the Catalyzed Particulate Filter (CPF). Measurements were made in the dilution tunnel to investigate the effect of primary dilution ratio and mixture temperature on the nuclei and accumulation mode particle formation. Experiments were conducted at two different engine modes namely Mode 11 (25% load - 311 Nm, 1800 rpm) and Mode 9 (75% load - 932 Nm, 1800 rpm). The nanoparticle formation decreased with increasing dilution ratios for a constant mixture temperature in the baseline as well as downstream of the CPF II for Mode 11 condition. At Mode 9 condition in the baseline, the dilution ratio had a little effect on the nanoparticle formation, since the distribution was not bimodal and was dominated by accumulation mode particles.

The effects of exhaust gas recirculation (EGR) on heavy-duty diesel emissions were studied at two EPA steady-state operating conditions, old EPA mode 9* (1800 RPM, 75% Load) and old EPA mode 11 (1800 RPM, 25% Load). Data were collected at the baseline, 10% and 16% EGR rates for both EPA modes. The study was conducted using a 1995 Cummins M11-330E heavy-duty diesel engine and compared to the baseline emissions from the Cummins 1988 and 1991 L10 engines. The baseline gas-, vapor- and particle-phase emissions were measured together with the particle size distributions at all modes of operation. The total particulate matter (TPM) and vapor phase (XOC) samples were analyzed for physical, chemical and biological properties. The results showed that newer engines with electronic engine controls and higher injector pressures produce TPM decreases from the 1988 to 1991 to 1995 engines with the solids decreasing more than the soluble organic fraction (SOF) of TPM.

The purpose of this research was to study the pressure drop profiles and regeneration temperature characteristics of Silicon Carbide (SiC) filters with and without a copper-based additive in the fuel, and also to compare their performance with two cordierite traps designated as EX-47 and EX-80. The collection of the particulate matter inside the trap imposes a backpressure on the engine which requires a periodic oxidation or regeneration of the particulate matter. The presence of copper additive in the fuel reduces the particulate ignition temperature from approximately 500 to 375°C. Two SiC systems were tested during this research. The first system consisted of one 14 L SiC trap, while the second system, the dual trap system (DTS), consisted of two 12 L SiC traps mounted in parallel. The test matrix included two types of regeneration tests, controlled and uncontrolled and three levels of Cu fuel additive (0, 30, and 60 ppm).

The purpose of this study was to investigate the pressure drop and regeneration characteristics of a silicon carbide (SiC) wall-flow diesel particulate filter. The performance of a 25 μm mean pore size SiC dual trap system (DTS) consisting of two 12 liter traps connected in parallel in conjunction with a copper (Cu) fuel additive was evaluated. A comparison between the 25 μm DTS and a 15 μm DTS was performed, in order to show the effect of trap material mean pore size on trap loading and regeneration behavior. A 1988 Cummins LTA 10-300 diesel engine was used to evaluate the performance of the 15 and 25 μm DTS. A mathematical model was developed to better understand the thermal and catalytic oxidation of the particulate matter. For all the trap steady-state loading tests, the engine was run at EPA mode 11 for 10 hours. Raw exhaust samples were taken upstream and downstream of the trap system in order to determine the DTS filtration efficiency.